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PubMed2004

f-State occupancy at the gamma-alpha phase transition of Ce-Th and Ce-Sc alloys.

Resonant inelastic x-ray scattering spectra were measured for a series of Ce solid solutions (Ce-Th and Ce-Sc) across the gamma-alpha phase transition. They reveal a well-defined feature associated with the 4f2 configuration when the incident energy is tuned to the Ce L3 preedge region. This component is normally hidden in x-ray absorption spectra because of lifetime broadening. The f1/f2 ratio estimated by resonant inelastic x-ray scattering presents a sharp drop across the gamma-alpha transition and hysteresis as a function of temperature that closely resemble the magnetization loop. These measurements confirm recent dynamical mean-field theory calculations that unexpectedly predict significant double occupancy of f orbitals in the ground state.

Journal Article↗

PubMed1998

The cdc25B phosphatase is essential for the G2/M phase transition in human cells.

Cdc25 phosphatases play key roles in cell cycle progression by activating cyclin-dependent kinases. In human cells, cdc25 proteins are encoded by a multigene family, consisting of cdc25A, cdc25B and cdc25C. While cdc25A plays a crucial role at the G1/S phase transition, cdc25C is involved in the dephosphorylation and activation of the mitotic kinase, cdc2/cyclinB. In addition, cdc25C itself is regulated by cdc2/cyclinB which then creates a positive feedback loop that controls entry into mitosis. In this study we show that the activity of cdc25B appears during late S phase and peaks during G2 phase. Both in vitro and in vivo cdc25B is activated through phosphorylation during S-phase. Using a cell duplication, microinjection assay we show that ablation of cdc25B function by specific antibodies blocks cell cycle progression in Hs68 cells by inhibition of entry into mitosis. Cdc25B function neither plays a role in later stages of mitosis nor for the inititation of DNA replication. These results indicate that cdc25B is a mitotic regulator that might act as a 'starter phosphatase' to initiate the positive feedback loop at the entry into M phase.

Antibodies↗

PubMed2003

Intrinsic noise-induced phase transitions: beyond the noise interpretation.

We discuss intrinsic noise effects in stochastic multiplicative-noise partial differential equations, which are qualitatively independent of the noise interpretation (Itô vs Stratonovich), in particular in the context of noise-induced ordering phase transitions. We study a model which, contrary to all cases known so far, exhibits such ordering transitions when the noise is interpreted not only according to Stratonovich, but also to Itô. The main feature of this model is the absence of a linear instability at the transition point. The dynamical properties of the resulting noise-induced growth processes are studied and compared in the two interpretations and with a reference Ginzburg-Landau-type model. A detailed discussion of a different numerical algorithm valid for both interpretations is also presented.

Journal Article↗

PubMed2003

Static and dynamic dielectric properties of strongly polar liquids in the vicinity of first order and weakly first order phase transitions.

The paper presents the results of measurements of the linear dielectric properties of the compounds from the homologous series of alkylcyanobiphenyls (C(n)H(2n+1)PhPhCN, nCB) in the vicinity of the first order transition (from the isotropic liquid to the crystalline phase) of nonmesogenic nCB's (n=2-4) and the weakly first order transition (from the isotropic liquid to the nematic phase) of 5CB. The experimental method for the separation of the critical part of the static permittivity derivative and the activation energy for rotation of the mesogenic molecules, in the vicinity of weakly first order phase transition, is proposed. It is shown that the critical temperature dependence of the permittivity and the activation energy can be described with a function of (T-T*)(-alpha) type, with the same values of the temperature of virtual transition of the second order (T*) and the critical exponent (alpha).

Journal Article↗

PubMed2005

Quantum phase transition in capacitively coupled double quantum dots.

We investigate two equivalent, capacitively coupled semiconducting quantum dots, each coupled to its own lead, in a regime where there are two electrons on the double dot. With increasing interdot coupling, a rich range of behavior is uncovered: first a crossover from spin- to charge-Kondo physics, via an intermediate SU(4) state with entangled spin and charge degrees of freedom, followed by a quantum phase transition of Kosterlitz-Thouless type to a non-Fermi-liquid "charge-ordered" phase with finite residual entropy and anomalous transport properties. Physical arguments and numerical renormalization group methods are employed to obtain a detailed understanding of the problem.

Journal Article↗

PubMed1995

Phase Transitions and Critical Fluctuations in Rhythmic Coordination of Ipsilateral Hand and Foot.

Four subjects performed rhythmic movements of the ankle and the wrist in time with an auditory metronome, in two modes of coordination, antiphase and in-phase. The forearm was placed in either a prone or a supine position. When movements were prepared in the antiphase mode, spontaneous transitions to the in-phase mode, or to phase wandering were observed as metronome frequency was increased. When prepared in the in-phase mode, transitions between in-phase modes or to phase wandering were occasionally observed. Predicted signature features of nonequilbrium phase transitions were noted, including loss of stability and critical fluctuations. The stability of the movement patterns was determined by spatial (dependent upon the direction of movement) rather than anatomical (dependent on the coupling of specific muscle groups) constraints. The position of the forearm had no consistent bearing upon the variability of the phase relations between the limbs, the frequency of phase transitions, or the time of onset of transitions. These results are discussed with reference to the coordination dynamics (e.g., multistability, loss of stability) of multijoint movements.

Journal Article↗

PubMed2004

First-order phase transition of fixed connectivity surfaces.

We report numerical evidence of the discontinuous transition of a tethered membrane model which is defined within a framework of the membrane elasticity of Helfrich. Two kinds of phantom tethered membrane models are studied via the canonical Monte Carlo simulation on triangulated fixed connectivity surfaces of spherical topology. One surface model is defined by the Gaussian term and the bending energy term, and the other, which is tensionless, is defined by the bending energy term and a hard wall potential. The bending energy is defined by using the normal vector at each vertex. Both models undergo the first-order phase transition characterized by a gap of the bending energy. The phase structure of the models depends on the choice of discrete bending energy.

Journal Article↗

PubMed2002

Poly(D,L-lactic acid-co-glycolic acid)-b-poly(ethylene glycol)-b-poly (D,L-lactic acid-co-glycolic acid) triblock copolymer and thermoreversible phase transition in water.

Novel thermoreversible gelation behavior of aqueous solutions of ABA-type triblock copolymers composed of the central polyethylene oxide (PEG) block and two poly(D,L-lactic acid-co-glycolic acid) side blocks was found. Phase transition characteristics, such as critical gel concentration (CGC) and lower and upper critical gel temperature (CGT), are closely related to the molecular structure of the triblock copolymers. The CGC and the lower CGT both increases with increasing PEG/PLGA molecular weight ratio. Increasing the GA content in PLGA block induces a somewhat higher CGC. The copolymer forms micelles with a PLGA loop core and a PEG shell in water. Also grouped micelles are identified seemingly due to the bridging of two micelles sharing two PLGA blocks of a block copolymer chain. As the temperature increases the association of micelles increases, which results in gelation. The ABA-type copolymers exhibit a relatively low CGC (<10%) and low sol-gel transition temperatures compared to BAB-type copolymers. As the temperature increases further gel-sol transition is observed, which would result from the shrinkage of micelles with temperature increase. The hydrodynamic size of the micelles is monitored by dynamic laser scattering, and a possible gelation mechanism was suggested.

Gels↗

PubMed1984

Impurity controlled phase transitions of phospholipid monolayers.

The phase diagram of monolayers of L-alpha-dimyristoyl phosphatidic acid has been studied by fluorescence microscopy. For pressures corresponding to the nearly horizontal slope in the pressure area diagram the growth of crystalline platelets can be observed. They are of dendritic nature; their sizes can be controlled via pressure, compression speed, temperature and pH, and increased up to 100 micron. Due to repulsive interaction a hexagonal arrangement of crystalline platelets can be established. It is shown that the textures do not depend on the dye probe for concentrations below 3 mol%. On the other hand via incorporation of impurities in concentrations of about 1 mol% the coexistence of lipid and solid phases can be controlled. Since, for a constant surface pressure, this coexistence can be maintained, these monolayers are suitable model systems to study the interactions of proteins and vesicles with coexisting fluid and solid membrane areas.

Glycerophospholipids↗

PubMed1978

Turbidity changes of lipid vesicles near the phase transition temperature as an indication of fusion.

Sonicated liposomes of dipalmitoyl phosphatidylcholine show sharp turbidity changes on heating at two distinct temperatures. A decrease in turbidity at the lower temperature (approx. 37degrees C) is thought to be associated with the phase transition of small vesicles and a decrease at about 44 degrees C with larger vesicles or multilayer. An increase of turbidity between 38 and 43 degrees C is attributed to the fusion of small vesicles. The turbidity changes were studied under various modes of vesicle preparation to confirm the interpretation of the turbidity data. Alternate interpretations are discussed.

Chemical Phenomena↗

PubMed2000

Dynamics of the silicon (111) surface phase transition

The manner in which phase transformations occur in solids determines important structural and physical properties of many materials. The main problem in characterizing the kinetic processes that occur during phase transformations is the difficulty of observing directly, in real time, the growth of one phase at the expense of another. Here we use low-energy electron microscopy to study the real-time kinetics of a phase transformation confined to the silicon (111) surface. We show that the transformation is governed by the rate at which material is exchanged between the first layer of the crystal and the surface. In bulk phase transformations, the dynamics are usually governed either by the rate of diffusion of material to the phase boundaries or by the structural rearrangement of atoms at the phase boundary. The kinetic process that we have identified here has no bulk analogue and leads to domain dynamics that are qualitatively different from those expected for bulk systems.

Journal Article↗

PubMed2001

Phase transition in a spatial Lotka-Volterra model.

Spatial evolution is investigated in a simulated system of nine competing and mutating bacterium strains, which mimics the biochemical war among bacteria capable of producing two different bacteriocins (toxins) at most. Random sequential dynamics on a square lattice is governed by very symmetrical transition rules for neighborhood invasions of sensitive strains by killers, killers by resistants, and resistants by sensitives. The community of the nine possible toxicity/resistance types undergoes a critical phase transition as the uniform transmutation rates between the types decreases below a critical value P(c) above that all the nine types of strains coexist with equal frequencies. Passing the critical mutation rate from above, the system collapses into one of three topologically identical (degenerated) states, each consisting of three strain types. Of the three possible final states each accrues with equal probability and all three maintain themselves in a self-organizing polydomain structure via cyclic invasions. Our Monte Carlo simulations support that this symmetry-breaking transition belongs to the universality class of the three-state Potts model.

Bacterial Physiological Phenomena↗

PubMed2003

Surface-induced molecular tilt above the smectic-A-smectic-C phase transition in a nonchiral liquid crystal.

A polyimide-coated substrate was rubbed in such a way as to possess two competing easy axes for liquid crystal alignment. On cooling a homeotropically aligned liquid crystal through the smectic-A phase toward the smectic-C phase transition, an increasing tilt of the molecules relative to the layer normal was observed. The tilt was localized to within a smectic-C correlation length of the interface, and was found to increase monotonically with the rubbing strength associated with the preparation of the polyimide surface. The results are discussed in light of the dual easy axis model [T. Shioda et al., Phys. Rev. E 67, 041706 (2003)], and suggest that the two easy axes are not mutually orthogonal.

Journal Article↗

PubMed2005

Phase transitions in multiplicative competitive processes.

We introduce a discrete multiplicative process as a generic model of competition. Players with different abilities successively join the game and compete for finite resources. Emergence of dominant players and evolutionary development occur as a phase transition. The competitive dynamics underlying this transition is understood from a formal analogy to statistical mechanics. The theory is applicable to bacterial competition, predicting novel population dynamics near criticality.

Animals↗

PubMed2000

Phase transition in the collisionless damping regime for wave-particle interaction

Gibbs statistical mechanics is derived for the Hamiltonian system coupling a wave to N particles self-consistently. This identifies Landau damping with a regime where a second order phase transition occurs. For nonequilibrium initial data with warm particles, a critical initial wave intensity is found: above it, thermodynamics predicts a finite wave amplitude in the limit N-->infinity; below it, the equilibrium amplitude vanishes. Simulations support these predictions providing new insight into the long-time nonlinear fate of the wave due to Landau damping in plasmas.

Journal Article↗

PubMed2003

Micromagnetic phase transitions and spin wave excitations in a ferromagnetic stripe.

Magnetic excitations of micrometer-wide ferromagnetic stripes subjected to a transverse applied field have been measured between 1 and 20 GHz. The complexity of the observed response is attributed to the spatially nonuniform equilibrium spin distribution. This one is modeled analytically and numerically, which allows one to distinguish two micromagnetic phases governing the ground state. The nucleation-related phase transitions are evidenced by soft modes, while the different observed resonances are attributed to spin wave modes localized in the two phases and at their interface.

Journal Article↗

PubMed2004

Phase transition in a system of one-dimensional bosons with strong disorder.

We study one-dimensional disordered bosons at large commensurate filling. Using a real space renormalization group approach, we find a new random fixed point which controls a phase transition from a superfluid to an incompressible Mott glass. The transition can be tuned by changing the disorder distribution even with vanishing interactions. We derive the properties of the transition, which suggest that it is in the Kosterlitz-Thouless universality class.

Journal Article↗

PubMed2005

Dirty, skewed, and backwards: the smectic A-C phase transition in aerogel.

We study the smectic A-C transition in anisotropic and uniaxial disordered environments, e.g., uniaxially stretched aerogel. We find very strange behavior of translational correlations: the low-temperature, lower-symmetry smectic C phase is less translationally ordered than the high-temperature, higher-symmetry smectic A phase, with short ranged and algebraic translational correlations, respectively. Specifically, the A and C phases belong to the quasi-long-ranged translationally ordered "XY Bragg glass" and short ranged translationally ordered "m=1 Bragg glass" phase, respectively. The A-C phase transition itself belongs to a new universality class, whose fixed points and exponents we find in a d=5-epsilon expansion.

Journal Article↗