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PubMed2002

[Study and application of flow injection liquid-liquid extraction non-aqueous media mercury reduction atomic fluorescence spectrometry].

A new method for on-line solvent extraction covalent hydride generation in a non-aqueous media was proposed. Flow injection techniques were used to develop an efficient on-line solvent extraction pre-concentration and pre-separation system. The hydride generation is carried out in an aliquot of metal-complex extraction solution by sodium tetrahydroborate(III) in N,N-dimethyl formamide solution and anhydrons acetic acid. Hg is extracted by KI + HNO3 + (NH2)2CS into TBP and hydride generation by proposed method. A improved u-type gas-liguid separator was used. The working conditions and manifolds scheme of flow injection had been optimized. The method is applied to the determination of mercury in GSD-4 and GSD-6 geological reference materials with good accuracy and precision.

Borohydrides↗
PubMed2001

[Direct determination of selenium and bismuth in antimony and antimony compound by hydride generation-atomic fluorescence spectrometry].

The interference of Sb in determination of Se and Bi in antimony powder and antimony compound has been studied in different acidity, it is found that the interference of antimony has been reduced apparently in high acidity. Simultaneously, according to the difference of hydride generation reaction between Sb5+ and Sb3+, a sensitive and rapid method has been developed and used to determine Se and Bi in real samples. The recovery of the method is 95%-105% for practical samples. Detection limits are 0.00004 x 10(-2) (content) for Se and 0.0001 x 10(-2) mg.L-1 (content) for Bi respectively. The relative standard deviations of Se are 2.4% (content = 0.00169 x 10(-2) mg.L-1) and 5.4% (content = 0.00056 x 10(-2) mg.L-1). The relative standard deviations of Bi are 5.0% (content = 0.00024 x 10(-2) mg.L-1) and 1.3% (content = 0.00229 x 10(-2) mg.L-1). The method has been applied to determination of Se and Bi in practical samples with satisfactory results.

Antimony↗
PubMed2001

[Determination of trace Sn in geosamples by flow injection on-line co-precipitation hydride generation atomic fluorescence spectrometry].

It is reported that a FI on-line co-precipitation technique for the pre-concentration of trace amount of Sn with the precipitate of Mg(OH)2 as carrier is hyphenated with AFS determination. The co-precipitation is carried out in NaOH medium and the precipitate is collected in a precipitation collector. The precipitate is then dissolved by HCl and reacted with NaBH4, the hydride is transferred directly into the atomizer. The relative standard deviation is 5.15% for 10 determinations of 30 ng.mL-1 Sn and the detection limit of 0.21 ng.g-1 is obtained. The developed method has been applied to the determination of trace Sn in geosamples with satisfactory results.

Chemical Precipitation↗