Self-assembling poly(dioxaborole)s as blue-emissive materials.

Weijun Niu; Mark D Smith; John J Lavigne

doi:10.1021/ja065986c

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Self-assembling poly(dioxaborole)s as blue-emissive materials.

Weijun Niu·Mark D Smith·John J Lavigne

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Abstract

Conjugated, borole-linked polymers have been self-assembled based on boronate ester formation between a fluorene-2,7-diboronic acid and 1,2,4,5-tetrahydroxybenzene. Readily soluble polymers with molecular weights approaching 60 000 have been generated with materials exhibiting extended conjugation over approximately 3-5 borole linkages. Emission from these polymers reaches into the visible (blue) range, representing a novel class of blue-emitting materials.

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Borates Boronic Acids Light Molecular Structure Polymers Stereoisomerism Journal Article Research Support, Non-U.S. Gov't

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Weijun Niu, Mark D Smith, John J Lavigne. 2006-12-27. Self-assembling poly(dioxaborole)s as blue-emissive materials.. https://doi.org/10.1021/ja065986c

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