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PubMed · 12123038

Continuous hydroamination in a liquid-liquid two-phase system.

Volker Neff·Thomas E Müller·Johannes A Lercher
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Abstract

The direct addition of NH across a CC multiple bond (hydroamination) was efficiently catalysed in a liquid-liquid two-phase system. The latter comprised a polar catalyst phase of Zn(CF3SO3)2 in the ionic liquid 1-ethyl-3-methylimidazolium trifuoromethanesulfonate and a substrate mixture in heptane. The possibility of catalysing different hydroamination reactions continuously was demonstrated.

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AminesCarbonCatalysisHeptanesMesylatesSolubilitySolventsWaterZinc CompoundsJournal Article

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Volker Neff, Thomas E Müller, Johannes A Lercher. 2002-04-21. Continuous hydroamination in a liquid-liquid two-phase system.. https://doi.org/10.1039/b111630d

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