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Detection of organic matter in interstellar grains.

Star formation and the subsequent evolution of planetary systems occurs in dense molecular clouds, which are comprised, in part, of interstellar dust grains gathered from the diffuse interstellar medium (DISM). Radio observations of the interstellar medium reveal the presence of organic molecules in the gas phase and infrared observational studies provide details concerning the solid-state features in dust grains. In particular, a series of absorption bands have been observed near 3.4 microns (approximately 2940 cm-1) towards bright infrared objects which are seen through large column densities of interstellar dust. Comparisons of organic residues, produced under a variety of laboratory conditions, to the diffuse interstellar medium observations have shown that aliphatic hydrocarbon grains are responsible for the spectral absorption features observed near 3.4 microns (approximately 2940 cm-1). These hydrocarbons appear to carry the -CH2- and -CH3 functional groups in the abundance ratio CH2/CH3 approximately 2.5, and the amount of carbon tied up in this component is greater than 4% of the cosmic carbon available. On a galactic scale, the strength of the 3.4 microns band does not scale linearly with visual extinction, but instead increases more rapidly for objects near the Galactic Center. A similar trend is noted in the strength of the Si-O absorption band near 9.7 microns. The similar behavior of the C-H and Si-O stretching bands suggests that these two components may be coupled, perhaps in the form of grains with silicate cores and refractory organic mantles. The ubiquity of the hydrocarbon features seen in the near infrared near 3.4 microns throughout out Galaxy and in other galaxies demonstrates the widespread availability of such material for incorporation into the many newly forming planetary systems. The similarity of the 3.4 microns features in any organic material with aliphatic hydrocarbons underscores the need for complete astronomical observational coverage in the 2-30 microns region, of lines of sight which sample dust in both dense and diffuse interstellar clouds, in order to uniquely specify the composition of interstellar organics. This paper reviews the information available from ground-based observations, although currently the Infrared Satellite Observatory is adding to our body of knowledge on this subject by providing more extensive wavelength coverage. The Murchison carbonaceous meteorite has also been used as an analog to the interstellar observations and has revealed a striking similarity between the light hydrocarbons in the meteorite and the ISM; therefore this review includes comparisons with the meteoritic analog as well as with relevant laboratory residues. Fundamental to the evolution of the biogenic molecules, to the process of planetary system formation, and perhaps to the origin of life, is the connection between the organic material found in the interstellar medium and that incorporated in the most primitive solar system bodies.

Astronomy↗

X-ray and molecular emission from the nearest region of recent star formation.

The isolated, young, sunlike star TW Hya and four other young stars in its vicinity are strong x-ray sources. Their similar x-ray and optical properties indicate that the stars make up a physical association that is on the order of 20 million years old and that lies between about 40 and 60 parsecs (between about 130 and 200 light years) from Earth. TW Hya itself displays circumstellar CO, HCN, CN, and HCO+ emission. These molecules probably orbit the star in a solar-system-sized disk viewed more or less face-on, whereas the star is likely viewed pole-on. Being at least three times closer to Earth than any well-studied region of star formation, the TW Hya Association serves as a test-bed for the study of x-ray emission from young stars and the formation of planetary systems around sunlike stars.

Astronomical Phenomena↗

The first 800 million years: environmental models for early Earth.

Space exploration has changed our views not only on the properties of celestial bodies and the interplanetary medium but also our perspective on the formation of such bodies, including the Earth. However, on few points do the new hetegonic insights approach certainty. More appropriately, they can be said to raise physically meaningful questions and to decrease the degrees of freedom allowable in any given scenario, which necessarily extends into the early history of the planetary crust, ocean and atmosphere. An attempt is made here to outline the basic schemes envisaged in modern studies of the origin of the Earth and the ramification of consequences for its early evolution that currently appear allowable and supported by observation.

Atmosphere↗

Implications of Mars Pathfinder data for the accretion history of the terrestrial planets.

Accretion models of the terrestrial planets often assume planetary bulk compositions with nonvolatile element abundance ratios equivalent to those of C1 carbonaceous chondrites. The moment of inertia factor of Mars reported by the Pathfinder team is inconsistent with a bulk planet C1 Fe/Si ratio or Fe content, which suggests that C1 chondrite accretion models are insufficient to explain the formation of Mars and the other terrestrial planets. Future planetary accretion models will have to account for variations in bulk Fe/Si ratios among the terrestrial planets.

Carbon↗

Isotopic ratios in planetary atmospheres.

Recent progress on measurements of isotopic ratios in planetary or satellite atmospheres include measurements of the D/H ratio in the methane of Uranus, Neptune and Titan and in the water of Mars and Venus. Implications of these measurements on our understanding of the formation and evolution of the planets and satellite are discussed. Our current knowledge of the carbon, nitrogen and oxygen isotopic ratios in the atmospheres of these planets, as well as on Jupiter and Saturn, is also reviewed. We finally show what progress can be expected in the very near future due to some new ground-based instrumentation particularly well suited to such studies, and to forthcoming space missions.

Atmosphere↗

Ways that our Solar System helps us understand the formation of other planetary systems and ways that it doesn't.

Models of planetary formation can be tested by comparison of their ability to predict features of our Solar System in a consistent way, and then extrapolated to other hypothetical planetary systems by different choice of parameters. When this is done, it is found that the resulting systems are insensitive to direct effects of the mass of the star, but do strongly depend on the properties of the disk, principally its surface density. Major uncertainty results from lack of an adequate theoretical model that predicts the existence, size, and distribution of analogs of our Solar System, particularly the gas giants Jupiter and Saturn. Nevertheless, reasons can be found for expecting that planetary systems, including those containing biologically habitable planets similar to Earth, may be abundant in the Galaxy and Universe.

Astronomical Phenomena↗

Photo-induced fractionation of water isotopomers in the Martian atmosphere.

The history and size of the water reservoirs on early Mars can be constrained using isotopic ratios of deuterium to hydrogen. We present new laboratory measurements of the ultraviolet cross-sections of H2O and its isotopomers, and modeling calculations in support of a photo-induced fractionation effect (PHIFE), that reconciles a discrepancy between past theoretical modeling and recent observations. This supports the hypothesis that Mars had an early warm atmosphere and has lost at least a 50-m global layer of water. Likely applications of PHIFE to other planetary atmospheres are sketched.

Atmosphere↗

Gaia and natural selection.

Evidence indicates that the Earth self-regulates at a state that is tolerated by life, but why should the organisms that leave the most descendants be the ones that contribute to regulating their planetary environment? The evolving Gaia theory focuses on the feedback mechanisms, stemming from naturally selected traits of organisms, that could generate such self-regulation.

Biological Evolution↗

Accretion of Moon and Earth and the emergence of life.

The discrepancy between the impact records on the Earth and Moon in the time period, 4.0-3.5 Ga calls for a re-evaluation of the cause and localization of the late lunar bombardment. As one possible explanation, we propose that the time coverage in the ancient rock record is sufficiently fragmentary, so that the effects of giant, sterilizing impacts throughout the inner solar system, caused by marauding asteroids, could have escaped detection in terrestrial and Martian records. Alternatively, the lunar impact record may reflect collisions of the receding Moon with a series of small, original satellites of the Earth and their debris in the time period about 4.0-3.5 Ga. The effects on Earth of such encounters could have been comparatively small. The location of these tellurian moonlets has been estimated to have been in the region around 40 Earth radii. Calculations presented here, indicate that this is the region that the Moon would traverse at 4.0-3.5 Ga, when the heavy and declining lunar bombardment took place. The ultimate time limit for the emergence of life on Earth is determined by the effects of planetary accretion--existing models offer a variety of scenarios, ranging from low average surface temperature at slow accretion of the mantle, to complete melting of the planet followed by protracted cooling. The choice of accretion model affects the habitability of the planet by dictating the early evolution of the atmosphere and hydrosphere. Further exploration of the sedimentary record on Earth and Mars, and of the chemical composition of impact-generated ejecta on the Moon, may determine the choice between the different interpretations of the late lunar bombardment and cast additional light on the time and conditions for the emergence of life.

Earth, Planet↗

Influx of cometary volatiles to planetary moons: the atmospheres of 1000 possible Titans.

We use a Monte Carlo model to simulate impact histories of possible Titans, Callistos, and Ganymedes. Comets create or erode satellite atmospheres, depending on their mass and velocity distributions: faster and bigger comets remove atmophiles; slower or smaller comets supply them. Mass distributions and the minimum total mass of comets passing through the Saturn system were derived from the crater records of Rhea and Iapetus. These were then scaled to give a minimum impact history for Titan. From this cometary population, of 1000 initially airless Titans, 16% acquired atmospheres larger than Titan's present atmosphere (9 x 10(21) g), and more than half accumulated atmospheres larger than 10(21) g. In contrasts to the work of Zahnle et al. (1992), we find that, in most trials, Callisto acquires comet-based atmospheres. Atmospheres acquired by Callisto and, especially, Ganymede are sensitive to assumptions regarding energy partitioning into the ejecta plume. If we assume that only the normal velocity component heats the plume, the majority of Ganymedes and half of the Callistos accreted atmospheres smaller than 10(20) g. If all the impactor's velocity heats the plume, Callisto's most likely atmosphere is 10(17) g and Ganymede's is negligible. The true cometary flux was most likely larger than that derived from crater records, which raises the probability that Titan, Ganymede, and Callisto acquired substantial atmospheres. However, other loss processes (e.g., sputtering by ions swept up by the planetary magnetic field, solar UV photolysis of hydrocarbons) are potentially capable of eliminating small atmospheres over the age of the solar system. The dark material on Callisto's surface may be a remnant of an earlier, now vanished atmosphere.

Atmosphere↗

Natural transfer of viable microbes in space.

The possibility and probability of natural transfer of viable microbes from Mars to Earth and Earth to Mars traveling in meteoroids during the first 0.5 Ga and the following 4 Ga are investigated, including: --radiation protection against the galactic cosmic ray nuclei and the solar rays, dose rates as a function of the meteorite's radial column mass (radius x density), combined with dose rates generated by natural radioactivity within the meteorite; and survival curves for some bacterial species using NASA's HZETRN transport code --other factors affecting microbe survival: vacuum; central meteorite temperatures at launch, orbiting, and arrival; pressure and acceleration at launch; spontaneous DNA decay; metal ion migration --mean sizes and numbers of unshocked meteorites ejected and percentage falling on Earth, using current semiempirical results --viable flight times for the microbe species Bacillus subtilis and Deinococcus radiodurans R1 --the approximate fraction of microbes (with properties like the two species studied) viably arriving on Earth out of those ejected from Mars during the period 4 Ga BP to the present time, and during the 700 Ma from 4.5 to 3.8 Ga. Similarly, from Earth to Mars. The conclusion is that if microbes existed or exist on Mars, viable transfer to Earth is not only possible but also highly probable, due to microbes' impressive resistance to the dangers of space transfer and to the dense traffic of billions of martian meteorites which have fallen on Earth since the dawn of our planetary system. Earth-to-Mars transfer is also possible but at a much lower frequency.

Bacillus subtilis↗