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PubMed · 15340907

Smart materials based on self-assembled hydrogen-bonded comb-shaped supramolecules.

Gerrit ten Brinke·Olli Ikkala
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Abstract

Block copolymer self-assembly and supramolecular chemistry can be combined most naturally to prepare smart polymer nanomaterials. An attractive route is based on comb-shaped supramolecules, obtained by attaching side chains to (co)polymers by physical (non-covalent) interactions. Hydrogen bonding is a key element of our approach. It combines an ease of synthesis with other important approach-specific elements, such as hierarchical self-assembly, strongly enhanced processability, swelling, and cleaving. Functional properties discussed include anisotropic proton conductivity, switching proton conductivity, electronically conducting nanowires, polarized luminance, dielectric stacks (optical reflectivity), functional membranes, and nano objects.

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AnisotropyElectric ConductivityElectronsHydrogen BondingMacromolecular SubstancesMembranes, ArtificialModels, MolecularMolecular StructureNanotechnologyPolymersProtonsTemperatureJournal Article

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Gerrit ten Brinke, Olli Ikkala. 2004. Smart materials based on self-assembled hydrogen-bonded comb-shaped supramolecules.. https://doi.org/10.1002/tcr.20018

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