Solid-state decomposition of alkoxyfuroic acids.

J T Carstensen; R Kothari

doi:10.1002/jps.2600701002

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PubMed · 7299642

Solid-state decomposition of alkoxyfuroic acids.

J T Carstensen·R Kothari

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Abstract

A series of alkoxyfuroic acids with alkyl lengths of n = 8-18 was synthesized, and the solid-state decomposition was studied. Bawn kinetics were adhered to, and the solid and liquid decomposition rate constants were established; they followed an Arrhenius relationship well, with energy of activations and preexponential factors being a function of the chain length. There was a break in this correlation between n = 14 and n = 16. The liquefaction points were of the expected correlation with inverse temperature. The isokinetic temperature (Ti) fell fairly well on the line demonstrated for other compound series.

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Atmospheric Pressure Chemical Phenomena Chemistry, Physical Drug Stability Furans Kinetics Temperature Journal Article Research Support, Non-U.S. Gov't

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J T Carstensen, R Kothari. 1981. Solid-state decomposition of alkoxyfuroic acids.. https://doi.org/10.1002/jps.2600701002

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