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PubMed · 640701

A computer simulation study for the digital processing of longitudinal tomograms obtained with a zone plate camera.

S Webb·R P Parker·D R Dance·A Nicholas
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S Webb, R P Parker, D R Dance, A Nicholas. 1978. A computer simulation study for the digital processing of longitudinal tomograms obtained with a zone plate camera.. https://doi.org/10.1109/tbme.1978.326240

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The present paper describes a theoretical study on the mechanism underlying the reaction of cellular glutathione (GSH) with polyunsaturated fatty acid ozonides. The reaction can be catalyzed by glutathione S-transferases and leads to detoxication of the ozonides. Semi-empirical molecular orbital computer calculations suggest that the reaction of glutathione with ozonides involves a nucleophilic attack at one of the carbon atoms of the ozonide ring, instead of at one of the peroxidic oxygen atoms of the ozonide ring. This implies a mechanism different from that of the glutathione S-transferase-mediated reaction with hydroperoxides, previously proposed for the glutathione-dependent detoxication of fatty acid ozonides.

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