Coiled molecules in spring loaded devices.

Dariush Ajami; Julius Rebek

doi:10.1021/ja064233n

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Coiled molecules in spring loaded devices.

Dariush Ajami·Julius Rebek

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Abstract

A cylindrical capsule containing a coiled alkane incorporates spacers. The alkane lengthens and gauche strain is relieved. The spacer can be removed to reset the system to the original state. The system represents a spring-loaded device that operates reversibly in response to acids and bases.

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Alkanes Alkynes DNA Ethers, Cyclic Imidazoles Magnetic Resonance Spectroscopy Models, Molecular Molecular Conformation Resorcinols Heterocyclic Compounds, 2-Ring Imidazolidines Journal Article Research Support, N.I.H., Extramural

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Dariush Ajami, Julius Rebek. 2006-11-29. Coiled molecules in spring loaded devices.. https://doi.org/10.1021/ja064233n

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