Pulse voltammetry at microcylinder electrodes.

Abstract

Microcylindrical electrodes are easier to construct and maintain than microdisk electrodes. In the normal-pulse mode, ranges of time parameters and electrode sizes can be found such that depletion of reactant is unimportant and the response to the analysis pulse is predicted by theory for planar conditions. Similarly, ranges of parameters are found for reverse-pulse voltammetry such that the potential-dependent response can be treated as a sequence of individual double-pulse responses. Cylindrical diffusion and convection act to replenish reactant quickly near the electrode and thus permit overall experiment times in the range of seconds. For square-wave voltammetry the shape and position of the net current response are independent of the extent of cylindrical diffusion.