Coupled aggregation and sedimentation processes: the sticking probability effect.

Abstract

The influence of the sticking probability P and the drift velocity on kinetics and structure formation arising in coupled aggregation and sedimentation processes was studied by means of simulations. For this purpose, a large prism with no periodical conditions for the sedimentation direction was considered allowing for sediment formation at the prism base. The time evolution of the cluster size distribution (CSD) and weight-average cluster size (n(w)) were determined in three different regions of the prism. The cluster morphology and the sediment structure were also analyzed. We found that the coupled aggregation and sedimentation processes in the bulk are governed by P for short times, and controlled by the Péclet number Pe for long times. In the lower part of the reaction volume, where the sediment grows, the local n(w) grows at sufficiently large times analytically with an exponent of four. This behavior seems to be independent of Pe and P. The obtained results are in good agreement with the experimental data reported by C. Allain, M. Cloitre, and M. Wafra [Phys. Rev. Lett. 74, 1478 (1995)] and support the idea of a possible internal cluster rearrangement for the experiments. Finally, we discuss how the scale dependent fractal character of the sediment is related to the different stages of the aggregation process.