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Biomedical subjects

S G Vermilyea

Publications and source records attributed to S G Vermilyea.

At least 19 recordsLinked to original sources
PubMed1999

In vitro corrosion resistance of high-palladium dental casting alloys.

OBJECTIVE: The objective of this study was to characterize the in vitro corrosion behavior of five high-palladium dental alloys in two media using a potentiodynamic polarization technique. METHODS: Potentiodynamic cyclic polarization between -1000 and +1000 mV (SCE), 12 h open-circuit potential measurement, and linear polarization were performed on cast specimens of three Pd-Cu-Ga alloys and two Pd-Ga alloys in deaerated 0.09% NaCl solution and Fusayama artificial saliva at 37 degrees C. Zero-current potential, corrosion current density, open-circuit potential, and polarization resistance were determined. The Kruskal-Wallis test and the Mann-Whitney U-test were used to analyze the numeric findings. RESULTS: The Pd-Cu-Ga and Pd-Ga alloys in both the as-cast and heat-treated conditions showed spontaneous passive behavior under electrochemical conditions similar to those in the oral environment. The Pd-Cu-Ga alloys Liberty and Spartan Plus exhibited increased activity in the Fusayama artificial saliva after the porcelain-firing heat treatment, which may have arisen from internal oxidation of casting defects. Heat-treated Freedom Plus had an unstable oxide film to form on the surface during anodic polarization and may have a limited tendency for pitting corrosion in the Fusayama artificial saliva. The two heat-treated Pd-Ga alloys remained passive in the test media. As a group, the high-palladium alloys exhibited satisfactory corrosion resistance. SIGNIFICANCE: Corrosion of high-palladium alloys in the oral environment involves a release of ions that is related to their biocompatibility. Knowledge of the in vitro corrosion behavior of these alloys may lead to better understanding of any biologically adverse effects in vivo.

Corrosion↗
PubMed1998

Effects of three soldering techniques on the strength of high-palladium alloy solder joints.

STATEMENT OF PROBLEM: Little information is available on the optimum technique for soldering high-palladium alloys, which have gained considerable popularity for prosthodontic applications. PURPOSE: The objective of this study was to compare the flexural stress at the proportional limit of four noble dental alloy specimens soldered with torch, oven, and infrared-techniques. MATERIALS AND METHODS: The high-palladium alloys studied were Legacy XT (Jelenko), Freedom Plus (Jelenko), and IS 85 (Williams/Ivoclar). A gold-palladium alloy, Olympia (Jelenko), served as the control. Thirty round bars, 18 x 3 mm, were cast from each alloy, cut in half, aligned, and joined using Olympia Pre solder (Jelenko) for the gas-oxygen torch and the infrared technique and Alboro LF solder (Jelenko) for the oven technique. Each soldered bar was subjected to three-point bending, and the maximum elastic stress or strength of the solder joint was calculated at the proportional limit. Data were analyzed by two-way ANOVA and the Ryan-Einot-Gabriel-Welsch (REGW) multiple range test at the 0.05 level of significance. RESULTS: There was no significant difference between torch and oven-soldering, but both were significantly different from the infrared technique. ANOVA showed a significant difference between alloys, but this difference could not be detected with the REGW test. SEM examination of the fracture surfaces revealed grooves associated with the path of crack propagation. X-ray energy-dispersive spectroscopic analysis failed to detect copper in the solders, and there were no significant changes in the solder compositions after the melting procedures. CONCLUSIONS: All three techniques can yield satisfactory solder joints in high-palladium alloys. These joints should be well-polished to achieve optimal strength.

Analysis of Variance↗
PubMed1996

Metallurgical structure and microhardness of four new palladium-based alloys.

PURPOSE: This investigation compared the Vickers hardness and microstructures of four recently marketed, palladium-based alloys for metal-ceramic restorations. MATERIALS AND METHODS: Wax patterns simulating copings for maxillary central incisors were invested in a fine-grained, carbon-free, phosphate-bonded investment. Following burnout, the palladium alloys were fused with a gas-oxygen torch, centrifugally cast, and bench-cooled. Representative castings were embedded in transparent metallographic resin and sectioned to yield two mirror-image specimens. The specimens were evaluated in either the as-cast condition or following heat treatment simulating the firing cycles for Vita VMK porcelain. Vickers hardness measurements (n = 50) were made using a 1-kg load, and photomicrographs of polished and etched specimens were obtained with a scanning electron microscope. RESULTS: The measured values of microhardness for the as-cast alloys were in excellent agreement with values reported by the manufacturer. The hardness in the as-cast condition was significantly greater for the Pd-Cu-Ga-In alloy, compared with the other three alloys, which did not contain copper. For the three high-palladium (> or = 75 wt%) alloys, there were small (4%-8%) decreases in hardness following heat treatment, whereas a larger decrease (13%) in hardness occurred for the Pd-Ag-In-Sn alloy after heat treatment. The porcelain firing cycles caused microstructural homogenization for all four alloys, and the relatively thick near-surface oxidation region in the Pd-Cu-Ga-In and Pd-Ag-In-Sn alloys was not observed in the two heat-treated Pd-Ga-Ag-In-Au alloys. CONCLUSIONS: The multiphasic microstructures of these alloys may have some significance for the in vitro and clinical corrosion behavior and the metal-ceramic bond strength. The hardness for the three high-palladium alloys may be controlled by submicroscopic precipitates that remain unaltered by heat treatment. The significantly greater hardness for the Pd-Cu-Ga-In alloy may cause greater difficulty for finishing castings in the dental laboratory compared with the other three alloys studied. The strengthening mechanism for the Pd-Ag-In-Sn alloy has significant temperature dependence, which might be exploited to achieve optimum mechanical properties.

Analysis of Variance↗
PubMed1994

Effect of ultrasonic cleaning and air polishing on porcelain labial margin restorations.

This study examined porcelain labial margins after ultrasonic scaling and air polishing. Thirty metal coupons were covered with 1.5 mm thick shoulder porcelain and cemented to acrylic resin blocks. A reference mark divided each specimen into a "treated" and an "untreated" side. The specimens were treated as three groups with: (1) an air polisher; (2) an ultrasonic scaler, and (3) the ultrasonic scaler and the air polisher. Surface roughness was determined and selected specimens were observed under scanning electron microscope. Surface roughness ranged from 0.37 microns to 1.06 microns for the untreated sides and from 0.86 microns to 2.80 microns for the treated sides. Increases in roughness were 69% for the ultrasonic scaler/air-polisher; 127% for the air polisher, and 162% for the ultrasonic scaler. ANOVA indicated a significant difference between the treatments. Specimens treated with the air polisher or the ultrasonic scaler and air polisher combination were less distorted than those treated with the ultrasonic scaler alone. The data suggested that careless use of an ultrasonic scaler or air polisher could substantially alter porcelain facial margins.

Analysis of Variance↗
PubMed1994

Effect of disinfection of custom tray materials on adhesive properties of several impression material systems.

The effects of impression tray disinfection procedures on the bond strength of impression-material adhesives to two types of resin trays were evaluated with a tensile test. Autopolymerizing acrylic resin and a visible light-curing resin were formed into one-half inch cubes. A screw eye was attached to each cube before polymerization. Perforated trays were fabricated with stops to maintain an even one-eighth inch of impression material over the resin block. Hooks on the opposite side permitted attachment of the metal plate to a mechanical testing machine. Before adhesive was applied, one third of the resin specimens were immersed in a 1:213 iodophor solution; one third in a 10% sodium hypochlorite solution, and one third were kept in the "as fabricated" condition. Polysulfide, polyether, and polyvinyl siloxane impression material-adhesive systems were evaluated. The resin-impression material-metal plate couples were attached to a mechanical testing machine and tensile forces were applied at a separation rate of 5 inches per minute. Mean values for adhesive strength ranged from 3.49 kg/cm2 for the autopolymerizing acrylic resin/iodophor/polyether combination to 10.55 kg/cm2 for the autopolymerizing acrylic resin/untreated/polyvinyl siloxane combination. Differences were detected among materials and disinfecting procedure. Clinically, disinfection of resin trays may adversely affect retention of the impression material to the tray.

Acrylic Resins↗
PubMed1987

Composite dowels and cores: effect of moisture on the fit of cast restorations.

A study was undertaken to evaluate the effect of interim restorations on the dimensional stability of composite post and core buildups subjected to moisture during the fabrication of cast restorations. Dimensional change associated with composite dowel and core buildups did not significantly alter the fit of cast restorations compared with natural teeth under the same conditions. The use of composite dowels and cores for the restoration of endodontically treated teeth is not contraindicated because of potential dimensional instability of the resin when exposed to moisture. Well-fitting interim restorations for either natural teeth or composite dowel and core buildups improved the fit of cast restorations 23% to 36%.

Composite Resins↗
PubMed1986

Changes in pH of irreversible hydrocolloid impression materials during setting.

Two ophthalmic and four dental irreversible hydrocolloid materials were tested in vitro to determine the initial pH and changes in pH to completion of set over 4 minutes. The ophthalmic Moldite material became more basic during its setting whereas the ophthalmic Moldeye material remained stable throughout the setting. The other materials tested decreased in pH with time.

Chemical Phenomena↗
PubMed1985

Effect of metal conditioners on porcelain-alloy bond strength.

The effect of three metal conditioners on the apparent bond strength of a single porcelain to four alloys was evaluated. On the basis of the bond strength data the following conclusions can be drawn. The use of metal conditioners provided no improvement in the apparent porcelain-alloy bond strength of Biocast and Biobond alloy. The use of Unibond alloy with its recommended conditioner Uniseal gave lower bond strength values than Unibond without the conditioner. With Rexillium III alloy the use of Uniseal gave the highest bond strength values, but these were statistically equal to those obtained with the recommended coating agent (Jeneric bonding agent). With the exception of Rexillium III alloy, it appears that coating agents may have a function other than bond strength improvement. In light of the continued marketing of new alloys, bonding agents, and porcelains, further research is needed to determine the mechanism of action of bonding agents as well as the porcelain-bonding agent-alloy interaction of various commercial products. Studies designed to address these topics are in progress.

Dental Alloys↗
PubMed1985

Apparent bond strength of nonnoble alloy-porcelain combinations.

The apparent bond strengths of four porcelains and five nonnoble alloys were determined. On the basis of the data, the following conclusions can be drawn: The use of Vita, Ceramco, or Will-Ceram porcelains with Rexillium III, Pentillium, or Bak-On-NP alloy gave similar bond strength values. With the exception of Unibond alloy, the bond strength values obtained with Biobond porcelain were lower than those obtained with the other porcelain materials. The ceramometal bond strength values obtained with Unibond alloy were similar with all of the porcelains tested. The continued availability of a bewildering array of new alloys and porcelains suggests the urgent need for research designed to determine the bonding mechanisms and compatibility of various porcelain-alloy combinations. The data from this investigation provide criteria for the rational selection of bond strength-compatible porcelains and alloys for clinical use.

Dental Alloys↗
PubMed1985

A comparison of healing and pain following excision of inflammatory papillary hyperplasia with electrosurgery and blade-loop knives in human patients.

Twenty human patients participated in a study designed to compare electrosurgery with blade-loop knives for the excision of inflammatory papillary hyperplasia in a split-mouth study. Questionnaires were used to assess pain and patient preference during a 2-week postoperative period, and photographs were made to chronicle the healing process. Healing occurred at approximately the same rate following each procedure. The majority of subjects did not perceive a difference in discomfort with either technique on the day of surgery or at any time during follow-up. Of those who did have a preference, a significant majority favored electrosurgery on the day of treatment. This preference became statistically insignificant on the second postoperative day and beyond.

Adult↗
PubMed1984

Preliminary observations on clinical use of a base metal casting alloy.

A study was conducted to develop a laboratory technique and to evaluate the clinical efficacy of a base metal casting alloy. Slight modification of recommended investing procedures is required to produce consistently well-fitting castings with the test alloy. After 12 months of clinical service, the test alloy did not differ from the control alloy in tarnish, untoward gingival response, resistance to abrasion, or tooth sensitivity.

Chemical Phenomena↗
PubMed1984

The effect of carbon fiber orientation on the fatigue resistance and bending properties of two denture resins.

The following conclusions were made concerning the effects of carbon fiber orientation on the flexural fatigue resistance and bending properties of two denture base acrylic resins. Hi-I resin, regardless of fiber presence or orientation, was more resistant to flexural fatigue than Lucitone resin. Carbon fibers placed perpendicular to the direction of applied stress produced the most favorable combination of increased resistance to bending and to flexural fatigue. Production of properly oriented fibers that are well centered within the resin is technically difficult and yields less predictable property improvements than result from randomly dispersed fibers.

Acrylic Resins↗
PubMed1983

The effects of die relief agent on the retention of full coverage castings.

The effect of a commercial die relief agent on the retention of castings cemented with a zinc phosphate, a zinc polycarboxylate, or a modified zinc oxide-eugenol cement was studied. Forces required to dislodge unspaced castings from tooth preparations were higher when zinc phosphate cement was the luting medium. Die relief agents resulted in a 32% reduction in the forces required to dislodge castings cemented with zinc phosphate. Data for the other cements did not differ statistically. Shear strength-tensile ratios of the cements indicate that the high shear strength provided by zinc phosphate cement may be negated by the cementation of oversize castings fabricated from relieved dies.

Crowns↗
PubMed1983

Soldering nonnoble alloys.

Successful presoldering of nonnoble alloys is variable at best. Under controlled conditions of joint gap distance, investing, and soldering, more than one third of the soldered joints are likely to fail. Furthermore, the recorded strength of successful solder joints was inconsistent. Improved heat application and controlled oxidation are required. Until new materials and/or techniques are developed, the soldering of nonnoble alloys prior to the application of porcelain is unwarranted.

Dental Alloys↗
PubMed1983

Casting accuracy of base metal alloys.

The effect of investment material on the casting accuracy of five base metal alloys was evaluated. Overall, the fit of the test castings was poor. Individual alloy-investment interaction appears to be significant. Although marketed for use with base metal alloys, it appears that investment manufacturers' recommended techniques require alteration to enhance the fit of base metal restorations.

Dental Alloys↗
PubMed1983

Observations on nickel-free, beryllium-free alloys for fixed prostheses.

Mechanical properties, electrochemical behavior, heat treatment response, micro-structural features, and compositions of two proprietary nickel-free, beryllium-free fixed prosthodontic alloys were studied. The alloys showed compositional and microstructural differences. Mechanical property values of Biocast and Neobond II are comparable with those of base metal alloys for removable partial dentures. The high hardness, high modulus of elasticity, and low elongation impede adjustment, adaptation of margins, and polishing of the final restoration.

Chemical Phenomena↗