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Characterization and hardening of concrete with ultrasonic testing.

In this study, we describe a technique which can be used to characterize some relevant properties of 26 cylindrical samples (15 x 30 cm2) of concrete. The characterization has been performed, according to Spanish regulations in force, by some destructive and ultrasound-based techniques using frequencies of 40 kHz. Samples were manufactured using different water/cement ratios (w/c), ranging from 0.48 to 0.80, in order to simulate different values of compressive strength at each sample. We have correlated the propagation velocity v of ultrasonic waves through the samples to compressive strength R values. As some other authors remark, there exists an exponential relationship between the two above parameters. We have found that a highly linear relationship is present between R and w/c concentration at the samples. Nevertheless, when the same linear model is adopted to describe the relationship between v and w/c, the value of r decreases significantly. Thus, we have performed a multiple regression analysis which takes into account the impact of different concrete constituents (water, cement, sand, etc.) on ultrasound propagation speed. One of the most relevant practical issues addressed in our study is the estimation of the hardening curve of concrete, which can be used to quantify the viability of applying the proposed method in a real scenario. Subsequently, we also show a detailed analysis of the temporal evolution of v and R through 61 days, beginning at the date where the samples were manufactured. After analyzing both parameters separately, a double reciprocal relationship is deduced. Using the above parameters, we develop an NDE-based model which can be used to estimate hardening time of concrete samples.

Journal Article↗

Effect of retention grooves on fracture strength of Class 2 composite resin and amalgam restorations.

The effect of approximal retention grooves on fracture strengths of class 2 composite resin and amalgam restorations was tested in vitro. Results indicated that retention grooves significantly improved (P less than 0.05) the compressive strength of amalgam restorations (38.6% stronger). For posterior composite resin restorations, there was no significant difference in mean compressive strength of restorations in preparations with and without retention grooves.

Composite Resins↗

[Effects of bone morphogenetic protein and transforming growth fractor-beta on biomechanical property for fracture healing in rabbit ulna].

OBJECTIVE: To investigate the effects of exogenous bone morphogenetic protein (BMP) and transforming growth factor-beta (TGF-beta) on biomechanical property for ulna of fracture healing. METHODS: Thirty-six adult rabbits were made the model of right ulnar fracture and treated locally with TGF-beta/PLA, BMP/PLA, TGF-beta + BMP/PLA or PLA (as control group). Fracture healing was evaluated by measurement of the mechanical parameters and geometric parameters. RESULTS: As compared with control group, the geometric parameters, the bending broken load, the ultimate bending strength, the bending elastic modulus, the ultimate flexural strength, the flexural elastic modulus, the ultimate compressing strength, the compressing elastic modulus, and the ultimate tensile strength for ulna of fracture healing increased significantly in the treatment groups(P < 0.01). These parameters were higher in TGF-beta + BMP/PLA group than in TGF-beta/PLA group or in BMP/PLA group and in TGF-beta/PLA group than in BMP/PLA group(P < 0.05). There was no significant difference in bone density between the treatment groups and control group. CONCLUSION: Local application of exogenous TGF-beta and BMP can increase the callus formation and enhance biomechanical strength of bone after fracture healing. A combination of TGF-beta and BMP has synergetic effect in enhancing fracture healing.

Animals↗

Intervertebral disc degeneration can predispose to anterior vertebral fractures in the thoracolumbar spine.

UNLABELLED: Mechanical experiments on cadaveric thoracolumbar spine specimens showed that intervertebral disc degeneration was associated with reduced loading of the anterior vertebral body in upright postures. Reduced load bearing corresponded to locally reduced BMD and inferior trabecular architecture as measured by histomorphometry. Flexed postures concentrated loading on the weakened anterior vertebral body, leading to compressive failure at reduced load. INTRODUCTION: Osteoporotic fractures are usually attributed to age-related hormonal changes and inactivity. However, why should the anterior vertebral body be affected so often? We hypothesized that degenerative changes in the adjacent intervertebral discs can alter load bearing by the anterior vertebral body in a manner that makes it vulnerable to fracture. MATERIALS AND METHODS: Forty-one thoracolumbar spine "motion segments" (two vertebrae and the intervertebral disc) were obtained from cadavers 62-94 years of age. Specimens were loaded to simulate upright standing and flexed postures. A pressure transducer was used to measure the distribution of compressive "stress" inside the disc, and stress data were used to calculate how compressive loading was distributed between the anterior and posterior halves of the vertebral body and the neural arch. The compressive strength of each specimen was measured in flexed posture. Regional volumetric BMD and histomorphometric parameters were measured. RESULTS: In the upright posture, compressive load bearing by the neural arch increased with disc degeneration, averaging 63 +/- 22% (SD) of applied load in specimens with severely degenerated discs. In these specimens, the anterior half of the vertebral body resisted only 10 +/- 8%. The anterior third of the vertebral body had a 20% lower trabecular volume fraction, 16% fewer trabeculae, and 28% greater intertrabecular spacing compared with the posterior third (p < 0.001). In the flexed posture, flexion transferred 53-59% of compressive load bearing to the anterior half of the vertebral body, regardless of disc degeneration. Compressive strength measured in this posture was proportional to BMD in the anterior vertebral body (r2 = 0.51, p < 0.001) and inversely proportional to neural arch load bearing in the upright posture (r2 = 0.28, p < 0.001). CONCLUSIONS: Disc degeneration transfers compressive load bearing from the anterior vertebral body to the neural arch in upright postures, reducing BMD and trabecular architecture anteriorly. This predisposes to anterior fracture when the spine is flexed.

Aged↗

Metallic aluminum in MSWI fly ash: quantification and influence on the properties of cement-based products.

This article focuses on the effects of metallic aluminum contained in municipal solid waste incineration (MSWI) fly ashes on cement-based materials in which they are added. The ash under study was treated by an industrial physicochemical process of neutralization. The paper also presents a method to quantify the metallic aluminum content of ash: it consists in measuring the amount of hydrogen gas produced by the oxidation reaction of metallic aluminum. This method is simple and fast. Results show that studied ash contains an appreciable amount of metallic aluminum. Investigations were carried out to study the incorporation of the ash in concrete: in this case, the presence of metallic aluminum is worrying because it could be responsible for disorders in concrete. In fact, swellings are observed on cement pastes and mortars containing ash during the first 24 h of hydration. A test based on hydrostatic weighing permits to quantify the swelling of fresh cement paste and to study the evolution of this swelling. Causes of swelling are analyzed. Results show that ettringite formation occurs after the end of the expansion reaction. So it can be concluded that metallic aluminum is the sole responsible for the observed swelling. Consequences of swelling are also analyzed by measuring compressive strength of ash-containing mortars: this swelling leads to cracks in the mortars and significant decrease of their compressive strength.

Aluminum↗

Light-cured lining materials: a laboratory study.

OBJECTIVES: The purpose of this study was to compare seven light-cured lining materials (four glass ionomer and three non-glass ionomer), with a chemical-cured glass ionomer lining material. METHODS: Specimens were prepared and tested according to the methods prescribed in Australian/International Standards for compressive strength, diametral tensile strength, depth of cure, radiopacity, and acid erosion. Other tests were adhesion to dentin and adhesion to resin composite. RESULTS: Compressive strengths ranged from 48.6 MPa to 307.1 MPa, and diametral tensile strengths from 5.8 MPa to 34.8 MPa. Most of the light-cured materials were stronger than the chemical-cured glass ionomer. Depth of cure increased with increased irradiation times, with values of 0.63 mm to 6.43 mm for 60 s irradiation. Radiopacity was in the range of 0.91 mm Al to 1.07 mm Al. All materials were unaffected or only slightly affected by acid erosion. Adhesion to dentin was effectively zero for the non-glass-ionomer products. Adhesion to composite was from 6.23 MPa to 25.1 MPa, and thermocycling affected only three light-cured and the one chemical-cured glass ionomer. SIGNIFICANCE: All products complied with the requirements of standards, where available. Incremental placement and curing is necessary for some products. Adhesion to dentin is better with glass ionomers, whereas their adhesion to composite may be unreliable.

Acrylic Resins↗

The mechanical properties of breast prostheses.

The mechanical properties of inflatable and gel-filled breast prostheses were evaluated using the Instron Universal Testing Machine. Prosthesis strength characteristics were evaluated in terms of compression strength (rather than tensile strength) because of the relationship to closed capsulotomy. The compression breaking strength of prostheses ranged from 0.62 to 10.8 pounds per square inch. There was considerable variation among prostheses. Pressures exceeding these values have been recorded during closed compression capsulotomy. The clinical relevance of these results is discussed.

Breast↗

Prediction of mechanical properties of the human calcaneus by broadband ultrasonic attenuation.

Broadband ultrasonic attenuation (dB MHz cm-1, nBUA) was determined for specimens from 20 human calcanei, along with apparent density, elasticity (Young's modulus), and compressive strength. The calcanei were modified to provide "whole" (only soft tissue removed), "core" (mediolateral cores corresponding to in vivo measurement region), "can" (cortical end plates removed from core), and "def" (core defatted) samples. The nBUA values for the various modifications were highly correlated. The presence of the cortical endplates creates a significant nBUA, probably due to complex phase interactions. nBUAcan was a good predictor of elasticity (R2 = 75.7%) and strength (R2 = 73.6%). Apparent density was a better predictor of the mechanical variables than nBUA, with R2 values of 88.5% for elasticity and 87.6% for strength. The morphological anisotropy defined by "fabric" for the specimens was extremely uniform. The coefficient of variation in nBUA (40.5%) and compressive strength (64.4%) was significantly greater than for apparent density (23.5%) and fabric (6.7%). It is well known that a power law relationship exists between apparent density and elasticity or strength in cancellous bone. An interesting finding in this work is that there also appears to be a power law relationship between nBUA and apparent density, with an exponent of approximately 2, which, in the light of clinical implications, warrants further investigation.

Aged↗

[Physical and mechanical properties of the thermosetting resin for crown and bridge cured by micro-wave heating].

A heating method using micro-waves was utilized to obtain strong thermosetting resin for crown and bridge. The physical and mechanical properties of the thermosetting resin were examined. The resin was cured in a shorter time by the micro-waves heating method than by the conventional heat curing method and the working time was reduced markedly. The base resins of the thermosetting resin for crown and bridge for the micro-waves heating method were 2 PA and diluent 3 G. A compounding volume of 30 wt% for diluent 3 G was considered good the results of compressive strength, bending strength and diametral tensile strength. Grams of 200-230 of the filler compounded to the base resins of 2 PA-3 G system provided optimal compressive strength, bending strength and diametral tensile strength. A filler gram of 230 provided optimal hardness and curing shrinkage rate, the coefficient of thermal expansion became smaller with the increase of the compounding volume of the filler. The trial thermosetting resin for crown and bridge formed by the micro-waves heating method was not inferior to the conventional resin by the heat curing method or the light curing method.

Crowns↗

Some mechanical properties of goose femoral cortical bone.

The ultimate compressive strength and modulus of elasticity of femoral cortical bone from adult geese (Anser anser), were determined by sex and by quadrant by compressing small right circular cylinders which were 2.4 mm in height and 0.8 mm in diameter. The average ultimate compressive strength was 183 +/- 29 MPa. The average modulus of elasticity was 13.2 +/- 3.4 GPa. The bending strength and bending modulus of elasticity were determined by a three point bend test on rectangular prisms which had the approximate dimensions 0.75 mm X 0.75 mm X 25 mm. The average bending strength was 263 +/- 44 MPa while the average bending modulus was 19.6 +/- 3.1 GPa. The calcium content was determined by atomic absorption spectrophotometry and no correlation was found with the mechanical properties. The histology of the cortical bone was examined both quantitatively and qualitatively. A unique type of Haversian bone is described. Goose bone was found to be morphologically similar to adolescent human bone and to have mechanical properties similar to those of adult human bone.

Animals↗

Bone-muscle strength indices for the human lower leg.

This cross-sectional study is based on images from the lower leg as assessed by peripheral quantitative computer tomography (pQCT). Measurements were performed in 39 female and 38 male control subjects and 15 female professional volleyball players, all between 18 and 30 years of age. The images were obtained at shank levels of 4%, 14%, 33%, and 66% from the distal end. Bone and muscle cross-sectional areas, and the bones' density-weighted area moment of resistance and of inertia were assessed. From these, muscle-bone strength indices (MBSIs) were developed for compression (CI = 100. bone area/muscle area) and bending (BI = 100. bone area moment of resistance/muscle area/tibia length). Significant correlations between muscle cross-sectional area and bone were found at all section levels investigated. The strongest correlation for compression was observed in the sections at 14% (correlation coefficient r = 0.74), where 4.10 +/- 0.46 cm(2) bone, on average, was related to 100 cm(2) muscle. The compression index (CI) at the 14% level was independent of the tibia length. Interestingly, the 15 athletes had significantly greater CIs than the control subjects. This is most probably due to the greater tension development in the athletes. The highest correlation for bending was for anteroposterior bending at 33% of tibia length (r = 0.81), where the area moment of resistance, R, was on, average, 4.21 +/- 0.54 cm(3)/100 cm(2) muscle/m tibia length. Analysis of the bones' area moment of inertia showed that buckling is a possible cause of bending at the 33% and 66% levels, but not at the 14% level. No gender differences in MBSI were found. Likewise, age was without significant effect. The data show that bone architecture depends critically on muscle cross section and tension development. Moreover, bone geometry (e.g., the tibia length) influences the geometrical distribution of bone mineral, as it was found that long bones adapted to the same compressive strength are wider than short ones. We conclude that MBSIs offer a powerful diagnostic tool for bone disorders and may contribute to improving the treatment of bone metabolic and other diseases.

Absorptiometry, Photon↗

[Visible light cured resin. Chronological change in mechanical properties of matrix resin immersed in MeOH].

Monomer composition was examined to improve durability of matrix resin of visible light cured composite resin. As a monomer, five kinds of cyclophosphazene monomers, two kinds of commercial monomers and a mixture of commercial monomers were prepared to the visible light cured resins. The mechanical properties of these set products were examined with time after immersion in MeOH, an aging accelerating solvent. Compressive strength of the resins using cyclophosphazene monomers tended to decrease with time, but it increased in accordance with the increase of the number of polymerization group. Compressive strength of the resins using commercial monomers tended to decrease, but that using the BMPEPP monomer tended to increase with time. Yield point of the resins with the cyclophosphazene monomer 4 PN-(EMA)8 tended to increase with the time but that of the resins with other cases monomers decreased. The yield point of all three resins made using commercial monomers tended to decrease with time, but the rate of decrease was small for BMPEPP monomer. Compressive elastic modulus of the resins using cyclophosphazene monomers tended to increase with time when the number of polymerization group was 6-8, while it decreased when the number was 4-5. When commercial monomers were used, it tended to decrease with time, but the rate of decrease was small for the BMPEPP monomer. Transverse strength of the resins using cyclophosphazene monomers showed a tendency to decrease with time. When a commercial monomer was used, cracks appeared in the Bis-GMA+Tri-EDMA monomer after 7 days, and with the other two monomers, the transverse strength tended to decrease with time, though the rate of decrease was small for the BMPEPP monomer. Transverse elastic modulus tended to decrease with time, but the rate of decrease was small for the BMPEPP monomer.

Composite Resins↗

Mechanical properties of poly(methyl methacrylate) bone cements.

Samples of low viscosity poly(methyl methacrylate) (PMMA), graphite reinforced PMMA, and graphite reinforced low viscosity PMMA were evaluated for their compression strength and fracture toughness. These results were compared with two currently used plain PMMA bone cements. There were no statistically significant differences in compression strength between the five cements. Graphite reinforcement of plain cement produced a 32% increase in fracture toughness over plain cement. Graphite reinforcement of low viscosity cement also produced a significant increase in toughness (31%) over low viscosity cement with fiber reinforcement. However, low viscosity cement demonstrated significantly less fracture toughness than plain PMMA.

Analysis of Variance↗

Studies on the setting of polyelectrolyte cements: part VI. The effect of halide salts on the mechanical properties and water balance of zinc polycarboxylate and glass-ionomer dental cements.

A study is reported in which a zinc polycarboxylate and a glass polyalkenoate dental cement, respectively, were prepared from aqueous solutions of NaCl, KCl, KBr and KI, all at 1 mol dm3 concentration, as well as from pure water. For the zinc polycarboxylate, setting as determined by oscillating rheometry was speeded up and water uptake was enhanced by the presence of the salts. Conversely, compressive strength at 24 h was unaffected. On the other hand, for the glass polyalkenoate, the setting reaction was slowed down, water uptake inhibited and compressive strength at 24 h reduced (from 94.3 MPa with pure water to 59.8 MPa with NaCl, 65.8 MPa for KCl, 67.0 MPa for KBr and 81.1 MPa for KI). Previous work with polyelectrolytes in aqueous solution suggests that the halides probably enhance the rate of the neutralization process. For the zinc polycarboxylate, this leads to a more rapid setting reaction. By contrast, for the glass polyalkenoate, it results in slower setting and weaker cements. This result is attributed to inhibition of the secondary setting reaction, involving the formation of the silicate/phosphate network, by enhanced neutralization, a process which is consequently concluded to occur earlier in the overall setting of these cements than had been assumed previously.

Journal Article↗

Injectable acrylic bone cements for vertebroplasty with improved properties.

Currently commercially available acrylic bone cements lack adequate radiopacity and viscosity when they are used in percutaneous vertebroplasty (PVP). In this work improved formulations of radiopaque and injectable poly(methyl methacrylate) bone cements were prepared with different amounts (10-50 wt.%) of BaTiO3 or SrTiO3 particles as the radiopaque agent. Two sets of cements were prepared by using untreated or silanated radiopaque particles, respectively. The influence of the content and nature of the radiopaque agent as well as its silanation with 3-(trimethoxysilyl) propyl methacrylate (gamma-MPS), on the curing parameters, residual monomer content, radiopacity, mechanical properties, and injectability of the resulting materials, was examined. Doughing and setting times, maximum temperature, and compressive strength of all formulations fulfilled the requirements of standard specifications, with values of peak temperature in the range 57-72 degrees C and those of compressive strength between 114 and 135 MPa. Formulations containing at least 20 wt.% BaTiO3 or SrTiO3 had radiopacities equal to or greater than that corresponding to 2 mm of Al as required for surgical plastics. Injectability of any of the formulations provided 75-80 wt.% of the total mass manually injected through a conventional biopsy needle 4 min after mixing. Silanation of the BaTiO3 or SrTiO3 particles led to formulations with improved mechanical properties and injectability compared to those obtained with the untreated fillers.

Barium Compounds↗

The mechanical stability of barium titanate (ceramic) implants in vitro.

Dense, polycrystalline barium titanate (BaTiO3) specimens showed a modulus of rupture of 85.5 +/- 9.0 MPa and a compressive strength of 486 +/- 75 MPa. These values are considerable higher than those which had been previously reported. In addition, there was no significant drop in compressive strength after in vitro aging for 4 weeks in saline solution.

Barium↗

Dental application of binary urethane monomer mixtures:strengthened resin matrix.

The strengthened resin matrices in six experimental binary visible light-cured (VLC) urethane monomer mixtures were examined in terms of mechanical strength. A 60 wt% bis-GMA/40 wt% binary monomer mixture was used as a control sample. A dry state (1 day in air at 37 degrees C) and a wet state by immersion in distilled water (7 and 30 days at 37 degrees C) were investigated. The compressive strength and diametral tensile strength of urethane monomer samples had values equivalent to, or greater than those of a control sample in the dry state, but had increased values in the wet state. The nano-indentation hardness values in experimental urethane monomer mixtures were greater than that in a control sample in the dry state, showing that immersion in water gave increased strength (maximum increase was about 2.5 times) in six binary urethane monomer mixtures. The compressive strength of the samples in the dry and wet states exhibited linearly increasing elastic modulus values for the resin matrix in the range about 50 to 2600 MPa. The toughened resin matrix had smaller amounts of residual monomer in the urethane monomer mixtures (0.41 to 5.03 wt%) compared with that of the binary 60bis-GMA/40TEGDMA mixture (0.71 to 6.26 wt%). This study has revealed that resin matrices are strengthened by the use of four-functional urethane monomers in experimental binary urethane monomer mixtures.

Journal Article↗

Seating accuracy and fracture strength of vented and nonvented ceramic crowns luted with three cements.

Methods to facilitate the seating of artificial crowns can improve the gingival margins and ensure longevity. This study examined the effects of venting and different luting agents on the seating accuracy and compressive strength of Dicor ceramic crowns. Vented and unaltered anterior restorations were tested using zinc phosphate cement (ZnPO4), glass ionomer, and composite resin cement. Rexillium metal dies of a tooth preparation of a maxillary canine were provided and standardized crowns were fabricated. The artificial crowns were evaluated for adaptation of the finish line before and after cementation, then were compressively loaded to failure. Under the conditions of this study, neither the design of the artificial crown nor the luting agent had a significant effect on the compressive strength. Composite resinous cement appeared to enhance seating of the crown, whereas ZnPO4 cement inhibited seating.

Cementation↗