PubMed · 10497292
Surface photograft polymerization on segmented polyurethane using the iniferter technique.
Abstract
A segmented polyurethane (SPU) film was chloromethylated and subsequently dithiocarbamated. The treated films were immersed in solutions containing poly(ethylene glycol) methacrylate (PEGMA) or N, N-dimethyl-acryl amide (DMAAm) and irradiated with ultraviolet (UV) light. The resultant surfaces were highly wettable with water. The surface chemical compositions, as determined by X-ray photoelectron spectroscopy, indicated that surface graft polymerization, initiated from surface-derivatized dithiocarbamate, had occurred and had altered the surface properties and the composition of SPU. The platelet adhesion test using platelet-rich plasma showed minimal adhesion for the poly(PEGMA)-grafted surface, followed by the poly(DMAAm)-grafted surface.
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H J Lee, T Matsuda. 1999-12-15. Surface photograft polymerization on segmented polyurethane using the iniferter technique.. https://doi.org/10.1002/(sici)1097-4636(19991215)47%3A4%3C564%3A%3Aaid-jbm13%3E3.0.co%3B2-3
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