PubMed · 9546885
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J Zurlinden. 1998-01-12. Relief for migraine sufferers.. https://pubmed.ncbi.nlm.nih.gov/9546885/
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An enantiospecific route to the previously unreported 1,6-difunctionalized dodecahydrobenz[f]indene ring system is described. Optically pure Hajos-Parrish ketone is used as the building block for preparation of a 6-methyleneinden-5-ol. This allylic alcohol is then utilized in a Claisen rearrangement under Johnson's conditions to introduce a side chain that is further modified and cyclized to produce the benz[f]indene ring system.
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