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Asymmetric induction in intramolecular meta photocycloaddition: cyclodextrin-mediated solid-phase photochemistry of various phenoxyalkenes.

K Vízvárdi·K Desmet·I Luyten·P Sandra·G Hoornaert·E Van der Eycken
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Abstract

[reaction: see text]. An approach to the asymmetric intramolecular meta photocycloaddition of phenoxyalkenes is described. The beta-cyclodextrin complexes of several phenoxyalkenes have been synthesized and irradiated in the solid phase. The effect of the CD-hosting on the regio- and enantioselectivity is discussed. Values of ee up to 17% were obtained.

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AlkenesChromatography, High Pressure LiquidCyclodextrinsMagnetic Resonance SpectroscopyModels, ChemicalPhotochemistryJournal ArticleResearch Support, Non-U.S. Gov't

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K Vízvárdi, K Desmet, I Luyten, P Sandra, G Hoornaert, E Van der Eycken. 2001-04-19. Asymmetric induction in intramolecular meta photocycloaddition: cyclodextrin-mediated solid-phase photochemistry of various phenoxyalkenes.. https://doi.org/10.1021/ol0156345

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