Elimination of the 4-hydroxyl group of the alkaloids related to morphine. VII. Synthesis of the active 2'-hydroxy-2-methyl-5,9-diethyl-6,7-benzomorphan derivatives.
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Alkaloids↗
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Results for “Benzomorphans”
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Separation and quantitative analysis of some benzomorphane derivatives by thin-layer chromatography.
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Analgesics↗
Synthesis of 6,7-benzomorphan from 4-phenylpyridine.
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Bridged-Ring Compounds↗
Synthesis and analgetic activity of the diastereomeric 8-hydroxy-6,7-benzomorphans.
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Alcohols↗
Synthesis and analgetic activity of 3- and 4-methyl-6,7-benzomorphans.
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Analgesics↗
Homologs of benzomorphan derivatives. I.
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Analgesics↗
Acyl derivatives of 5-hydroxy-6,7-benzomorphans. Prodine congeners.
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Analgesics↗
Absolute configuration of some benzomorphan analgetics and related compounds.
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Analgesics↗
Synthesis of 6,7-benzomorphan and related nonquaternary carbon structures with marked analgetic activity.
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Analgesics↗
Syntheses of benzomorphan and related compounds. II. The debenzylation of quaternary ammonium salts with thiophenol.
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Azocines↗
Interesting pharmacological properties of the optical isomers of alpha-5,9-diethyl-2'-hydroxy-2-methyl-6,7-benzomorphan.
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Analgesics↗
Structures related to morphine. XXXII. Alpha- and beta-2,9-dimethyl-5-propyl-6,7-benzomorphan from 3-methyl-4-propylpyridine.
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Bridged-Ring Compounds↗
Synthesis of 2,9beta-dimethyl-6,7-benzomorphan.
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Analgesics↗
Pentazocine and phenazocine. A double-blind comparison of two benzomorphan derivatives in postoperative pain.
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Adolescent↗
2'-hydroxy-5,9-dimethyl-2-(3-methyl-2-butenyl)-6,7-benzomorphan (pentazocine) hydrochloride hydrate.
The title compound [1,2,3,4,5,6-hexahydro-6,11-dimethyl-3-(3-methyl-2-butenyl)-2,6-methano- 3- benzazocin-8-ol hydrochloride hydrate, C19H28NO+.-Cl-.1/8H2O, (I)] crystallizes with two molecules per asymmetric unit. A comparison of the bond lengths and torsion angles shows a side-chain orientation similar to that of cyclazocine but unlike that of naloxone. The two molecules are linked through a hydrogen-bond network to the interlayer Cl ions, forming a linear chain extending along the ac diagonal of the unit cell.
Crystallography, X-Ray↗
Stereochemical and structural assignment to benzomorphans by mass spectrometry.
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Electrons↗
The comparative pharmacology of morphine, ketocyclazocine and 2'-hydroxy-5,9-dimethyl-2-allyl-6,7-benzomorphan in rodents [proceedings].
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Animals↗
Synthesis of morphine-like structures. I. 9-Hydroxymethyl-2,5-dimethyl-6,7-benzomorphan.
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Morphine↗