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Revisiting the S-Au(111) interaction: static or dynamic?

Abstract

The Au-S interaction is probably the most intensively studied interaction of Au surfaces with nonmetals, as, for example, it plays an important role in Au ore formation(1) and controls the structure and dynamics of thiol-based self-assembled monolayers (SAMs). Various S-induced surface structures on Au(111) were recently reported for different conditions and predominantly interpreted in terms of a static Au surface. Here, we demonstrate that the Au(111) surface exhibits a very dynamic character upon interaction with adsorbed sulfur: large-scale surface restructuring and incorporation of Au atoms into a growing 2D AuS phase were observed in situ. These results provide new insight into the Au-S surface chemistry.

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Monika M Biener, Juergen Biener, Cynthia M Friend. 2005-03-01. Revisiting the S-Au(111) interaction: static or dynamic?. https://doi.org/10.1021/la047387u

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