PubMed Health⌕ Search

PubMed · 11623969

A distinct break between butane and pentane.

Abstract

In organic chemistry, hydrocarbon compounds with one to four carbon atoms are given individual names such as methane, ethane, propane and butane, whereas those with five carbons or more are named by the serial Greco-Roman numerals like pentane pente, 5), hexane hex, 6 (and heptane hepta, 7). The author points out a distinct conceptual break between the numbers four and five. There have been arguments that primitive cultures had numerals only up to four, and a quantum mental leap was required to cross the boundary after four. Linguistic discussions are made to substantiate the break by scrutinizing the spellings of the numbers "five", "eight" and "nine" of the proto-Indo-European language. In ancient Roman times, 1 (children's ages were counted by winters up to four and by years from five on, 2 (the first four calender months had real names and after four they were called by serial numbers, (3) children up to the fourth were given individual names but from the fifth child on they were named by serial number words, and (4) the words of the number of times had a sharp break between four and five. In various Indo-European languages long ago, the numbers one through four were inflected adjectives, while the numbers beyond four were non-inflectable. All the above observations indicate an existence of a conceptual break after the number four. The author concludes that the notion of such break latently survived in peoples' minds for a long time and came to light when naming of the hydrocarbons was attempted in the 19th century.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

M Uchibayashi. 1999. A distinct break between butane and pentane.. https://pubmed.ncbi.nlm.nih.gov/11623969/

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related citations

Stereochemical identification of (R)- and (S)-ibuprofen using residual dipolar couplings, NMR, and modeling.

In this work, we describe an NMR-based method that utilizes an orientation media composed of the chiral polypeptide liquid crystal poly-gamma-benzyl-L-glutamate (PBLG) dissolved in CDCl(3), to measure the (1)H-(1)H, (1)H-(13)C and (13)C-(13)C residual dipolar couplings (RDCs) of (R) and (S)-ibuprofen. Calculated RDCs, obtained from the lowest energy conformers, are then compared with the experimentally measured RDCs to predict the stereochemistry of each enantiomer. Excellent agreement between calculated and experimental RDCs was found when the lowest energy structure of each enantiomer, obtained in a simulated PBLG/CDCl(3) environment, was used to back-calculate the RDCs. This method is generally useful for small molecular weight molecules that possess either one or two chiral centers, are soluble in low viscosity organic solvents, and will not crystallize (Clegg, Crystal Structure Analysis. Principles and Practice. New York: Oxford University Press; 2002) or cannot be derivatized with a Mosher's reagent (Dale and Mosher, J Am Chem Soc 1973;95:512-519).

Chemistry, Organic↗

A cyclic triphenylamine dimer for organic field-effect transistors with high performance.

A cyclic ethylene linked triphenylamine dimer formed highly crystalline thin film via vapor deposition. Meanwhile, the corresponding linear molecule only resulted in amorphous films under the same condition. The performance as FET semiconductor also improved significantly when the molecular structure derived from linear to cyclic type. The cyclic molecule displayed mobilities in excess of 10-2 cm2 V-1 s-1 and high on/off ratios up to 107.

Chemistry, Organic↗

Stereoselective syntheses of piperidinones and their modification by organometallic coupling reactions.

Dehydropiperidinones stereoselectively obtained from N-arabinosyl imines were iodinated at the enaminone structure. Knochel iodine-magnesium exchange afforded Grignard compounds of these piperidinone derivatives which reacted, either directly or after transmetalation to zinc or copper intermediates, with alkyl-, aryl- or acylhalides to give correspondingly substituted piperidinones. Stereoselective conjugate allyl cuprate addition to a thus obtained 5-allyl dehydropiperidinone and ring-closing metathesis of the product gave a hydroquinolinone containing three stereogenic centers.

Chemistry, Organic↗