GLYOXYLATE FERMENTATION BY STREPTOCOCCUS ALLANTOICUS.
Valentine, R. C. (University of Illinois, Urbana), H. Drucker, and R. S. Wolfe. Glyoxylate fermentation by Streptococcus allantoicus. J. Bacteriol. 87:241-246. 1964.-Extracts of Streptococcus allantoicus were found to degrade glyoxylate, yielding tartronic semialdehyde and CO(2). Tartronic semialdehyde was prepared chemically, and its properties were compared with the enzymatic product: reduction by sodium borohydride yielded glycerate; heating at 100 C yielded glycolaldehyde and CO(2); autoxidation yielded mesoxalic semialdehyde; periodate oxidation yielded glyoxylate and a compound presumed to be formate. Tartronic semialdehyde reductase was present in extracts of S. allantoicus and in a species of Pseudomonas grown on allantoin. A scheme for the synthesis of acetate from glyoxylate by S. allantoicus is discussed.