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Separated quadrupolar field experiment.

Abstract

We describe an NMR experiment that produces spectra correlating the first-order quadrupolar spectrum and the central transition spectrum of half-integer quadrupolar spins, allowing one to separate the quadrupolar parameters in overlapping spectra under both static and magic-angle-spinning conditions. Promising fields of applications include situations where the sample cannot easily be rotated, or where it cannot be rotated at the magic angle.

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BibTeXRIS

Rajeev Kumar, Wen Ling, Wolfgang Schoefberger, Alexej Jerschow. 2005. Separated quadrupolar field experiment.. https://doi.org/10.1016/j.jmr.2004.09.025

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