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At least 235 records · Page 13Linked to original sources
PubMed1978

[Effect of dietary nitrogen compounds and urea on the GLDH and DS activities in broilers].

The influence of concentration of nitrogenous matters (N-matters) and urea supplement in diet for broilers was studied, as exerted on the activities of the enzymes glutamate dehydrogenase (GLDH) and glutamine synthetase (GS) in liver, kidney, tissue and contents of the cecum. If 2% urea had been substituted for a portion of N-matters, no significant differences in the activities of both enzymes in liver and cecum were found. Higher levels of GLDH were recorded in the kidney of broilers given diets with the urea supplement of 17 and 19% N-matters concentrations. The GLDH and GS activities were significantly high in the contents of the cecum, the GLDH activity being the highest with the diet of 19% N-matters concentration. No significant changes in the GLDH activity depending on the concentration of N-matters in the diet were observed in the liver. The GS activity increased moderately with the higher concentration of N-matters.

Animal Feed↗
PubMed1977

[Effects of small nitrogen compound concentrations on the upper respiratory tract].

The authors examined a group of 160 persons employed at an exposure to small concentration (below HAC) of nitrogen and ammonia oxides, and a group of 130 controls. It was found that in the group of subjects exposed to toxic compounds the percentage of persons suffering from inflammation of the upper respiratory tract was much higher (37.5%) than in the control group (13.1%). Olfactometric examinations indicated a disadvantageous effect of the mentioned compounds upon the acuity of the sense of smell, whereas rhinospirometric examination did not reveal any differences between the control group and the group of persons exposed to nitrogen and ammonia oxides.

Adult↗
PubMed2006

Quasi-isomeric gallium amides and imides GaNR2 and RGaNR (R = organic group): reactions of the digallene, Ar'GaGaAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2) with unsaturated nitrogen compounds.

Reactions of the "digallene" Ar'GaGaAr'(1) (Ar' = C(6)H(3)-2,6-(C(6)H(3)-2,6-Pr(i)(2))(2)), which dissociates to green :GaAr' monomers in solution, with unsaturated N-N-bonded molecules are described. Treatment of solutions of :GaAr' with the bulky azide N(3)Ar(#) (Ar(#) = C(6)H(3)-2,6-(C(6)H(2)-2,6-Me(2)-4-Bu(t))(2)), afforded the red imide Ar'GaNAr(#) (2). Addition of the azobenzenes, ArylNNAryl (Aryl = C(6)H(4)-4-Me (p-tolyl), mesityl, and C(6)H(3)-2,6-Et(2)) yielded the 1,2-Ga(2)N(2) ring compound Ar'GaN(p-tolyl)N(p-tolyl)GaA' (3) or the products MesN=NC(6)H(2)-2,4-Me(2)-6-Ga(Me)Ar' (4) and 2,6-Et(2)C(6)H(3)N=NC(6)H(3)-2-Et-6-Ga(Et)Ar' (5). Reaction of GaAr' with N(2)CPh(2) yielded the 1,3-Ga(2)N(2) ring compound Ar'Ga(mu:eta(1)-N(2)CPh(2))(2)GaAr' (6), which is quasi-isomeric to 3. Calculations on simple model isomers showed that the Ga(I) amide GaNR(2) (R = Me) is much more stable than the isomeric Ga(III) imide RGaNR. This led to the synthesis of the first stable monomeric Ga(I) amide, GaN(SiMe(3))Ar' ' (8) (Ar' ' = C(6)H(3)-2,6-(C(6)H(2)-2,4,6-Me(3))(2) from the reaction of LiN(SiMe(3))Ar' ' (7) and "GaI". Compound 8 is also the first one-coordinate gallium species to be characterized in the solid state. The reaction of 8 with N(3)Ar' ' afforded the amido-imide derivative Ar' 'NGaN(SiMe(3))Ar' ' (9), a gallium nitrogen analogue of an allyl anion. All compounds were spectroscopically and structurally characterized. In addition, DFT calculations were performed on model compounds of the amide, imide, and cyclic 1,2- and 1,3-species to better understand their bonding. The pairs of compounds 2 and 8 as well as 3 and 6 are rare examples of quasi-isomeric heavier main group element compounds.

Journal Article↗