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Apparent discrepancy between theory and experimental data for dissolution from the rotating disk under stirred and unstirred conditions.

A P Simonelli·D R Flanagan·W I Higuchi
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A P Simonelli, D R Flanagan, W I Higuchi. 1968. Apparent discrepancy between theory and experimental data for dissolution from the rotating disk under stirred and unstirred conditions.. https://doi.org/10.1002/jps.2600570940

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PubMed1993

An experimental method for determining the Hildebrand solubility parameter of organic nonelectrolytes.

A three-solvent system was used to determine the Hildebrand solubility parameters of organic nonelectrolytes. The experimental Hildebrand solubility parameter represents a weighted average of the mole fraction solubilities of the solute in these three individual solvents (ethyl acetate, 1-propanol, and 1,2-propanediol). The solvent system estimated the Hildebrand solubility parameters of solutes within a range from 8.9 to 14.8 (cal/cm3)2(1). Deviations ranged from 0.8 to 12.9%, with the highest value at the extreme and well within 10% at the median. Estimation of the Hildebrand solubility parameters of solutes within a wider range and with somewhat better accuracy was made with a five-solvent system (hexane, ethyl acetate, 1-propanol, 1,2-propanediol, and water).

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