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Ground-state entropies of the Potts antiferromagnet on diamond hierarchical lattices.

The ground-state degeneracies of the q-state Potts antiferromagnet on general diamond hierarchical lattices are computed, for q> or =3, by means of two distinct methods. The first method, denominated the recursive approach, is based on exact recursion relations for the total number of ground states, leading to the exact ground-state entropy in the thermodynamic limit. The second method, called the factorization approach, consists in a simple approximation, where the total number of ground states is factorized as a product of the number of ground states at each hierarchy level. The factorization approach appears to be a poor approximation for small values of q, but its accuracy improves substantially as q increases, and it becomes exact in the limit q--> infinity. In spite of the fact that such a model presents no frustration, a residual entropy at zero temperature is found for all q> or =3. Similarly to what happens on Bravais lattices, the residual entropy approaches its maximum allowed value, ln q, as q increases.

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Mobility spectrum computational analysis using a maximum entropy approach.

A method to calculate a smooth electrical conductivity versus mobility plot ("mobility spectrum") from the classical magnetoconductivity tensor in heterogeneous structures with the help of a "maximum entropy principle" has been developed. In this approach the closeness of the fit and the entropy of the mobility spectrum are optimized. The spectrum is then the most probable one with the least influence of the personal bias of the investigator for any given set of experimental data and is maximally noncommittal with regard to the unmeasured data. The advantages of the maximum entropy mobility spectrum analysis as compared to the conventional mobility spectrum analysis are demonstrated using a synthetic dataset.

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Entropy and bifurcations in a chaotic laser.

We compute bounds on the topological entropy associated with a chaotic attractor of a semiconductor laser with optical injection. We consider the Poincaré return map to a fixed plane, and are able to compute the stable and unstable manifolds of periodic points globally, even though it is impossible to find a plane on which the Poincaré map is globally smoothly defined. In this way, we obtain the information that forms the input of the entropy calculations, and characterize the boundary crisis in which the chaotic attractor is destroyed. This boundary crisis involves a periodic point with negative eigenvalues, and the entropy associated with the chaotic attractor persists in a chaotic saddle after the bifurcation.

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Critique of q-entropy for thermal statistics.

During the past 12 years there have been numerous papers on a relation between entropy and probability which is nonadditive and has a parameter q that depends on the nature of the thermodynamic system under consideration. For q=1 this relation corresponds to the Boltzmann-Gibbs entropy, but for other values of q it is claimed that it leads to a formalism that is consistent with the laws of thermodynamics. However, it is shown here that the joint entropy for systems having different values of q is not defined in this formalism, and consequently fundamental thermodynamic concepts such as temperature and heat exchange cannot be considered for such systems. Moreover, for q not equal 1 the probability distribution for weakly interacting systems does not factor into the product of the probability distribution for the separate systems, leading to spurious correlations and other unphysical consequences, e.g., nonextensive energy, that have been ignored in various applications given in the literature.

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Minimization of the Renyi entropy production in the stationary states of the Brownian process with matched death and birth rates.

We analyze the Fleming-Viot process. The system is confined in a box, whose boundaries act as a sink of Brownian particles. The death rate at the boundaries is matched by the branching (birth) rate in the system and thus the number of particles is kept constant. We show that such a process is described by the Renyi entropy whose production is minimized in the stationary state. The entropy production in this process is a monotonically decreasing function of time irrespective of the initial conditions. The first Laplacian eigenvalue is shown to be equal to the Renyi entropy production in the stationary state. As an example we simulate the process in a two-dimensional box.

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Coarse-grained entropy and information dimension of dynamical systems: The driven Lorentz gas.

We study the resolution dependence of the steady-state saturation values of coarse-grained entropies characterizing general dynamical systems. For dissipative maps they are proportional to the information codimension of the chaotic attractor. Thus, they provide a highly accurate method for determining the information dimension and related characteristics of the dynamical system. This general result is demonstrated for the field-driven Lorentz gas. In the discussion, we take the results on the resolution dependence of the entropy as the starting point to revisit different approaches to define thermodynamic entropy production for transport processes in dynamical systems, and discuss the role of local equilibrium in this enterprise.

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Nonequilibrium stationary states and entropy.

In transformations between nonequilibrium stationary states, entropy might not be a well defined concept. It might be analogous to the "heat content" in transformations in equilibrium which is not well defined either, if they are not isochoric (i.e., do involve mechanical work). Hence we conjecture that in a nonequilibrium stationary state the entropy is just a quantity that can be transferred or created, such as heat in equilibrium, but has no physical meaning as "entropy content" as a property of the system.

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Entropy-induced microphase separation in hard diblock copolymers.

Whereas entropy can induce phase behavior that is as rich as seen in energetic systems, microphase separation remains a very rare phenomenon in entropic systems. In this paper, we present a density functional approach to study the possibility of entropy-driven microphase separation in diblock copolymers. Our model system consists of copolymers composed of freely jointed slender hard rods. The two types of monomeric segments have comparable lengths, but a significantly different diameter, the latter difference providing the driving force for the phase separation. At the same time this system can also exhibit liquid crystalline phases. We treat this system in the appropriate generalization of the Onsager approximation to chain-like particles. Using a linear stability (bifurcation) analysis, we analytically determine the onset of the microseparated and the nematic phases for long chains. We find that for very long chains the microseparated phase always pre-empts the nematic. In the limit of infinitely long chains, the correlations within the chain become Gaussian and the approach becomes exact. This allows us to define a Gaussian limit in which the theory strongly simplifies and the competition between microphase separation and liquid crystal formation can be studied essentially analytically. Our main results are phase diagrams as a function of the remaining model parameters: i.e., the diameter ratio, the length ratio, and the number ratio of the two types of segments. We also determine the amplitude of the inhomogeneous order as a function of position along the chain at the onset of the microphase separation instability. Finally, we give suggestions as to how this type of entropy-induced microphase separation could be observed experimentally.

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Kolmogorov-Sinai entropy for dilute systems of hard particles in equilibrium.

In an equilibrium system, the Kolmogorov-Sinai entropy h(KS) equals the sum of the positive Lyapunov exponents, the exponential rates of divergence of infinitesimal perturbations. Kinetic theory may be used to calculate the Kolmogorov-Sinai entropy for dilute gases of many hard disks or spheres in equilibrium at low number density n. The density expansion of h(KS) is NnuA[ln n + B + O(n)], where nu is the single-particle collision frequency. Previous calculations of A were successful. Calculations of B , however, were unsatisfactory. In this paper, I show how the probability distribution of the stretching factor can be determined from a nonlinear differential equation by an iterative method. From this the Kolmogorov-Sinai entropy follows as the average of the logarithm of the stretching factor per unit time. I calculate approximate values of B and compare these to results from existing simulations. The agreement is good.

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Configurational entropy and its crisis in metastable states: ideal glass transition in a dimer model as a paragidm of a molecular glass.

We discuss the need for discretization to evaluate the configurational entropy in a general model. We also discuss the prescription using restricted partition function formalism to study the stationary limit of metastable states where a more stable equilibrium state exists. We introduce a lattice model of dimers as a paradigm of molecular fluid and study stationary metastability in it to investigate the root cause of glassy behavior. We demonstrate the existence of entropy crisis in metastable states, from which it follows that the entropy crisis is the root cause underlying the ideal glass transition in systems with particles of all sizes. The orientational interactions in the model control the nature of the liquid-liquid transition observed in recent years in molecular glasses.

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The mean-field model Phi4: entropy, analyticity, and configuration space topology.

A large deviation technique is applied to the mean-field model Phi4, providing an exact expression for the configurational entropy s(v,m) as a function of the potential energy v and the magnetization m. Although a continuous phase transition occurs at some critical energy vc, the entropy is found to be a real analytic function in both arguments, and it is only the maximization over m which gives rise to a nonanalyticity in s(v)=supm s(v,m). This mechanism of nonanalyticity-generation by maximization over one variable of a real analytic entropy function is restricted to systems with long-range interactions and has--for continuous phase transitions--the generic occurrence of classical critical exponents as an immediate consequence. Furthermore, this mechanism can provide an explanation why, contradictory to the so-called topological hypothesis, the phase transition in the mean-field model need not be accompanied by a topology change in the family of constant-energy submanifolds.

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Entropy production in the majority-vote model.

We analyzed the entropy production in the majority-vote model by using a mean-field approximation and Monte Carlo simulations. The dynamical rules of the model do not obey detailed balance so that entropy is continuously being produced. This nonequilibrium stochastic model is known to have a critical behavior belonging to the universality class of the equilibrium Ising model. We show that the entropy production exhibits a singularity at the critical point whose exponent is estimated numerically.

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Entropy of seismic electric signals: analysis in natural time under time reversal.

Electric signals have been recently recorded at the Earth's surface with amplitudes appreciably larger than those hitherto reported. Their entropy in natural time is smaller than that of a "uniform" distribution. The same holds for their entropy upon time reversal. Such a behavior, which is also found by numerical simulations in fractional Brownian motion time series and in an on-off intermittency model, stems from infinitely ranged long range temporal correlations and hence these signals are probably seismic electric signal activities (critical dynamics). This classification is strikingly confirmed since three strong nearby earthquakes occurred (which is an extremely unusual fact) after the original submission of the present paper. The entropy fluctuations are found to increase upon approaching bursting, which is reminiscent of the behavior identifying sudden cardiac death individuals when analyzing their electrocardiograms.

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Tachyon condensation and black hole entropy.

String propagation on a cone with deficit angle 2pi(1-1 / N) is considered for the purpose of computing the entropy of a large mass black hole. The entropy computed using the recent results on condensation of twisted-sector tachyons in this theory is found to be in precise agreement with the Bekenstein-Hawking entropy.

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Light sheets and Bekenstein's entropy bound.

From the covariant bound on the entropy of partial light sheets, we derive a version of Bekenstein's bound: S/M<or=pix/ variant Planck's over 2pi, where S, M, and x are the entropy, total mass, and width of any isolated, weakly gravitating system. Because x can be measured along any spatial direction, the bound becomes unexpectedly tight in thin systems. Our result completes the identification of older entropy bounds as special cases of the covariant bound. Thus, light sheets exhibit a connection between information and geometry far more general, but in no respect weaker, than that initially revealed by black hole thermodynamics.

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Universality of entropy scaling in one dimensional gapless models.

We consider critical models in one dimension. We study the ground state in the thermodynamic limit (infinite lattice). We are interested in an entropy of a subsystem. We calculate the entropy of a part of the ground state from a space interval (0,x). At zero temperature it describes the entanglement of the part of the ground state from this interval with the rest of the ground state. We obtain an explicit formula for the entropy of the subsystem at any temperature. At zero temperature our formula reproduces a logarithmic formula, discovered by Vidal, Latorre, Rico, and Kitaev for spin chains. We prove our formula by means of conformal field theory and the second law of thermodynamics. Our formula is universal. We illustrate it for a Bose gas with a delta interaction and for the Hubbard model.

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New universal scaling laws of diffusion and Kolmogorov-Sinai entropy in simple liquids.

A new universal scaling law relating the self-diffusivities of the components of a binary fluid mixture to their excess entropies is derived using mode coupling theory. These scaling laws yield numerical results, for a hard sphere as well as Lennard-Jones fluid mixtures, in excellent agreement with simulation results even at a low density region, where the empirical scaling laws of Dzugutov [Nature (London) 381, 137 (1996)]] and Hoyt, Asta, and Sadigh [Phys. Rev. Lett. 85, 594 (2001)]] fail completely. A new scaling law relating the Kolmogorov-Sinai entropy to the excess entropy is also obtained.

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Entropy, holography, and the second law.

The geometric entropy in quantum field theory is not a Lorentz scalar and has no invariant meaning, while the black hole entropy is invariant. Renormalization of entropy and energy for reduced density matrices may lead to the negative free energy even if no boundary conditions are imposed. The presence of particles outside the horizon of a uniformly accelerated observer prevents the description in terms of a single Unruh temperature.

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