Spatially resolved NQR.

Abstract

Pure nuclear quadrupole resonance (NQR) was combined with a rotating-frame imaging technique (rho NQRI). The method is suitable for powdery or crystalline materials containing quadrupole nuclei. The spatial information is encoded in the amplitudes of the free-induction decays (FIDs) by gradients of the radio frequency amplitude of the excitation pulse. The pulse length is incremented in a series of experiments so that a pseudo-FID can be formed from the intensities of a selected NQR line. A deconvolution procedure is used for the analysis of the pseudo-FIDs. The result is a sample profile along the gradient direction. The technique is particularly suitable for the detection of the spatial distribution of physical parameters producing NQR line shifts. Examples are stress or temperature. Two-dimensional images can be produced by rotating the sample step by step. For each orientation a profile across the sample is evaluated. A backprojection reconstruction formalism then permits the rendering of two-dimensional NQR images.