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PubMed2005

Single d-metal atoms on F(s) and F(s+) defects of MgO(001): a theoretical study across the periodic table.

Single d-metal atoms on oxygen defects F(s) and F(s+) of the MgO(001) surface were studied theoretically. We employed an accurate density functional method combined with cluster models, embedded in an elastic polarizable environment, and we applied two gradient-corrected exchange-correlation functionals. In this way, we quantified how 17 metal atoms from groups 6-11 of the periodic table (Cu, Ag, Au; Ni, Pd, Pt; Co, Rh, Ir; Fe, Ru, Os; Mn, Re; and Cr, Mo, W) interact with terrace sites of MgO. We found bonding with F(s) and F(s+) defects to be in general stronger than that with O2- sites, except for Mn-, Re-, and Fe/F(s) complexes. In M/F(s) systems, electron density is accumulated on the metal center in a notable fashion. The binding energy on both kinds of O defects increases from 3d- to 4d- to 5d-atoms of a given group, at variance with the binding energy trend established earlier for the M/O2- complexes, 4d < 3d < 5d. Regarding the evolution of the binding energy along a period, group 7 atoms are slightly destabilized compared to their group 6 congeners in both the F(s) and F(s+) complexes; for later transition elements, the binding energy increases gradually up to group 10 and finally decreases again in group 11, most strongly on the F(s) site. This trend is governed by the negative charge on the adsorbed atoms. We discuss implications for an experimental detection of metal atoms on oxide supports based on computed core-level energies.

Elements↗
PubMed2003

Sequential chemical oxidation and aerobic biodegradation of equivalent carbon number-based hydrocarbon fractions in jet fuel.

Remediation of petroleum mixtures is complicated by the differing environmental degradabilities of hundreds of individual hydrocarbons in the mixtures. By grouping the individual hydrocarbons into a few fractions based on equivalent carbon number (EC), the present study examined the chemical and biological degradation of the fractions. With or without prechemical oxidation (25 days) by three oxidants (KMnO4, H202, MgO2), sterile and live microcosms were constituted with aquifer samples for aerobic biodegradation (134 days) of JP-4 jet fuel. Eighty-seven hydrocarbons were recovered and grouped into nine EC fractions. The apparent removal and actual transformation rate constants were estimated for both chemical and biological degradations. The data show that prechemical oxidations facilitated removal of total petroleum hydrocarbons (TPH) (up to 80%) within shorter times (<50 days) than biological alone. KMnO4 and H202 were better oxidants in terms of mass reduction in shorter times yet to some extent inhibited the subsequent microbial activity. MgO2 was a moderate oxidant with less inhibition of microbial activity. Selective degradation of the EC fractions was observed for both chemical and biological processes. The biological processes were much less effective than the prechemical oxidations in transforming aromatic fractions, the more toxic fractions. The favorable substrates (i.e., aliphatic EC approximately 10) for microbial growth were also those most subject to chemical oxidation. The results suggest that for remediation of petroleum contaminants, sequential chemical and biological technologies may surpass biological alone and more moderate oxidants such as MgO2 may be better candidates. More work is needed on the optimal dose and residence time for applied oxidants and on the application to engineering design and formulation of cleanup standards.

Biodegradation, Environmental↗
PubMed2005

Fracture resistances of cast metal and ceramic dowel and core restorations: a pilot study.

PURPOSE: The purpose of this study was to compare fracture strengths of teeth restored with cast metal and ceramic dowel and cores supporting all-ceramic crowns. MATERIALS AND METHODS: Eighteen recently extracted teeth were randomly divided into 3 equal groups. Metal dowel and cores (MDC) were fabricated for 1 group using a base metal alloy, and served as the control. The other groups received In-Ceram Spinell (ICS) and IPS Empress 2 (IPS) dowel and cores. IPS Empress 1 crowns were fabricated for all samples. Each tooth was subjected to a shear force at a crosshead speed of 2 mm/min on a universal testing machine until failure occurred. RESULTS: The mean fracture strengths and standard deviations of MDC, ICS, and IPS restorations were 1101 N (361), 832 N (288), and 1137 N (367), respectively. The differences between groups were insignificant (p < 0.05). Fractures of the all-ceramic crowns were observed in the MDC group, whereas the failure of ceramic dowel and core restorations was associated with root fracture at the cervical region. CONCLUSIONS: Due to improved mechanical properties, In-Ceram Spinell and IPS Empress 2 ceramic dowel and cores may be candidates for the restoration of endodontically treated anterior teeth.

Aluminum Oxide↗
PubMed2002

Clinical experience with In-Ceram Spinell crowns: 5-year follow-up.

Prompted by increased patient requests for esthetic treatment, restorative clinicians have evaluated a variety of new materials and procedures. This study reports on 5 years' experience with In-Ceram Spinell all-ceramic crowns. A total of 40 anterior crowns were positioned in 13 patients from October 1995 to December 1998. The clinical examination was made following modified California Dental Association/Ryge criteria. Final evaluation was carried out in October 2000, for an observation period of 22 to 60 months (mean 50 months). Only one failure was recorded, and the fractured crown needed to be replaced; according to Kaplan-Meier analysis, the estimated success rate was 97.5%. A thorough description of the clinical procedures through which anterior teeth can be successfully treated with all-ceramic Spinell crowns is described.

Aluminum Oxide↗
PubMed2006

[Fracture resistance of Procera Allceram depending on the framework design--an in vitro study].

Procera AllCeram is one of the all-ceramic systems with an aluminium-oxide core employing CAD/CAM technology. The aim of the current study was to investigate the fracture resistance of Procera AllCeram full-ceramic crowns with a reduced core design compared to the conventional method. In addition, a possible influence of the preparation form (molars or premolars) and the cementation material (glas-ionomer or composite) was analyzed. For both preparation forms, 30 ceramic cores with reduced margins (collarless cores, test) and 30 cores with extended cores (control) were veneered with porcelain in a standardized procedure (total 120 crowns). For the test group, Procera-AllCeram-margin ceramic material was used for the porcelain collar. 40 crowns each were cemented on stainless steel dies with either Ketac-Cem Aplicap or Panavia F. The additional 40 crowns were set on polyurethane dies without cementation and occlusally loaded until fracture occurred. Among the molar crowns, no differences were observed in fracture resistance neither for the different core designs (test or control) nor for the cementation materials. For the premolar form, fusing of a porcelain margin was associated with a reduction in fracture resistance, while the use of composite cement was accompanied with an increase. The present in vitro results indicate that for Procera AllCeram crowns with a highly undulating preparation margin, a conventional core design combined with adhesive cementation is preferable, especially in the posterior region due to higher chewing forces; this assumption needs to be proven in clinical studies.

Aluminum Oxide↗
PubMed1997

Reinforcement of acrylic resins for provisional fixed restorations. Part II: Changes in mechanical properties as a function of time and physical properties.

In Part I, it was found that (i) 2 vol.% admixture of reinforcing elements in PMMA (Jet) resin matrix had a significant beneficial effects on the mechanical properties, and (ii) among these, zirconia exhibited the greatest improvements in modulus of elasticity, transverse strength, toughness, and hardness number. Using the best combination (i.e., PMMA resin matrix and 2 vol.% ZrO2), exothermic temperature raise and polymerization shrinkage were further investigated. Deterioration in mechanical properties due to prolonged water sorption were also studied for 5 weeks. The following can be concluded: (1) By increasing liquid/powder ratio for PMMA control samples, the peak temperature occurrence was retarded by 3 min and raised by 8 degrees C. (2) The effect of admixed oxide particles to PMMA resin matrix or the heat generated during polymerization was not significant. (3) The polymerization volumetric shrinkage was influenced by the a mixture of particles, with increases as large as 0.9% (or 0.3% in linear shrinkage). (4) PMMA resin admixed with 2 vol.% of zirconia particles showed a continuous weight gain due to water sorption, mechanical properties appears to be increasing up to 1-week sorption, followed by rapid drop of all properties. (5) Autopolymerizing acrylic resins are a resin-resin composite material of pre-polymerized beads embedded in a newly formed acrylic matrix. The main fracture modality appears to occur through the matrix and at the interface, although some trans-beads fractures were identified. (6) It was suggested that incorporating certain type of oxide particles into the pre-polymerized beads would provide stronger resin matrix.

Acrylic Resins↗
PubMed1994

Cholesterol oxides in plasma and lipoproteins of magnesium-deficient rabbits and effects of their lipoproteins on endothelial barrier function.

The cholesterol oxide (ChO) levels in the plasma and low density lipoproteins (LDL and VLDL) in four groups of rabbits fed for seven weeks either normal (NC) or high cholesterol (HC) with low or normal magnesium (Mg) diets were determined and compared with the NC group fed a standard rabbit diet. The plasma from the NC group contained low levels of different cholesterol oxides. These cholesterol oxides were significantly elevated in the plasma of rabbits fed a HC-normal magnesium or a HC-low magnesium diet. In the NC-low Mg group, 7 alpha-hydroxycholesterol, 7 beta-hydroxycholesterol and 7-ketocholesterol were elevated while the other cholesterol oxides remained within the normal range of the NC group. When the cholesterol oxides were assayed in the LDL and VLDL fractions as micrograms/mg protein, the fractions obtained from the groups fed NC-low Mg, HC-normal Mg or HC-low Mg diets showed higher levels of cholesterol oxides than the fractions obtained from the NC group. When LDL and VLDL fractions from the different groups were incubated at equal protein concentration with confluent endothelial cell monolayers, transendothelial albumin transfer was significantly increased by the lipoproteins from the experimental groups as compared to the control group. These results suggest that elevation of cholesterol oxides in magnesium deficiency or hypercholesterolaemia may be related to their atherogenic effects through decreasing the endothelial barrier function which could enhance the deposition of cholesterol rich lipoproteins into the arterial wall.

Animal Feed↗
PubMed1993

Preliminary study of the relationship between plasma and erythrocyte magnesium variations and some circulating pro-oxidant and antioxidant indices in a standardized physical effort.

The aim of this preliminary study was to determine the relationship between exercise, magnesium (Mg) status, oxidative stress, and antioxidant defence systems. Some corresponding indices have been evaluated: plasma Mg, ascorbate, uric acid, adrenaline, creatine kinase (CK), thiobarbiturate reactive substances, adrenochrome; and in erythrocytes (RBC): reduced and oxidized glutathione (GSH and GSSG) and Mg. Venous blood samples were withdrawn before and 3 min after completion of a 40 min run. Only two significant changes were observed after effort: plasma Mg decreased (P < 0.009) and plasma adrenaline increased (P < 0.005). There was a non-significant tendency for indices of oxidative stress and antioxidant capacity to increase. The significant correlations between plasma Mg and CK (r = -0.88) and between RBC Mg and plasma ascorbate (r = -0.76) disappeared after the effort. Further research is necessary, with a larger number of subjects and variables, to obtain a better understanding of these interactions.

Adult↗
PubMedDate not supplied

The effect of tooth preparation height and diameter on the resistance of complete crowns to fatigue loading.

This study investigated the relationship between tooth preparation height and diameter and the resistance of cemented crowns to dynamic loading. Crown and abutment analogs were cemented using zinc oxide-eugenol, zinc phosphate, glass-ionomer, and resin composite luting agents. Abutment height varied from 1 to 7 mm in increments of 1 mm. Diameters of 3, 4, 5, 6, 7, and 8 mm were tested. A testing apparatus designed to apply dynamic stresses was used. The cemented crowns were loaded until the cement bond failed or the components reached 1 million stress cycles. The staircase technique was applied for data analysis. The results showed that: (1) the relationship between abutment height (or diameter) and resistance to dynamic lateral loading is approximately linear; and (2) crowns luted using resin composite cement were more resistant than those placed using glass-ionomer cement, which in turn were more resistant than crowns cemented with zinc phosphate or zinc oxide-eugenol cements.

Cementation↗
PubMed2006

Effect of core and veneer thicknesses on the color parameters of two all-ceramic systems.

STATEMENT OF PROBLEM: Specific contributions of the core and the veneer thickness on the appearance of layered disk specimens are not well characterized. PURPOSE: This study examined the effect of varying core and veneer thickness on the color parameters of layered disk specimens made of 2 ceramic systems. MATERIAL AND METHODS: Disk specimens 16 mm in diameter with core/veneer thickness (mm) of 0.8/0.2 (baseline), 0.8/0.7, 0.8/1.2, 1.0/0.5, 1.3/0.2, and 1.8/0.2 were made from a leucite-reinforced ceramic (IPS Empress; 2B shade), and thickness (mm) of 0.5/0.5 (baseline), 0.5/1.0, 0.5/1.5, 0.8/0.7, 1.0/0.5, and 1.5/0.5 were made from a glass-infiltrated spinell ceramic (In-Ceram Spinell; A2 shade). Color parameters L*, a*, and b* of CIELAB color space were measured against a neutral gray background with a tri-stimulus colorimeter, and deltaE between disk group and its respective baseline group was calculated. Analysis of variance was used to determine the effect of material and core and veneer thickness on the color parameters (alpha = .05). RESULTS: Increasing the total disk thickness resulted in decrease of L* (P < .001) and an increase of a* (P < .001), b* (P < .001), and deltaE (P = .0236). For leucite-reinforced ceramic, the core thickness, veneer thickness, and their interaction exhibited significant influence on the mean values of a* and b* (P < .0028) but not on the mean values of L*. For spinell ceramic, the core thickness and veneer thickness exhibited significant influence on the mean values of L* and b* (P < .0272) but not on a*; the interaction demonstrated significant influence on b* (P = .0003) but not on L* and a*. CONCLUSION: The color appearance of the layered ceramic disk specimens is strongly influenced not only by the core thickness and veneer thickness, but also by their interaction.

Aluminum Oxide↗
PubMed2006

[Long-term clinical results of VITA In-Ceram Classic: a systematic review].

VITA In-Ceram Classic is a system to fabricate all-ceramic crowns and fixed partial dentures (FPDs) with a glass-infiltrated aluminium oxide core material. This systematic review gives an overview of the clinical performance of the In-Ceram Classic types Alumina, Spinell and Zirconia. Based on a systematic literature research, an evidence-based selection and assessment of clinical studies of In-Ceram Classic ceramics was carried out. A total of 294 publications were found, 21 of which conformed to the inclusion criteria. Only few meaningful studies of In-Ceram Alumina FPDs and In-Ceram Zirconia crowns and FPDs were found. The Five-year survival rate of In-Ceram Alumina crowns and In-Ceram Spinell crowns ranging from 91.7% to 100% is similar to the survival rate of conventional metal-ceramic crowns. The Five-year survival rate of single-retainer In-Ceram Alumina resin-bonded fixed partial dentures (RBFPDs) was 92.3%, and thus higher than that of two-retainer RBFPDs. In-Ceram Classic Alumina can be recommended for anterior and posterior crowns as well as for anterior single-retainer RBFPDs. In-Ceram Classic Spinell can be recommended for anterior crowns. Further studies have to be initiated in order to evaluate in detail the clinical performance of VITA In-Ceram Classic.

Aluminum Oxide↗
PubMed2004

[Effect of hyperthyreosis on the concentration of antioxidative vitamins and microelements].

In the course of hyperthyreosis reactive oxygen production increases and oxidative stress develops. The consequences of oxidative stress comprise disturbances in balance of pro- and antioxidative agents, including changes in concentration of antioxidative vitamins and microelements. Although the results of published studies concerning changes of concentrations of vitamins and microelements in hyperthyreosis are contradictory, most frequently a decrease of zinc and magnesium concentrations was observed.

Antioxidants↗
PubMed2002

Arsenic(III) oxidation and arsenic(V) adsorption reactions on synthetic birnessite.

The oxidation of arsenite (As(III)) by manganese oxide is an important reaction in both the natural cycling of As and the development of remediation technology for lowering the concentration of dissolved As(III) in drinking water. This study used both a conventional stirred reaction apparatus and extended X-ray absorption fine structure (EXAFS) spectroscopy to investigate the reactions of As(III) and As(V) with synthetic birnessite (MnO2). Stirred reactor experiments indicate that As(III) is oxidized by MnO2 followed by the adsorption of the As(V) reaction product on the MnO2 solid phase. The As(V)-Mn interatomic distance determined by EXAFS analysis for both As(III)- and As(V)-treated MnO2 was 3.22 A, giving evidence for the formation of As(V) adsorption complexes on MnO2 crystallite surfaces. The most likely As(V)-MnO2 complex is a bidentate binuclear corner sharing (bridged) complex occurring at MnO2 crystallite edges and interlayer domains. In the As(III)-treated MnO2 systems, reductive dissolution of the MnO2 solid during the oxidation of As(III) caused an increase in the adsorption of As(V) when compared with As(V)-treated MnO2. This suggested that As(III) oxidation caused a surface alteration, creating fresh reaction sites for As(V) on MnO2 surfaces.

Absorptiometry, Photon↗