Comprehensive two-dimensional gas chromatography with atomic emission detection and correlation with mass spectrometric detection: principles and application in petrochemical analysis.

Leo L P van Stee; Jan Beens; René J J Vreuls; Udo A Th Brinkman

doi:10.1016/s0021-9673(03)01301-3

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Comprehensive two-dimensional gas chromatography with atomic emission detection and correlation with mass spectrometric detection: principles and application in petrochemical analysis.

Leo L P van Stee·Jan Beens·René J J Vreuls·Udo A Th Brinkman

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Abstract

Comprehensive gas chromatography (GC x GC) has been combined with atomic emission detection (AED) to enable element-selective detection. Under optimised experimental conditions, the requirement of minimum five data points across a peak can be obtained even for analytes eluting early from the second-dimension column. Simple manipulation of the results allows the combined presentation of up to four sets of elemental data in one two-dimensional plot. GC x GC with AED and mass spectrometric (MS) detection in petrochemical analysis for fingerprinting as well as the identification of N- and S-containing unknowns is presented as an application.

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Leo L P van Stee, Jan Beens, René J J Vreuls, Udo A Th Brinkman. 2003-11-26. Comprehensive two-dimensional gas chromatography with atomic emission detection and correlation with mass spectrometric detection: principles and application in petrochemical analysis.. https://doi.org/10.1016/s0021-9673(03)01301-3

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