Speciation of heavy metals in bed sediments of wetlands in urban Coimbatore, India.
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Sedimentary rocks at Eagle crater in Meridiani Planum are composed of fine-grained siliciclastic materials derived from weathering of basaltic rocks, sulfate minerals (including magnesium sulfate and jarosite) that constitute several tens of percent of the rock by weight, and hematite. Cross-stratification observed in rock outcrops indicates eolian and aqueous transport. Diagenetic features include hematite-rich concretions and crystal-mold vugs. We interpret the rocks to be a mixture of chemical and siliciclastic sediments with a complex diagenetic history. The environmental conditions that they record include episodic inundation by shallow surface water, evaporation, and desiccation. The geologic record at Meridiani Planum suggests that conditions were suitable for biological activity for a period of time in martian history.
Nickel complex of O, O'-dinonyldithiophosphoric acid was prepared and characterised. Solvent extraction of nickel dinonyldithiophosphate [Ni(DNDTP)2] from acidic aqueous solutions into different organic phases was investigated and concentration of nickel was determined spectrophotometrically. A simple and selective spectrophotometric method was developed and applied to sediment samples.
In view of the need for rapid and low-cost solid-phase assays for contaminated sediments, a new 6-day "culture/maintenance-free" microbiotest has been developed with the freshwater ostracod crustacean Heterocypris incongruens at the Laboratory for Biological Research in Aquatic Pollution at the Ghent University in Belgium. The sensitivity of the Ostracodtoxkit F has been compared with that of the 10-day sediment contact test with the amphipod crustacean Hyalella azteca and the two pore water assays (on the anostracan crustacean Thamnocephalus platyurus and the microalgae Raphidocelis subcapitata) selected by the Flemish Environmental Agency for initial hazard assessment of contaminated sediments. The exercise was performed on 26 sediments collected at random from various rivers of the Flemish hydrographic basin in Belgium. The toxicity data ranged from nontoxic to highly toxic for the solid-phase assays and showed that the mortality of the two test biota varied from "nearly identical" to "substantially different," depending on the sediment. The correlation coefficient for the data pairs was weakly positive (r = 0.60), mainly because of 5 samples for which a low mortality had been noted with the ostracod versus a much higher mortality for the amphipod. However, for 4 out of the 5 samples of concern, a substantial growth inhibition was recorded for H. incongruens, showing that this assay eventually performed as did the amphipod test in detecting the toxic character of the sediments. The comparison of toxicity data of the two solid-phase assays with those of the two pore water tests again confirmed that both types of bioassay provided complementary (nonredundant) information. On the basis of its various advantages (independence of stock culturing/maintenance, user-friendliness, precision, and time and cost savings) the new ostracod microbiotest appears to be a promising tool for routine toxicity assessment of contaminated sediments.
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