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Novel 3-D structures in polymer films by coupling external and internal fields.

Abstract

A route to produce novel three-dimensional structures in thin films is demonstrated. Such structures are most difficult to produce in a simple manner without the use of multiple fabrication steps. Here, we show the generation of 3-D cage-type structures using a combination of electrohydrodynamic instabilities and dewetting in a polymer/polymer/air trilayer. Removal of one of the components by use of a selective solvent or by degradation of one of the components reveals the formation of a three-dimensional structure, where one polymer is encased in the other. Thus, by coupling an external field with a surface field inherent to the polymers, a novel fabrication strategy is shown that has clear applications in microfluidics and microelectromechanical systems with extensions to patterned surfaces and structured fluids, like block copolymers.

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BibTeXRIS

Michael D Dickey, Suresh Gupta, K Amanda Leach, Elizabeth Collister, C Grant Willson, Thomas P Russell. 2006-04-25. Novel 3-D structures in polymer films by coupling external and internal fields.. https://doi.org/10.1021/la052954e

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