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Novel template-directed anodic phenol-coupling reaction.

Itamar M Malkowsky·Christina E Rommel·Roland Fröhlich·Ulrich Griesbach·Hermann Pütter·Siegfried R Waldvogel
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Abstract

Substituted phenols were anodically coupled to the corresponding 2,2'-biphenols via tetraphenoxy borate derivatives. This electrochemical method is particularly useful for methyl-substituted substrates, such as 2,4-dimethyl phenol. The selective ortho-coupling reaction can be easily performed on a multikilogram scale.

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BoratesElectrochemistryOxidation-ReductionPhenolsJournal ArticleResearch Support, Non-U.S. Gov't

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Itamar M Malkowsky, Christina E Rommel, Roland Fröhlich, Ulrich Griesbach, Hermann Pütter, Siegfried R Waldvogel. 2006-09-25. Novel template-directed anodic phenol-coupling reaction.. https://doi.org/10.1002/chem.200600375

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