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Solventless sample preparation for pesticides analysis in environmental water samples using solid-phase microextraction-high resolution gas chromatography/mass spectrometry (SPME-HRGC/MS).

Dalva A Souza·Fernando M Lanças
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Abstract

Solid-phase micro-extraction (SPME) coupled on line with high resolution gas chromatography and mass spectrometric detection is described for the analysis of pesticides in environmental water samples. Experiments were performed in order to optimize the SPME extraction conditions for selected pesticides including tiomethon, trichorfon, dimethoate, diazinon, malathion, dicofol, methidathion, ethion, bromopropylate and pyrazophos from spiked water solutions. To enhance the SPME efficiency, experimental conditions including the fiber composition, stirring rate, temperature, adsorption time, desorption time and salt concentration were optimized. After validation, the SPME-GC/MS methodology was applied to real-world environmental water samples.

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Acrylic ResinsAdsorptionDimethylpolysiloxanesFresh WaterGas Chromatography-Mass SpectrometryMineral FibersOsmolar ConcentrationPesticide ResiduesPolyethylene GlycolsSiliconesSolventsTemperatureTime FactorsVinyl CompoundsWater Pollutants, ChemicalJournal ArticleResearch Support, Non-U.S. Gov't

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Dalva A Souza, Fernando M Lanças. 2003. Solventless sample preparation for pesticides analysis in environmental water samples using solid-phase microextraction-high resolution gas chromatography/mass spectrometry (SPME-HRGC/MS).. https://doi.org/10.1081/pfc-120021662

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