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Shading Vita In-ceram YZ substructures: influence on value and chroma, part II.

In this study, the influence of differently shaded substructures made of Y-TZP from different manufacturers (without, with 0.5 mm or 1.0 mm ceramic veneer with Vita VM9 Base Dentin) on the lightness, the saturation, and the color shade (= value, chroma, and hue) was measured and assessed with a spectral photometer (Easy Shade, Vita) on a clinical case in the mouth and on models of different color. Shading substructures made of Y-TZP facilitated adaptation to the basic shade and reduced the layer thickness of the veneer ceramic required to achieve the desired color. This should be done in the future as a matter of routine. In this way, tooth substance can be better conserved when preparing the teeth, and the esthetic result is not diminished. The material used for the production of the working models (plaster or plastic) should be tooth colored and in terms of lightness--analogous to the shading of the substructure--in order to facilitate clinical color measurement and quality control in the laboratory.

Aluminum Oxide↗

Clinical long-term results of VITA In-Ceram Classic crowns and fixed partial dentures: A systematic literature review.

PURPOSE: VITA In-Ceram Classic is a system designed to fabricate all-ceramic crowns and fixed partial dentures (FPDs) with a glass-infiltrated aluminum oxide core material. This systematic literature review gives an overview of the clinical performance of the VITA In-Ceram Classic Alumina, Spinell, and Zirconia restorations. MATERIALS AND METHODS: Based on a systematic literature review, an evidence-based selection and assessment of clinical studies of VITA In-Ceram Classic ceramics was carried out. RESULTS: A total of 299 publications were found, 21 of which met the inclusion criteria. Only a few meaningful studies of In-Ceram Alumina FPDs and In-Ceram Zirconia crowns and FPDs were found. The 5-year survival rate of In-Ceram Alumina crowns and In-Ceram Spinell crowns ranged from 91.7% to 100% and is similar to the survival rate of conventional metal-ceramic crowns. The 5-year survival rate of single-retainer In-Ceram Alumina resin-bonded FPDs (RBFPDs) was 92.3%, which is higher than that of 2-retainer RBFPDs. CONCLUSION: In-Ceram Classic Alumina can be recommended for anterior and posterior crowns as well as for anterior single-retainer RBFPDs. Further studies should be initiated to evaluate in detail the clinical performance of In-Ceram Classic Alumina FPDs. In-Ceram Classic Spinell can be recommended for anterior crowns, especially if highly esthetic results are requested. For In-Ceram Classic Zirconia crowns or FPDs no statement can be made presently because of insufficient data.

Aluminum Oxide↗

The new In-Ceram Spinell system--a case report.

The final color of all-ceramic restorations is mainly dependent on the light-transmission characteristics of the different components of the ceramic material. This article is a report on the improvement in light reflection and light transmission possible with the new In-Ceram Spinell crown system, which provides a natural-looking appearance.

Aluminum Oxide↗

Oxidation of magnesia-supported Pd-clusters leads to the ultimate limit of epitaxy with a catalytic function.

Oxide-supported transition-metal clusters and nanoparticles have attracted significant attention owing to their important role as components of model catalysts, sensors, solar cells and magnetic recording devices. For small clusters, functionality and structure are closely interrelated. However, knowledge of the structure of the bare cluster is insufficient as the interaction with the chemical environment might cause drastic structural changes. Here we show by ab initio simulations based on the density functional theory that the reaction with molecular oxygen transforms small, non-crystalline, magnesia-supported Pd-clusters to crystalline Pd(x)O(y) nano-oxide clusters that are in epitaxy with the underlying support. Restructuring of the Pd backbone is controlled by the electrostatic interaction with magnesia leading to a strong reduction of the O2 dissociation barrier. The supported Pd(x)O(y) clusters are likely to serve as Mars-van Krevelen oxygen reservoirs in catalytic oxidation reactions as observed for PdO overlayers and demonstrated here for the oxidation of CO molecules.

Catalysis↗

Martian soil component in impact glasses in a Martian meteorite.

Chemical compositions of impact melt glass veins, called Lithology C (Lith C) in Martian meteorite EET79001 were determined by electron microprobe analysis. A large enrichment of S, and significant enrichments of Al, Ca, and Na were observed in Lith C glass compared to Lithology A (Lith A). The S enrichment is due to mixing of plagioclase- enriched Lith A material with Martian soil, either prior to or during impact on Mars. A mixture of 87% Lith A, 7% plagioclase, and 6% Martian soil reproduces the average elemental abundances observed in Lith C. Shock melting of such a mixture of plagioclase-enriched, fine-grained Lith A host rock and Martian soil could yield large excesses of S (observed in this study) and Martian atmospheric noble gases (found by Bogard et al., 1983) in Lith C. These mixing proportions can be used to constrain the elemental abundance of phosphorus in Martian soil.

Aluminum Oxide↗

Chemical differences between white and gray mineral trioxide aggregate.

The purpose of this research was to determine and compare the composition of white mineral trioxide aggregate and gray mineral trioxide aggregate. Electron probe microanalysis results indicated that lime (CaO), silica (SiO2), and bismuth oxide (Bi2O3) were the dominant compounds in each case and were present at comparable levels in either of the types of mineral trioxide aggregate analyzed. It was concluded that the most significant differences observed were between the measured concentrations of Al2O3 (+122%), MgO (+130%), and especially FeO (+1000%) when gray mineral trioxide aggregate was compared with white mineral trioxide aggregate.

Aluminum Compounds↗

The contribution of adenine nucleotide loss to ischemia-induced impairment of rat kidney cortex mitochondria.

Adenine nucleotides and respiration were assayed with rat kidney mitochondria depleted of adenine nucleotides by pyrophosphate treatment and by normothermic ischemia, respectively, with the aim of identifying net uptake of ATP as well as elucidating the contribution of adenine nucleotide loss to the ischemic impairment of oxidative phosphorylation. Treatment of rat kidney mitochondria with pyrophosphate caused a loss of adenine nucleotides as well as a decrease of state 3 respiration. After incubation of pyrophosphate-treated mitochondria with ATP, Mg2+ and phosphate, the content of adenine nucleotides increased. We propose that kidney mitochondria possess a mechanism for net uptake of ATP. Restoration of a normal content of matrix adenine nucleotides was related to full recovery of the rate of state 3 respiration. A hyperbolic relationship between the matrix content of adenine nucleotides and the rate of state 3 respiration was observed. Mitochondria isolated from kidneys exposed to normothermic ischemia were characterized by a decrease in the content of adenine nucleotides as well as in state 3 respiration. Incubation of ischemic mitochondria with ATP, Mg2+ and phosphate restored the content of adenine nucleotides to values measured in freshly-isolated mitochondria. State 3 respiration of ischemic mitochondria reloaded with ATP recovered only partially. The rate of state 3 respiration increased by ATP-reloading approached that of uncoupler-stimulated respiration measured with ischemic mitochondria. These findings suggest that the decrease of matrix adenine nucleotides contributes to the impairment of ischemic mitochondria as well as underlining the occurrence of additional molecular changes of respiratory chain limiting the oxidative phosphorylation.

Adenine Nucleotides↗

Preparation and bactericidal property of MgO nanoparticles on gamma-Al2O3.

After being impregnated in the solution containing Mg(NO3)2 x 6H2O, gamma-Al2O3 was dried and calcined at 500 degrees C which results in the production of a bactericide, highly dispersed MgO loaded on the surface of gamma-Al2O3. The threshold value of the monolayer dispersion of MgO on gamma-Al2O3 is 14.97%, and MgO crystal formed when the load amount beyond this value. The samples with different load amount were characterized by X-ray Diffraction (XRD), Low-temperature N2 adsorption-desorption, Inductively Coupled Plasma (ICP) and High Resolution Scan Electronic Microscope (SEM). The results showed that these MgO microcrystals are highly dispersed and have regular size in the range of 4 to 10.8 nm. The specific surface, pore volume and pore size of the sample decreases with the increase of load amount. It is demonstrated that gamma-Al2O3 with highly dispersed MgO on the surface is efficient bactericide, and the one with 20% load amount of MgO can kill more than 99% bacteria and spore cells.

Aluminum Oxide↗

Association of low plasma concentrations of antioxidant vitamins, magnesium and zinc with high body fat per cent measured by bioelectrical impedance analysis in Indian men.

This cross-sectional study was conducted to determine the association of high body fat per cent measured by bioelectric impedance analysis with known risk factors of obesity as well as with serum levels of vitamins, trace elements and magnesium and oxidative stress in an urban population in India. There were 850 men aged 25-64 years, randomly selected from the city of Moradabad. Subjects were divided into high body fat per cent (n = 357), over fat per cent (n = 230), desirable fat (n = 200) and low fat (n = 63) based on criteria of body fat per cent analysis. The prevalence of central obesity, sedentary lifestyle, family history and higher visible fat intake showed significant association with higher over fat per cent. Postprandial plasma insulin and glucose and serum iron and oxidative stress were significantly higher and plasma levels of vitamin C and E and serum zinc/insulin ratio as well as serum magnesium/insulin ratio showed inverse association with high body fat per cent. Multivariate logistic regression analysis after adjustment of age showed a significant positive association of body mass index (odds ratio 0.97), sedentary lifestyle (odds ratio 1.12) and serum iron (OR 1.00) with higher body fat per cent. Zinc (OR 1.03), magnesium (OR 1.02), vitamins C (OR 1.08 and E (OR 1.09) deficiency were risk factors of higher body per cent and central obesity. It is possible that some Indian men can benefit by increased intake of zinc, magnesium, vitamin C and vitamin E in conjunction with lifestyle changes.

Adult↗

Fractographic analyses of three ceramic whole crown restoration failures.

OBJECTIVES: Develop fractographic techniques to perform failure analyses of three ceramic whole-crown clinical failures. METHODS: Three clinical whole-crown failures of different ceramic material systems were studied. The systems included appropriate veneers applied to core materials of cold isostatically pressed alumina, injection molded alumina/alumina-magnesia spinel, and hot pressed lithium disilicate. The surface topography was examined for classical fractographic features, utilizing both optical and scanning electron microscopes independently as well as group examination by four fractographers. RESULTS: All three restorations displayed many common fractographic features, the most important of which was wake hackle. Wake hackle occurs when an approaching crack front sweeps by a small bubble or discontinuity in a brittle material, leaving a trail. The resulting trails can be used to trace back crack progression to an initial starting area. Wake hackle was found to be common in the veneer portions of the crowns, and the strategy of creating a wake hackle map enabled crack paths to be traced from a core area outward in all three restorations. The fracture origin areas were located where hoop stresses are high. Another helpful fracture feature was compression curl, an indication of flexural stress, most visible under low incident optical lighting. SIGNIFICANCE: This study indicates that fractographic analyses can be productively performed on ceramic whole-crown failures. Optical examination under low incident lighting and wake hackle mapping were developed as promising techniques. Hoop stress was implicated as a concern in the three studied specimens, and should be considered when analyzing other whole-crown failures.

Aluminum Oxide↗

Six-year clinical performance of all-ceramic crowns with alumina cores.

PURPOSE: The aim of the study was to evaluate the clinical performance of Procera Alumina AllCeram crowns (Nobel Biocare). MATERIALS AND METHODS: In 70 patients, 61 anterior and 46 posterior teeth were provided with single crowns and cemented with a glass-ionomer cement. RESULTS: Four patients were lost to follow-up. Six crowns had to be removed, all because of nonreparable fracture. At 6 years, the cumulative survival rate was 94.3% for all crowns, 96.7% for anterior crowns, and 91.3% for posterior crowns (survival = not removed). Most of the defects occurred within the first 1.5 years. CONCLUSION: The findings indicate a good clinical prognosis of both anterior and posterior Procera Alumina crowns.

Adult↗

[Long-term clinical results with Procera AllCeram full-ceramic crowns].

The aim of this prospective clinical study was to investigate the long-term survival rate of Procera AllCeram full-ceramic crowns, which were fabricated with aluminiumoxide cores. In 50 patients, 155 Procera crowns with a conventional or reduced core (porcelain collar) were placed on natural abutment teeth. 78% of this group (39 patients with 135 crowns) were examined between May and August 2005 according to the modified USPHS-Criteria. These crowns had been in place for a period of one to 92 months (mean 55 months). Almost half of the crowns were located in the molar region, while 28% were premolars and 24% anterior crowns. Due to one crown fracture the cumulative survival rate was 99% after five and seven years. The clinical success was achieved irrespective of the tooth position, tooth vitality, the preparation margin and the cementum medium used (composite resin or glasionomer cement). In addition, survival was neither influenced by the core design with reduced or conventional margin nor by the core thickness, which measured regularly 0.6 mm in the majority of the specimens. Based on the present findings, it can be concluded that Procera AllCeram is a predictable technique for metal-free, esthetic full-ceramic crowns in the anterior and posterior region.

Adult↗

Effect of luting media on the compressive strengths of two types of all-ceramic crown.

This study evaluated the effect of selected luting media on the compressive strength of two types of all-ceramic crown. Tooth preparation was standardized; each preparation had a shoulder width of approximately 1.2 mm, and all internal preparation angles were rounded. Hi-Ceram and Dicor all-ceramic crowns were fabricated and cemented into the preparations with zinc phosphate, glass-ionomer, or composite resin cement. Coronal compressive fracture strengths were determined, using a set of unrestored teeth as a control. There were no statistically significant differences among the mean compressive strengths of the three luting media, and there was no statistically significant difference between the mean compressive strength of Dicor and that of the natural tooth control.

Aluminum Oxide↗

Fracture strength of copy-milled and conventional In-Ceram crowns.

The purpose of this study was to compare the fracture resistance of copy-milled and conventional In-Ceram crowns. Four groups of 10 uniform sized all-ceramic anterior crowns were fabricated for this test: (1) In-Ceram Spinell (2) In-Ceram Alumina (3) Celay In-Ceram Spinell, and (4) Celay In-Ceram Alumina crowns. All specimens were cemented on stainless steel master die with resin cement and stored in 37 degrees C water for one day prior to loading into a universal testing machine. Using a steel ball at a crosshead speed of 0.5 mm min-1, the crowns were loaded at 30 degrees C angle until catastrophic failure occurred. Mean fracture strength was analysed and compared. Under the conditions of this study and the materials used, the following conclusions were drawn: 1. The strength of Celay In-Ceram anterior crowns had a slightly higher fracture strength than conventional In-Ceram crowns. 2. In-Ceram Alumina crowns had a significantly higher fracture strength than In-Ceram Spinell crowns in both conventional and copy milling methods.

Aluminum Oxide↗