PubMed Health⌕ Search

PubMed · 14639758

Differential thermal lensing in extended samples.

Abstract

We present a new scheme for a pump-probe mode-mismatched thermal lensing experiment aimed at extracting the value of low-absorbing components in the presence of a high-absorbing background. The method allows for the use of large path-length samples. Changes in the background absorption of a column of ethanol of 20 cm of 1% and a pollutant concentration detection limit of 0.04 ppm are obtained when using a pump light power of 34 mW.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

A Marcano, J Hung, L Rodríguez, L Borrero. 2003. Differential thermal lensing in extended samples.. https://doi.org/10.1366/000370203769699162

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related citations

Thermal analysis in the evaluation of sediment pollution.

Characterization of organic matter in four sediments in the infuence area of wastewater discharges was carried out by both chemical and thermal analysis in order to assess their pollution level. Oxidisable organic carbon and organic matter were calculated by the standard methodology in laboratory. Thermogravimetry (TG), between 50 and 900 degrees C, was simultaneously performed in oxidizing conditions on ground sediments samples after three different pretreatments. Linear regression adjust of thermal analysis results versus chemical parameters provides the better Pearson's coefficients, leading to the best coefficients for weight loss in 250-400 degree C temperature range versus oxidisable organic carbon and organic matter at 360 degrees C, respectively. These results demonstrated the utility of thermoanalysis technique for the evaluation of the organic matter content of fresh sediments.

Differential Thermal Analysis↗

An experimental study of sewage sludge incineration.

Sludge incinerated ash has been fired at different temperatures. This material was fired at 1050 degrees C for 3 h and until a peak of 1010 degrees C. After thermal treatment the ash was screened at 200 mesh.The ash was characterized by X-ray fluorescence and trace elements like Cr, Pb, Zn, Cu, and some oxides like quartz(SiO2), Al2O3, P2O5, Fe2O3 were found. Scanning electron microscopy(SEM) has shown one change of particle between 2 microm at 90 microm and apparent porosity, thermal analysis has shown loss of mass and residual decomposition in the TG, DTG and DTA curves.

Differential Thermal Analysis↗

Synthesis and fluorescence properties of rare earth (Eu3+ and Gd3+) complexes with alpha-naphthylacetic acid and 1,10-phenanthroline.

Rare earth binary complex Eu(NNA)3 (NNA, alpha-naphthylacetic acid), ternary complex Eu(NNA)3.phen (phen, 1,10-phenanthroline) and a series of dinuclear complexes with different mole ratios of Eu3+ to Gd3+ were synthesized. Many advanced approaches, such as element analysis, FTIR spectra, TG and DTA analysis, were used to determine the composition and structure of binary and ternary complex. Moreover, their fluorescence properties were studied by fluorescent spectra and lifetimes. The fluorescence spectra and decay curves of dinuclear complexes indicated that the fluorescence emission intensity was enhanced and the fluorescence lifetime was prolonged by Gd3+. The dinuclear complexes show the best properties when the mole ratio of Eu3+ to Gd3+ is 6:4. A new parameter Y, which was used to evaluate the effect of Gd3+, was introduced. In addition, the relationship of Y value and mole fraction of Gd3+ was analyzed by mathematical software. The results showed that Y value decreased by single exponential mode when the content of Gd3+ decreased.

Differential Thermal Analysis↗