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PubMed · 15180432

Anion binding with a tripodal amine.

Abstract

Binding studies of the tren-based amine, L (N,N',N' '-tris(2-benzylaminoethyl)amine), with inorganic anions and two crystal structures, [H(3)L][H(2)PO(4)](3).H(3)PO(4) and [H(3)L][Br](3), are reported. NMR titration results indicate that the ligand binds H(2)PO(4)(-) and HSO(4)(-) more strongly than NO(3)(-) and halides. In the crystal structure of the phosphate complex, the ligand is triprotonated with the three arms pointing outward in a trigonal-planar-like arrangement. Four phosphate species are associated with the receptor, and have been assigned as three H(2)PO(4)(-) counterions located between each of the tren arms, and an additional H(3)PO(4) molecule above the quasi-planar tren. The structure of the bromide complex is slightly different, although again the tren receptor is triprotonated and quasi-planar, but in this case C(2v)-like symmetry is seen with two of the arms pointed in the same direction with a bromide ion in between. The other two bromides lie outside of the tren arms.

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BibTeXRIS

Md Alamgir Hossain, Jennifer Ann Liljegren, Douglas Powell, Kristin Bowman-James. 2004-06-14. Anion binding with a tripodal amine.. https://doi.org/10.1021/ic049762b

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