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Through-bond electron-transfer interaction in proteins.

A A da Gama
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Abstract

A model for the through-bond electronic interaction between electron donor and acceptor in proteins is developed. We use a one-electron Hamiltonian, write the Dyson's equation in site representation and solve it by using a Green's function formalism with some renormalization ideas. An expression for Tab which describes the exponential decay with distance bond per bond is obtained. Covalent, non-covalent and convergent pathways are considered and no periodic approximation is needed.

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A A da Gama. 1990-01-23. Through-bond electron-transfer interaction in proteins.. https://doi.org/10.1016/s0022-5193(05)80226-7

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