1,8-bis(hydroxymethyl)anthracene.

W D Aumiller; R E Gerkin

doi:10.1107/s0108270197001108

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PubMed · 9208460

1,8-bis(hydroxymethyl)anthracene.

W D Aumiller·R E Gerkin

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Abstract

Anthracene-1,8-dimethanol, C16H14O2, crystallized in the centrosymmetric space group P21/n. The anthracene core is nearly planar and shows good agreement with the anthracene core of anthracene-1,8-dicarboxylic acid. The geometric disposition of the hydroxymethyl groups and the values of the hydrogen-bond parameters are strikingly similar to those in the naphthalene analog. As in that structure, each hydroxyl group participates both as a donor and acceptor in an infinite zigzag chain of hydrogen bonds which propagates along the [010] direction. Moreover, the disposition of the entire molecule in the cell of the present compound is also strikingly similar to that of the naphthalene analog in its cell.

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Anthracenes Chemical Phenomena Chemistry, Physical Crystallography, X-Ray Hydrogen Bonding Methanol Models, Molecular Molecular Structure Journal Article Research Support, U.S. Gov't, P.H.S.

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W D Aumiller, R E Gerkin. 1997-06-15. 1,8-bis(hydroxymethyl)anthracene.. https://doi.org/10.1107/s0108270197001108

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