PubMed · 4276441
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R Mapstone. 1974. Closed-angle glaucoma. Experimental results.. https://doi.org/10.1136/bjo.58.1.41
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Mannostatins A and B, along with the respective enantiomer and diastereoisomer having the (S)-sulfinyl function, were synthesized from myo-inositol. Inhibitory activity of the synthetic compounds against jack bean alpha-mannosidase was measured, revealing that the 4-aminocyclopentane-1,2,3-triol structure plays a major role in interaction with the enzyme.
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The absolute stereochemistry of yeast reduction products 2s and 2a from 2-(3',4'-dimethoxy-cinnamyl)-2-methylcyclopentane-1,3-dione (1) was investigated. The results from several spectral studies and chemical correlations enabled their absolute configurations to be concluded as (2S,3S) and (2R,3S), respectively.