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Transverse dephasing optimized solid-state NMR spectroscopy.

G De Paëpe·N Giraud·A Lesage·P Hodgkinson·A Böckmann·L Emsley
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Abstract

It is shown how coherence lifetimes in solid-state NMR experiments can be controlled. New decoupling schemes are introduced which actively optimize dephasing times, providing increases of up to a factor of 2 with respect to the best existing schemes. The new schemes are implemented in transverse-dephasing-optimized (TDOP) NMR experiments for the disorded solid cellulose, and for a microcrystalline protein, where sensitivity improvements of up to a factor of 5 are obtained.

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Bacillus subtilisBacterial ProteinsCarbon RadioisotopesCelluloseNuclear Magnetic Resonance, BiomolecularPhosphoproteinsJournal Article

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G De Paëpe, N Giraud, A Lesage, P Hodgkinson, A Böckmann, L Emsley. 2003-11-19. Transverse dephasing optimized solid-state NMR spectroscopy.. https://doi.org/10.1021/ja037213j

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