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[Study on properties of fluorescence and room temperature phosphorescence of 2-bromomethyl naphthalene].

The properties of fluorescence and room temperature phosphorescense (RTP) of 2-Bromomethyl naphthalene (2-BrMN)were studied. The results show that the wavelength for maximum fluorescence of 2-BrMN is lambda(ex/lambda(em) = 274/334 nm. The fluorescence intersity is proportional to the concentration of 2BrMN in the range of 1.0 x 10(-6) - 1.2 x 10(-4) mol x L(-1), and the detection limit is 4.7 x 10(-8) mol x L(-1). The RTP signal of 2-BrMN was induced by beta-cyclodextrin (beta-(CD) in the presence of dibromopropane (DBP) acting as a heavy atom perturbation. The RTP intensity is linear for 2-BrMN/beta-CD/DBP systems of 2-BrMN concentration in the range of 1.0 x 10(-5) - 1.2 x 10(-4) mol x L(-1) (lambda(ex)/lambda(em) = 271/493,521 nm), and the detection limit is 2.7 x 10(-6) mol x L(-1).

English Abstract↗

[The lipids of phosphorescent Vibrio albensis bacteria].

The lipid composition of fluorescent vibrios, V. eltor and nonagglutinating vibrios has been studied. In the fraction of polar lipids phosphatidylethanolamine, phosphatidylinositol and cardiolipin and in the fraction of neutral lipids monoglycerides, free fatty acids, diglycerides, triglycerides, sterol esters have been identified. The fatty acid composition of some classes of neutral lipids have been determined. Both similarity and differences between the strains under study in their lipid and fatty acid composition have been established.

Chromatography, Thin Layer↗

Fibre-optic oxygen sensor based on phosphorescence quenching.

A fibre-optic oxygen sensor is described which is based on an oxygen-sensitive luminescent film made from platinum octaethylporphyrin and polystyrene. The luminescence and quenching characteristics of such films were studied for their use in a fibre-optic oxygen biosensor. A prototype oxygen sensor was made from this material, and was tested in aqueous solutions and in the gaseous phase at physiological oxygen concentrations. Measurements of luminescence intensity and decay time were employed to determine oxygen concentration from luminescence quenching. The main working characteristics of this prototype oxygen sensor were studied.

Biosensing Techniques↗