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At least 19 recordsLinked to original sources

A spontaneous combustion reaction for synthesizing Pt hollow capsules using colloidal carbon spheres as templates.

Here we report a spontaneous combustion reaction in synthesizing Pt hollow capsules. In brief, Pt nanoparticles were loaded on the surface of colloidal carbon spheres by wet-chemical impregnation. When Pt-loaded carbon spheres were taken out of an argon-filled tube furnace at room temperature and exposed to air, they underwent spontaneous combustion. The internal carbon spheres templates were removed to leave nanostructured Pt hollow capsules. There are at least two critical conditions for the occurrence of the spontaneous combustion: the Pt particle size is below 5.8 nm, and the hydrogen content in the carbon spheres is above 2.570 wt %. Such a reaction is interesting for the preparation of metal hollow spheres and is also relevant with respect to removal of accumulated carbon on catalysts and for soot oxidation at room temperature.

Journal Article↗

Study of spontaneous combustion coals by GC and GC-MS.

Organic geochemical characteristics of 3 Chinese spontaneous combustion coals have been carried out by means of GC and GC-MS analysis. It has been observed that more compounds with low to medium carbon number, such as terpenoids and others can be found in spontaneous combustion coals than in normal samples.

Journal Article↗

Spontaneous combustion of shale spoils at a sanitary landfill.

Shale deposits excavated from the Upper Cretaceous, Eagle Ford Formation for a sanitary landfill near Dallas, Texas spontaneously combusted. The shale is dark gray in color, with 3-4% fractional organic carbon, and no lignite seams. Gradual sifting and segregation of fine particles, having high surface area per unit volume, along with moisture trapped in the pile as it accumulated led to spontaneous combustion. Hot summer temperatures compounded the problem by heating the pile and preventing heat from efficiently venting to the atmosphere. Maximum temperatures exceeded 960 degrees F (516 degrees C) at several hot spots located approximately 4 m beneath the pile surface. The ongoing combustion problem, which has lasted for approximately 1 year, eventually will be extinguished by spreading the deposits in thin layers, and compacting them to reduce air circulation and segregation of fines.

Fires↗

Early detection of open fires and spontaneous combustion in mines.

Until fairly recently the detection of heatings was based on men seeing or smelling smoke and the laboratory analysis of mine air samples. Continuous monitoring of carbon monoxide by means of tube bundle systems has been a big step forward in detecting spontaneous combustion of coal and has found widespread acceptance in U.K. mines; general fire detection relies on shaft monitors. Both are based on infra-red analysers like the Unor CO-analysers that can be installed underground. In recent years British laboratories have developed and adapted several devices based on other principles: ionisation, semi-conductors, electro-chemical cells, thermistors, detection "thermal noise", infra-red imagers. All these instruments are briefly described by the authors in this paper presented by Mr. Makower.

Air↗

Spontaneous human combustion: a sometimes incomprehensible phenomenon.

Several cases of human combustion, the cause of which was not evident, have been described over the last few centuries. There are three intriguing elements to such cases. Firstly, although the body is destroyed, the immediate surroundings are left almost intact. Secondly, there is often no visible source of heat that might have started the fire. Thirdly, sometimes bodies are not completely destroyed, certain parts being perfectly preserved, adjacent to others that are reduced to a state of ashes.

Journal Article↗

Zinc burns: a rare burn injury.

A patient was presented with significant burns resulting from a workplace accident in a zinc production unit. This occurred as a result of the spontaneous combustion of zinc bleed under high pressure. The patient sustained burns to the face, body, and hands and suffered significant injury to the left cornea. Computed imaging revealed solid particles in the ethmoid sinus and also in the right nasal fossa, dissecting the right lacrimal duct. Photographic documentation is presented. This injury was potentially preventable and resulted from poor observance of safety procedures.

Accidents, Occupational↗