Cristobalite contents of airborne respirable dust in the diatomaceous earth industry in California.
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Air Pollutants, Occupational↗
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Case study: inorganic pollutants associated with particulate matter from an area near a petrochemical plant.
The area of Gela (Sicily, Italy) contains one of the largest petroleum refineries in Europe and also has several oil fields both on land and offshore. This paper discusses how the oil refinery and traffic-related air pollution affect the chemical composition of airborne particulate matter over the town of Gela, using pine needles and urban road dust as the means of survey. Forty-one samples of pine needles from Pinus halepensis (Mill.) and two composite samples of roadway dust, each subdivided into six size fractions, were analyzed for major and trace elements. Information on the natural or anthropogenic origin of the observed heavy metals was deduced from factor analysis and element distribution maps. Factor analysis was applied to a data set of 20 element concentrations in pine needles and identified three main sources of metals: soil, vehicle traffic, and industrial emissions. The petrochemical plant appears to be associated with raised levels of As, Mo, Ni, S, Se, V, and Zn. Similarly, enhanced Cu, Pb, Pt, Pd, Sb, and partly Zn concentrations are closely associated with traffic. High correlations between Ni and V, As and Se, and Pb and Sb were observed. Element distribution maps, showing a decrease in heavy metal contents immediately farther inland, confirm that local sources play a considerable role in heavy metal pollution. Morphological alterations and accumulation of phenols were observed in sections of Pinus halepensis needles collected from sites with high traffic density and industrial emissions.
Air Pollutants↗
[Hygienic problems of industrialized regions of Far North and priorities of scientific research for their solution].
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Arctic Regions↗
Wheat flour allergy: an entire diagnostic tool for complex allergy.
Wheat proteins are involved in respiratory allergy, contact allergy and food allergy. Wheat allergens involve in these pathologies are well-known. However, establishment of wheat allergy diagnostic can be sometimes difficult on account of the complex allergenic composition of skin prick test (SPT) solutions of wheat flour. Therefore, we have studied specific IgE reactivity from patient sera with wheat food allergy, and characterized allergenic composition of wheat SPT solutions by specific antibodies directed to wheat allergens. The results showed that 20 of the 25 sera analyzed contained specific IgE to at least one wheat protein fraction. Among positive sera, 75% have specific IgE to water/salt soluble fraction, 85% to native gluten fractions and 65% to wheat isolate fraction. The results showed also that SPT solutions of wheat flour contained major food allergens from each allergenic fraction. These results highlighted the importance of using fractions, which constitute the whole wheat allergenic pattern, during specific IgE reactivity analyses. Moreover, we have observed that wheat isolate extract (results of food industrial process) contained not only modified allergens (neo-allergens) involve of specific food allergy to wheat isolate but also some native allergens involve in wheat food allergy. Thus, these results showed the importance to use, for wheat in vivo diagnosis together wheat SPT solutions (gluten extract and wheat isolate) in order to differentiate wheat food allergy to specific wheat isolate allergy.
Allergens↗
Applying the lessons of high risk industries to health care.
High risk industries such as commercial aviation and the oil and gas industry have achieved exemplary safety performance. This paper reviews how they have managed to do that. The primary reasons are the positive attitudes towards safety and the operation of effective formal safety management systems. The safety culture provides an important explanation of why such organisations perform well. An evolutionary model of safety culture is provided in which there is a range of cultures from the pathological through the reactive to the calculative. Later, the proactive culture can evolve towards the generative organisation, an alternative description of the high reliability organisation. The current status of health care is reviewed, arguing that it has a much higher level of accidents and has a reactive culture, lagging behind both high risk industries studied in both attitude and systematic management of patient risks.
Accidents, Occupational↗
Exposures in the alumina and primary aluminium industry: an historical review.
We reviewed specific chemical exposures and exposure assessment methods relating to published and unpublished epidemiological studies in the alumina and primary aluminium industry. Our focus was to review limitations in the current literature and make recommendations for future research. Although some of the exposures in the smelting of aluminium have been well characterised, particularly in potrooms, little has been published regarding the exposures in bauxite mining and alumina refining. Past epidemiological studies in the industry have concentrated on the smelting of aluminium, with many limitations in the methodology used in their exposure assessment. We found that in aluminium smelting, exposures to fluorides, coal tar pitch volatiles (CTPV) and sulfur dioxide (SO2) have tended to decrease in recent years, but insufficient information exists for the other known exposures. Although excess cancers have been found among workers in the smelting of aluminium, the exposure assessment methods in future studies need to be improved to better characterise possible causative agents. The small number of cohort studies has been a factor in the failure to identify clear exposure-response relationships for respiratory diseases. A dose-response relationship has been recently described for fluoride exposure and bronchial hyper-responsiveness, but whether fluorides are the causative agent, co-agent or simply markers for the causative agent(s) for potroom asthma, remains to be determined. Published epidemiological studies and quantitative exposure data for bauxite mining and alumina refining are virtually non-existent. Determination of possible exposure-response relationships for this part of the industry through improved exposure assessment methods should be the focus of future studies.
Aluminum↗
[Reporting of occupational hearing loss in the Norwegian offshore industry 1992-2003].
BACKGROUND: Our aim was to analyse the incidence of reported occupational hearing loss in the Norwegian offshore industry over the period 1992 to 2003. This industry has for many years focused on noise as a risk factor, and workers are regularly screened for hearing loss. MATERIALS AND METHODS: In 1992 the Petroleum Safety Authority in Norway established a reporting system for occupationally related diseases in the petroleum industry. The information gained might be helpful in preventing occupational hearing loss. A descriptive analysis of this register is presented. RESULTS: Hearing loss and musculoskeletal disorders were the most frequently reported work-related diseases. A total of 1709 cases of occupational hearing loss were reported from 1992 through 2003. The incidence of reported hearing loss varied, from 1 per 1000 in 1992 to 9 per 1000 in 2002. Most cases were found in the age group 50 to 59 years. The largest number of reported hearing losses was found among mechanics, painters and building structure cleaners, electricians, process technicians, and roughnecks. INTERPRETATION: The reported number of occupational hearing loss among workers in the Norwegian offshore industry in the period 1992 to 2003 shows that hearing loss is an important health challenge. Control measures are still needed. Continuous improvement in the reporting system and further research on risk factors and control measures should be discussed.
Extraction and Processing Industry↗
[Hygienic assessment of new technology of tank cars].
A washing and steaming station built by Finnish specialists in 1997 operates at the Ryazan petroleum processing plant. The process is completely automatic and hermetic, excludes the workers' contact with harmful industrial factors. There is a whole set of special clothes and individual protective means. The plant's gas-fighting and rescue service monitors the air environment every 3 months. There is a closed rinsing water regeneration system at the plant.
Environmental Monitoring↗
[The impact of industrial factors of oil processing plant on serum lipoproteins].
The study covered serum lipoproteins in workers engaged into production of higher fatty alcohols at oil-processing plant. The industrial factors appeared to induce changes in serum lipoproteins composition: lower share of High Density Lipoproteins and higher share of Very Low Density Lipoproteins. On the background of cardiovascular and gastrointestinal diseases, the occupational hazards may precipitate and aggravate alterations of serum lipoproteins composition in the workers.
Adult↗
Process for isolation of cardanol from technical cashew (Anacardium occidentale L.) nut shell liquid.
Commercially available technical cashew (Anacardium occidentale L.) nut shell liquid (CNSL) contains mainly cardanol (decarboxylated anacardic acid) and cardol. Cardanol, the monophenolic component of technical CNSL, is widely used as a synthon for the preparation of a number of polymers and agricultural products. This paper describes the separation of cardanol from toxic cardol. Technical CNSL was dissolved in a mixture of methanol and ammonium hydroxide (8:5) and extracted with hexane to obtain cardanol. The resultant methanolic ammonia layer was extracted with a mixture of ethyl acetate and hexane to yield cardol. This is the first industrially feasible process based on solvent extractions for the isolation of cardanol from technical CNSL.
Acetates↗
Offshore safety case approach and formal safety assessment of ships.
PROBLEM: Tragic marine and offshore accidents have caused serious consequences including loss of lives, loss of property, and damage of the environment. METHOD: A proactive, risk-based "goal setting" regime is introduced to the marine and offshore industries to increase the level of safety. DISCUSSION: To maximize marine and offshore safety, risks need to be modeled and safety-based decisions need to be made in a logical and confident way. Risk modeling and decision-making tools need to be developed and applied in a practical environment. SUMMARY: This paper describes both the offshore safety case approach and formal safety assessment of ships in detail with particular reference to the design aspects. The current practices and the latest development in safety assessment in both the marine and offshore industries are described. The relationship between the offshore safety case approach and formal ship safety assessment is described and discussed. Three examples are used to demonstrate both the offshore safety case approach and formal ship safety assessment. The study of risk criteria in marine and offshore safety assessment is carried out. The recommendations on further work required are given. IMPACT ON INDUSTRY: This paper gives safety engineers in the marine and offshore industries an overview of the offshore safety case approach and formal ship safety assessment. The significance of moving toward a risk-based "goal setting" regime is given.
Decision Making↗
Workplace risk factors for cancer in the German rubber industry: Part 1. Mortality from respiratory cancers.
OBJECTIVES: To determine the cancer specific mortality by work area among active and retired male workers in the German rubber industry. METHODS: A cohort of 11,663 male German workers was followed up for mortality from 1 January 1981 to 31 December 1991. Cohort members were classified as active (n = 7536) or retired (n = 4127) as of 1 January 1981 and had been employed for at least one year in one of five study plants producing tyres or technical rubber goods. Work histories were reconstructed with routinely documented "cost centre codes" which were classified into six categories: I preparation of materials; II production of technical rubber goods; III production of tyres; IV storage and dispatch; V maintenance; and VI others. Standardised mortality ratios (SMRs) adjusted for age and calendar year and 95% confidence intervals (95% CIs), stratified by work area (employment in respective work area for at least one year) and time related variables (year of hire, lagged years of employment in work area), were calculated from national reference rates. RESULTS: SMRs for laryngeal cancer were highest in work area I (SMR 253; 95% CI 93 to 551) and were significant among workers who were employed for > 10 years in this work area (SMR 330; 95% CI 107 to 779). Increased mortality rates from lung cancer were identified in work areas I (SMR 162; 95% CI 129 to 202), II (SMR 134; 95% CI 109 to 163), and V (SMR 131; 95% CI 102 to 167). Mortality from pleural cancer was increased in all six work areas, and significant excesses were found in work areas I (SMR 448; 95% CI 122 to 1146), II (SMR 505; 95% CI 202 to 1040), and V (SMR 554; 95% CI 179 to 1290). CONCLUSION: A causal relation between the excess of pleural cancer and exposure to asbestos among rubber workers is plausible and likely. In this study, the pattern of excess of lung cancer parallels the pattern of excess of pleural cancer. This points to asbestos as one risk factor for the excess deaths from lung cancer among rubber workers. The study provides further evidence for an increased mortality from laryngeal cancer among workers in the rubber industry, particularly in work area I.
Adult↗
[Cancer mortality among rubber industry workers in São Paulo, Brazil].
OBJECTIVE: To investigate cancer deaths among rubber industry workers according to company size. METHODS: This historical cohort study included 9,188 male workers, engaged as members of a workers' union in São Paulo, Southeastern Brazil, between 1975 and 1985, alive in January 1990 and followed until the end of 2000. Overall and specific cancer deaths were compared within the cohort, with subjects stratified according to company size and economic activity, sector of work, and worker qualification. Risk set assessment and conditional logistic regression were used to estimate relative risks, adjusted for age, time since first job, and duration of employment in the rubber industry. RESULTS: When compared to employees of larger companies, workers employed in small companies showed greater risk of death due to any type of cancer (RR=2.33, 95% CI: 0.90-6.03), stomach tumors (RR=3.47; 95% CI: 2.57-4.67), and upper aero-digestive tract tumors (RR=2.49; 95% CI: 1.78-3.48). Risk of death was greater among workers employed in maintenance (RR=2.23; 95% CI: 0.73-6.76); expedition, storage and transportation (RR=2.97; 95% CI: 0.77-11.38); and production (RR=3.51; 95% CI: 1.07-11.57), when compared to workers engaged in clerical work and support activities. CONCLUSIONS: Our results provide further evidence for an increased risk of stomach and upper aero-digestive tract tumors--and possibly of all types of cancer--among rubber industry workers employed in small companies when compared to employees of larger companies.
Adolescent↗
Burden of coronary heart disease on the Iranian oil industry (1999-2000).
To estimate the direct cost of coronary heart disease (CHD) to the Iranian oil industry, we calculated the cost of essential services for 1253 CHD patients admitted to the National Iranian Oil Corporation (NIOC) Central Hospital. The direct cost of CHD at the Hospital was 10940 million rials (US$ 1 = 8000 rials), or 8.7 million rials per patient. The direct cost of CHD to the Iranian oil industry was estimated at 22 770 million rials. Working days lost to workers hospitalized for CHD amounted to 62 832. The heavy burden of CHD on the Iranian oil industry necessitates the introduction of an industry-wide prevention programme.
Absenteeism↗
Microbiologically influenced corrosion in petroleum product pipelines--a review.
Microbiologically influenced corrosion is responsible for most of the internal corrosion problems in oil transportation pipelines and storage tanks. One problematic area in treating gas lines is the occurrence of the stratification of water in the line. Under these conditions, corrosion inhibitors do not come into contact properly and oil and inhibitors undergo degradation. The role of bacteria on oil degradation, the consequences of oil degradation in fuel systems and its influence on corrosion have been explained in detail. Besides, factors influencing on degradation of oil and corrosion inhibitors have also been discussed. Mechanism of microbiologically influenced corrosion in oil pipeline has been explained. Many of the misapplication of biocides/inhibitors occur mainly because the characteristics of biocides/inhibitors are not considered before use in pipeline industry. List of biocides and monitoring programme have been collected from literature and presented.
Bacteria↗
[Free radical lipid peroxidation in workers of oil processing industry].
Free radical lipid peroxidation in erythrocytes, plasma, and urine was studied in workers engaged in oil processing industry. The examinees were divided into 3 groups with different intensity of exposure to chemical factors: 1) 21 workers without contacts with chemicals; 2) 28 workers handling chemicals 2-3 times a weeks (risk group); 3) 46 workers permanently exposed to chemicals for 3-5 years. Control group consisted of 40 workers occupationally not exposed to chemicals. Free radical lipid peroxidation in erythrocytes, plasma, and urine was intensified in groups 2 and more so in group 3.
Adult↗
[Are sleep difficulties in night work a problem for the offshore industry?].
BACKGROUND: Shift work is increasingly used in industry and services; in the Norwegian offshore industry approximately 6750 employees work night shifts. We wanted to look into the implications of night shifts on sleep and circadian rhythm, with particularly focus on the offshore sector. MATERIAL AND METHODS: We conducted literature searches on Medline, covering the period from 1966 to 2003; only eight studies pertaining to the offshore activity in the North Sea with emphasis on sleep and night work were identified. RESULTS: Night shifts on oil platforms were associated with sleeping difficulties. The isolated setting on the installations in the North Sea probably facilitates biological adaptation to night work compared to work onshore. Light therapy has a documented effect for re-adaptation to normal daytime functioning upon returning home. INTERPRETATION: Night work disturbs sleep. The level of functioning during the first night shifts is probably lower than the optimal level of functioning. Only a few studies of adaptation to night work in the offshore industry have been conducted and little research has been done concerning swing shifts in the North Sea. The field is obviously in need of more empirically based knowledge.
Adaptation, Physiological↗
Occupational exposures to polycyclic aromatic hydrocarbons, and respiratory and urinary tract cancers: a quantitative review to 2005.
BACKGROUND: Exposure to polycyclic aromatic hydrocarbons (PAHs) has been reported in several industries, including those of the aluminum production, coal gasification, coke production, iron and steel foundries, coal tar and related products, carbon black and carbon electrodes production. PATIENTS AND METHODS: This paper reviews the results from cohort studies conducted on workers exposed to PAHs in these industries, with a focus on cancers of the respiratory and urinary tract. RESULTS: An excess risk from lung/respiratory cancers was found in most industries, the pooled relative risk (RR) being 2.58 (95% CI 2.28-2.92) for coal gasification, 1.58 (95% CI 1.47-1.69) for coke production, 1.40 (95% CI 1.31-1.49) for iron and steel foundries, 1.51 (95% CI 1.28-1.78) for roofers and 1.30 (95% CI 1.06-1.59) for carbon black production. The evidence for cancers of the bladder and of the urinary system is less consistent, with a significant increased risk only for workers in aluminum production (pooled RR = 1.29, 95% CI 1.12-1.49), coal gasification (pooled RR = 2.39, 95% CI 1.36-4.21), and iron and steel foundries (pooled RR = 1.29, 95% CI 1.06-1.57). CONCLUSIONS: Increased risks from lung and bladder cancers were found in PAH-related occupations. These were modest in most industries, apart from those for coal gasification, and whether they are due at least partially to some bias or confounding remains open to discussion.
Air Pollutants, Occupational↗