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PubMed · 15954755

Electrostatic control of aromatic stacking interactions.

Scott L Cockroft·Christopher A Hunter·Kevin R Lawson·Julie Perkins·Christopher J Urch
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Abstract

A supramolecular approach has been used to investigate the free energies of intermolecular aromatic stacking interactions. Chemical double mutant cycles have been used to measure the effect of a range of substituents on face-to-face stacking interactions with phenyl and pentafluorophenyl rings. Electrostatic effects dominate the trends in interaction energy.

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DNAHydrocarbons, AromaticHydrogen BondingModels, MolecularStatic ElectricityThermodynamicsJournal ArticleResearch Support, Non-U.S. Gov't

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Scott L Cockroft, Christopher A Hunter, Kevin R Lawson, Julie Perkins, Christopher J Urch. 2005-06-22. Electrostatic control of aromatic stacking interactions.. https://doi.org/10.1021/ja050880n

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