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PubMed1996

Applications of laser scanning microscopy for analysis of aquatic microhabitats.

Laser scanning microscopy was used 1) to analyze Mn oxide-encrusted biofilms and particles in marine Mn-oxidizing enrichment cultures, 2) to optimize fluorescence in situ hybridization protocols of 16S ribosomal RNA-targeted oligonucleotide signature probes for single bacterial cell identification in particles from a wetland, and 3) to develop a combined immunofluorescence-microautoradiography procedure for analysis of the distribution of 14C-labeled organic compounds and 14C-mineralizing bacteria in groundwater seep sediments. The results demonstrated the wide applicability and benefits of using laser scanning microscopy for analysis of complex microbial assemblages.

Animals↗
PubMed1992

Use of luting agents with an implant system: Part I.

When removal of the provisionally cemented superstructure from a cemented abutment becomes necessary, the retentive strengths of the abutment/fixture and superstructure/abutment luting agents become important considerations. This study compared the retentive strengths of castings cemented to machined titanium implant abutments and to a human premolar with three provisional luting agents. Also tested were the retentive strengths of cast noble metal implant abutments cemented into titanium fixtures with three permanent luting agents both dry and after storage in 0.9% physiologic saline for 30 days at 37 degrees C. No significant differences (alpha < 0.05) were noted in retentive values between the cemented castings on the titanium abutments and the natural tooth. The Temp Bond zinc oxide-eugenol luting agent exhibited a lower mean retentive strength than the IRM reinforced zinc oxide-eugenol and Life calcium hydroxide luting agents. Ketac Cem glass-ionomer cemented abutments that were stored in saline exhibited a significantly higher mean retentive strength than abutments cemented with either Core Paste or Resiment resin luting agents. On the basis of results from this study, it may be concluded that superstructures provisionally cemented with Temp Bond, IRM, or Life luting agents may be removed from implant abutments without disturbing the abutment/fixture or implant bond.

Analysis of Variance↗
PubMed2000

Introduction of thiol-reactive structures on to soluble and insoluble proteins.

When proteins containing disulphide groups were oxidized with magnesium monoperoxyphthalate at acidic pH, they acquired the property of binding thiol compounds. This was the case with the insoluble protein keratin, chosen for having a large number of disulphide bridges, and with soluble ones like BSA and immunoglobulins. The potential applications of some of these modified proteins for the preparation of soluble bioconjugates have been explored. As a particular example of an application, the immobilization of activated IgG on to solid phases might provide a new way for preparing immunoadsorbents.

Amino Acids↗
PubMed2002

High yield of pure multiwalled carbon nanotubes from the catalytic decomposition of acetylene on in-situ formed cobalt nanoparticles.

For the first time, multiwalled carbon nanotubes (MWNTs) could be formed selectively in a high yield, free of any disordered carbon by-product, from the catalytic decomposition of acetylene at 600 degrees C on a CoxMg(1-x)O solid solution. Starting from 1 g of catalytic substrate, 4 g of pure MWNTs were obtained after its dissolution in boiling concentrated HCl, without any additional purification in strongly oxidizing medium, as is required for other methods of nanotube production. In situ reduction of CoO by dihydrogen liberated from acetylene decomposition allows highly divided metal particles to be continuously produced as synthesis proceeds. This is undoubtedly the reason for the good performance of the catalyst and for the ability to produce nanotubes in a narrow diameter range, namely from 10 to 15 nm. With the use of acetylene instead of methane, the synthesis proceeds at low temperature, which prevents the growth of carbon shells, in which the metal particles are generally embedded, decreasing their activity. Because of the very low specific surface area of the catalyst support, the amount of disordered carbon by-product formed is negligible.

Acetylene↗
PubMed2004

Giant room-temperature magnetoresistance in single-crystal Fe/MgO/Fe magnetic tunnel junctions.

The tunnel magnetoresistance (TMR) effect in magnetic tunnel junctions (MTJs) is the key to developing magnetoresistive random-access-memory (MRAM), magnetic sensors and novel programmable logic devices. Conventional MTJs with an amorphous aluminium oxide tunnel barrier, which have been extensively studied for device applications, exhibit a magnetoresistance ratio up to 70% at room temperature. This low magnetoresistance seriously limits the feasibility of spintronics devices. Here, we report a giant MR ratio up to 180% at room temperature in single-crystal Fe/MgO/Fe MTJs. The origin of this enormous TMR effect is coherent spin-polarized tunnelling, where the symmetry of electron wave functions plays an important role. Moreover, we observed that their tunnel magnetoresistance oscillates as a function of tunnel barrier thickness, indicating that coherency of wave functions is conserved across the tunnel barrier. The coherent TMR effect is a key to making spintronic devices with novel quantum-mechanical functions, and to developing gigabit-scale MRAM.

Computers↗
PubMed2002

Removal of exhausted oils by adsorption on mixed Ca and Mg oxides.

Adsorption tests were performed on two different exhausted oils to reduce their polluting and health hazard potential: a "water-insoluble oil", utilised for automotive engine lubrication, and an "emulsified" oil, used as coolant for metal-cutting tools. Dolomite, a low-cost recovery material, was used to prepare two effective adsorbents: (a) a mixed Ca and Mg oxide obtained by thermal decomposition of dolomite at 1800 degrees C, and (b) an activated material obtained by submitting this product to chemical treatment with HCl. Preliminary tests carried out with an excess of the former material showed that the insoluble oil was adsorbed with lower yield (Y = 0.40) than the soluble (emulsified) oil (Y = 0.60). The material activation with HCl remarkably improved the adsorption of soluble oil organic fraction (Y > 0.90), while only a little increase in the removal yield was observed for the insoluble oil (Y = 0.44). The results presented and discussed in this work pointed out that the products of dolomite calcination can successfully replace the conventional adsorbing materials in the removal of organic pollutants, with particular concern to exhausted soluble oils, which cannot usually be recycled, thus reducing the operational costs of their treatment.

Adsorption↗
PubMed2003

Preconcentration of radium isotopes from natural waters using MnO2 Resin.

We have characterized "MnO2 Resin," a new resin developed by the PG Research Foundation, for radium adsorption over wide ranges of pH, reaction times and salt concentrations. We show that the sorption of 133Ba (used as a proxy for Ra) is highly dependent on pH with the most useful range from pH 4 to 8. The surface layers of the Mn oxides apparently become more positively charged under acidic conditions (below pH 4), which prevents diffusion of positively charged alkaline earth species (e.g. Ba2+, Ra2+) into the sorption sites. Adsorption at higher pH is thought to be inhibited because of carbonate complexation. We found that the sorption characteristics for radium onto MnO2 Resin are especially favorable for low-salinity waters but the sorption is still very satisfactory for highly salted solutions (KD=2.8x10(4) in both cases) but with slower kinetics. For analytical purposes, both column and pump experiments showed high recoveries with no measurable discrimination between Ra and Ba regardless of flow rates in fresh water. Seawater tests showed that recoveries of Ra and Ba are lower than fresh water at elevated flow rates with Ra adsorption higher than Ba at flow rates above 10 ml/min.

Barium Radioisotopes↗
PubMed2006

Charge transfers at metal/oxide interfaces: a DFT study of formation of K delta+ and Au delta- species on MgO/Ag(100) ultra-thin films from deposition of neutral atoms.

Ultra-thin oxide films grown on a metal substrate and of thickness smaller than 1 nm may exhibit unusual properties with respect to thicker films or single crystal oxide surfaces. In a previous study [G. Pacchioni, L. Giordano and M. Baistrocchi, Phys. Rev. Lett., 2005, 94, 226104] we have suggested that a Au atom adsorbed on a MgO/Mo(100) thin film becomes negatively charged by direct electron tunneling from the Mo metal and that this is related to the low MgO/Mo(100) work function. Here we show, based on periodic DFT supercell calculations, that charge transfer can occur also in the opposite direction by adsorption of electropositive K atoms on MgO/Ag(100) films. We predict the occurrence of a charge transfer also for Au on MgO/Ag(100) films despite the fact that here the work function is 1 eV larger than in MgO/Mo(100). The formation of a layer of adsorbed negative (Au delta-/MgO/Ag) or positive (K delta+/MgO/Ag) adsorbates results in an increase or decrease, respectively, of the MgO/Ag(100) work function as predicted by the classical Gurney model for ionic adsorbates on metal surfaces.

Computer Simulation↗
PubMed2005

Short-term retentive values of zirconium oxide posts cemented with glass ionomer and resin cement: an in vitro study and a case report.

OBJECTIVE: This paper presents the results of an investigation focusing on the retention of all-ceramic posts. The aim of the study was to evaluate the influence of two luting agents--a glass-ionomer cement (Ketac Cem) and a resin cement (Panavia F)--on the retention of a prefabricated ceramic post (Cerapost) after different pretreatment techniques in vitro. METHOD AND MATERIALS: Forty freshly extracted incisors and canines were treated endodontically. The root canals were filled with laterally condensed gutta-percha and sealer. The teeth were assigned to 1 of 4 groups, each containing 10 specimens: sandblasted/nonsandblasted post cemented with glass-ionomer cement and sandblasted/nonsandblasted post cemented with resin cement. Tensile tests were carried out. The specimens were also quantitatively analyzed under a scanning electron microscope. RESULTS: The retentive strengths of posts, sandblasted and nonsandblasted, and cemented with Panavia F resin cement, were significantly increased as compared to those cemented with Ketac Cem. CONCLUSION: Both the luting agent and the post-surface pretreatment had a significant influence on the retention of the ceramic post.

Adult↗
PubMedDate not supplied

The effect of recementation on crown retention.

PURPOSE: The object of this study was to evaluate retention of complete cast crowns cemented with different luting cements and to determine whether recemented castings are as retentive as when initially placed. MATERIALS AND METHODS: Thirty standardized Rexillium III complete crowns were made on extracted human molar teeth prepared with a modified milling machine using conventional laboratory techniques. The crowns were randomly assigned into three groups according to the luting cement used: zinc phosphate (Fleck's, Mizzy), adhesive resin (Panavia-EX, J. Morita), and glassionomer (Ketac-Cem, Aplicap, ESPE-Premier Sales). Retention was evaluated by measuring the tensile force required to dislodge the crowns from tooth preparations with an Instron testing machine after thermocycling (1,500 cycles between 5 degrees C and 55 degrees C with 1-minute dwell times). Subsequently, the tooth preparations were scraped clean and polished with flour of pumice (prophylaxis paste), and the fitting surfaces of the artificial crowns were ultrasonically cleaned and air abraded using 50-micron aluminum oxide powder prior to recementation. Results were subjected to two-way analysis of variance and Tukey's Studentized Range test. RESULTS: The analysis showed the highest mean retention for cast crowns cemented with Panavia-EX cement (314 N), but the difference was not statistically significantly different from crowns cemented with glass-ionomer cement (307 N). However, crowns cemented with zinc phosphate cement (233 N) had significantly lower values (P < 0.05). Restorations recemented with zinc phosphate had significantly lower retention (190 N) than their initial cementation (P < 0.05). CONCLUSIONS: Panavia-EX and glass-ionomer cements yielded the highest initial and recementation retentive strength, with values almost 32% higher than those obtained with zinc phosphate cement during the initial cementation and 59% higher than zinc phosphate for recementation. Zinc phosphate cement exhibited significantly lower retention for the initial and second trial of cementation.

Analysis of Variance↗
PubMed2005

Growth mechanism and ultraviolet-light emission of the self-assembled complex of MgO nanostructures.

Bulk-quantity net-like nanodendrites and four-fold hierarchical nanostructures were synthesized by direct thermal evaporation and oxidation of metallic Mg powder. Their formation mechanism is explained using the self-catalytic vapor-liquid-solid mechanism together with dendritic-crystal epitaxial growth mechanism. Four-branch and eight-branch nanodendrites were also detected. The photoluminescence spectrum reveals that the peak with the maximum intensity is centered at about 3.16 eV (392 nm). Through Gaussian fitting, a strong and narrow ultraviolet-light emission peak centered at 3.16 eV (392 nm) and a relatively weak but broad blue-light emission band centered at 2.74 eV (453 nm) were observed in the photoluminescence emission spectrum, which are respectively attributed to the recombination luminescence of the F+ and F centers (belonging to oxygen-vacancy related defect levels) in the MgO nanostructures. In addition, another very weak and broad red-infrared emission band can also be detected, which is probably due to the relaxation luminescence of impurity levels in the MgO nanostructures.

Crystallization↗
PubMed2006

Use of magnesia for boron removal from irrigation water.

The risk of B phytotoxicity due to high levels of B in irrigation water can be avoided by removing B from the water, before its use, through adsorption on certain adsorbents, such as magnesia (industrial MgO), if the latter can be proven to be an effective and easy to handle means for B removal. In addition, if such a material is applied as a fertilizer after its use and the adsorbed B is easily released into the soil solution, B phytotoxicity could constitute a potential hazard. The objectives of this work were to: (a) establish the optimum working conditions (equilibration time, solution to adsorbent ratio, and particle size of the adsorbent) for B adsorption, (b) assess the magnitude of B adsorption by magnesia, both in capacity and intensity terms, as well as the influence of temperature, (c) study B desorbability from magnesia, spiked with B at two rates, 5 and 0.5 mg g(-1), and (d) compare the results from b and c to those obtained using reagent grade MgO. The results showed that the time to achieve equilibrium depended on the B concentration of the external solution and ranged from 6 h (for B </= 10 mg L(-1)) to 48 h (for B >/= 50 mg L(-1)). The percentage of B adsorbed decreased as the volume of external solution to adsorbent increased and a working ratio of 50:1 was selected. For magnesia, B adsorption was particle size dependent with the smallest fraction (<0.1 mm) sorbing more B than the other three fractions studied (0.1-1.0, 1.1-2.0, 2.1-4.0 mm). Boron adsorption was conducted under strongly alkaline pH (10.3 +/- 0.2 and 10.4 +/- 0.1 for the reagent and magnesia, respectively) and increased with temperature. Both adsorbents exhibited a high B adsorption capacity (Langmuir maximum values were 5.85 +/- 0.39 and 4.45 +/- 1.31 mg B g(-1) for the reagent and magnesia, respectively) comparable to other metal oxides. However, the reagent grade MgO seemed to be superior to magnesia in terms of capacity and strength of B retention. This superiority of the reagent was attributed to its greater surface area (34.7 compared with 5.8 m(2) g(-1) for magnesia) and to its conversion to Mg(OH)(2) during the adsorption process, whereas magnesia remained unaltered, as was evident from X-ray diffractograms. Based on this data, magnesia seems to be an effective means for removing excess B from irrigation water, particularly if a material of fine particle size is used. Boron desorbability after 240 h of desorption time was more pronounced for magnesia reaching up to 55 and 60% of the amount of B added, at the spiked rates of 5 and 0.5 mg g(-1), respectively. Although these figures indicate that approximately half of the amount of B added remained adsorbed, they cannot be easily extrapolated to field conditions, and if B-laden magnesia is applied to soils, the possibility of B phytotoxicity cannot be excluded.

Adsorption↗
PubMed2005

Novel method for titanium crown casting using a combination of wax patterns fabricated by a CAD/CAM system and a non-expanded investment.

OBJECTIVES: For titanium casting, most commercial investments for titanium recommend casting at a low mold temperature to reduce oxidation. However, the thermal expansion values of the molds at low casting temperatures may be insufficient. The purpose of the current study was to investigate the possibility of obtaining accurate titanium crown casts using wax pattern fabricated by a CAD/CAM system with a non-expanded mold. METHODS: Three types of experimental magnesia-based investments (A, B and C) were made and their properties were evaluated for dental use. Two kinds of wax patterns for full-coverage coping crowns (S-0: cement space of 0 microm; S-20: cement space of 20 microm) were fabricated using a commercial CAD/CAM system. A traditional method (TM) using inlay wax was performed for comparison. The investment for titanium casting was decided from the fundamental data of experimental investments. Titanium crowns were replaced on the stone die and the thickness of the cement layer was evaluated. RESULTS: There were no significant differences for the setting time and setting expansion among the experimental investments, but the aluminous cement content played a role in hardening and contracting the mold. The fit of the titanium crowns differed significantly between the TM and the CAD/CAM system. The ranges of thickness obtained from the TM, S-0 and S-20 were 20.78-357.88 microm, 25.12-107.46 microm and 17.84-58.92 microm, respectively. SIGNIFICANCE: High quality titanium crown casting was obtained using a combination of wax patterns fabricated by a CAD/CAM system and a non-expanded MgO-based investment.

Analysis of Variance↗
PubMedDate not supplied

Marginal adaptation of 1 fiber-reinforced composite and 2 all-ceramic inlay fixed partial denture systems.

PURPOSE: The aim of this in vitro study was to evaluate the marginal adaptation and retention of inlay fixed partial dentures (IFPDs) made with 1 fiber-reinforced composite and 2 different ceramic materials using quantitative scanning electron microscope analysis after thermal cycling and mechanical loading, which simulated approximately 5 years of oral service. MATERIALS AND METHODS: Eighteen IFPDs made with fiber-reinforced composite (SR Adoro/Vectris), zirconium oxide-TZP (Cercon), and magnesia partially stabilized zirconia (DC-Leolux) covered with silica-based ceramics were tested in this study. The specimens were mechanically loaded in the vestibular cusp of the pontic element in a computer-controlled masticator with 1,200,000 half-sinusoid mechanical cycles of maximum 49 N each at a frequency of 1.7 Hz. A total of 3,000 thermocycles at 5 degrees C and 55 degrees C, 2 minutes each, were performed simultaneously. The marginal adaptation was analyzed at the interface of the luting composite and the abutment inlay/onlay (CI) and at the interface of the tooth and the luting composite (TC). RESULTS: The percentages of continuous margin at the CI interface were 94.6 +/- 3.1 and 88 +/- 6.7 for Adoro/Vectris, 92.9 +/- 5 and 85.7 +/- 6.1 for Cercon, and 96.2 +/- 2.1 and 82.2 +/- 9.8 for DC-Leolux, respectively, before and after loading. The percentages of continuous margin at the TC interface were 86.7 +/- 6.7 and 62.5 +/- 16.4 for Adoro/Vectris, 93.3 +/- 3.4 and 83.2 +/- 5.9 for Cercon, and 96.1 +/- 2.4 and 75.3 +/- 7 for DC-Leolux. Statistically significant differences were found after loading between the fiber-reinforced composite and the 2 ceramic systems at the TC interface. CONCLUSION: Within the limitations of this experimental study with regard to the sample size and contacting vectors, the results showed that flexibility of the framework may play an important role in the marginal adaptation of the IFPDs. More rigid materials may transfer less stress to the margins, thus promoting a more stable adhesion to the dental tissues.

Acid Etching, Dental↗
PubMed1998

Ultimate observation of tungsten atoms and clusters adsorbed on single crystalline MgO films.

Tungsten single atoms and clusters composed of four and five atoms deposited on MgO (001) thin films were observed by high-resolution transmission electron microscopy at R.T. The observation was realized by optimizing the thickness of the MgO films and by using special imaging techniques such as an off-Bragg HREM method. The multislice simulation for the interpretation of the image contrast showed a possibility of discrimination of the atomic configuration of clusters, such as "b.c.c.," "on-top," or "f.c.c." type clusters, from details of the image-contrast. The image intensity at the center of the clusters with the b.c.c. configuration was evidently smaller than that of the clusters with the f.c.c. configuration. The reason for the difference was clarified through the multislice image simulation, suggesting that the lattice mismatch between the clusters and the MgO lattice was a key factor in determining the intensity of the center of the clusters.

Adsorption↗
PubMed1999

Accurate structure refinement and measurement of crystal charge distribution using convergent beam electron diffraction.

The method for accurate structure refinement from energy-filtered convergent-beam electron diffraction (CBED) patterns is described with emphasis on recent progress in using imaging filters and 2-D detectors. Details are given about the underlying theoretical model and the statistical analysis of experimental data. The relationship between crystal potential and charge density is also derived for crystals at thermal equilibrium. The method is applied to the refinement of Si (111) and (222) structure factors using various goodness-of-fit (GOF) criteria. Results show that the refinement method is robust and highly accurate. The importance of the experimentally measured structure factors is illustrated through the study of the charge density in MgO. With the measured structure factors, it is possible to obtain details about the charge redistribution due to crystal bonding.

Crystallography↗
PubMed1996

Mechanical and biological properties of two types of bioactive bone cements containing MgO-CaO-SiO2-P2O5-CaF2 glass and glass-ceramic powder.

In this study two types of bioactive bone cement containing either MgO-CaO-SiO2-P2O5-CaF2 glass (type A) or glass-ceramic powder (type B) were made to evaluate the effect of the crystalline phases on their mechanical and biological properties. Type A bone cement was produced from glass powder and bisphenol-a-glycidyl methacrylate (BIS-GMA) resin, and type B from glass-ceramic powder containing apatite and wollastonite crystals and BIS-GMA resin. Glass or glass-ceramic powder (30, 50, 70, and 80 by wt %) was added to the cement. The compressive strength of type A (153-180 MPa) and B (167-194 MPa) cement were more than twice that of conventional polymethylmethacrylate (PMMA) cement (68 MPa). Histological examination of rat tibiae showed that all the bioactive cements formed direct contact with the bone. A reactive layer was seen at the bone-cement interface. In specimens with type A cement the reactive layer consisted of two layers, a radiopaque outer layer (Ca-P-rich layer) and a relatively radiolucent inner layer (low-calcium-level layer). With type B cement, although the Ca-P-rich layer was seen, the radiolucent inner layer was absent. Up to 26 weeks there was progressive bone formation around each cement (70 wt %) and no evidence of biodegradation. The mechanical and biological properties of the cements were compared with those of a previously reported bone cement containing MgO-free CaO-SiO2-P2O5-CaF2 glass powder (designated type C).

Animals↗