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Formation and structure of stable aggregates in binary diffusion-limited cluster-cluster aggregation processes.

Abstract

Binary diffusion-limited cluster-cluster aggregation processes are studied as a function of the relative concentration of the two species. Both, short and long time behaviors are investigated by means of three-dimensional off-lattice Brownian Dynamics simulations. At short aggregation times, the validity of the Hogg-Healy-Fuerstenau approximation is shown. At long times, a single large cluster containing all initial particles is found to be formed when the relative concentration of the minority particles lies above a critical value. Below that value, stable aggregates remain in the system. These stable aggregates are composed by a few minority particles that are highly covered by majority ones. Our off-lattice simulations reveal a value of approximately 0.15 for the critical relative concentration. A qualitative explanation scheme for the formation and growth of the stable aggregates is developed. The simulations also explain the phenomenon of monomer discrimination that was observed recently in single cluster light scattering experiments.

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BibTeXRIS

J M López-López, A Moncho-Jordá, A Schmitt, R Hidalgo-Alvarez. 2005-09-01. Formation and structure of stable aggregates in binary diffusion-limited cluster-cluster aggregation processes.. https://doi.org/10.1103/physreve.72.031401

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