PubMed · 903477
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H W Nass. 1977. New T1-201 nuclear decay data.. https://pubmed.ncbi.nlm.nih.gov/903477/
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Multivariate data analysis methods were used to recognize and classify soils of unknown geographic origin. A total of 103 soil samples were differentiated into classes, according to regions in Serbia and Montenegro from which they were collected. Their radionuclide (226Ra, 238U, 235U, 40K, 134Cs, 137Cs, 232Th and 7Be) activities detected by gamma-ray spectrometry were then used as the inputs in different pattern recognition methods. For the classification of soil samples using eight selected radionuclides, the prediction ability of linear discriminant analysis (LDA), k-nearest neighbours (kNN), soft independent modelling of class analogy (SIMCA) and artificial neural network (ANN) were 82.8%, 88.6%, 60.0% and 92.1%, respectively.
The MultiAgency Radiation Survey and Site Investigation Manual (MARSSIM), published in December 1997, has been used for designing final status surveys at a number of D&D sites to date. One of the more challenging aspects of the MARSSIM survey design is the strategy employed when multiple radionuclides are present, particularly in Class 1 survey units. The MARSSIM recommends that potential hot spots in a Class 1 survey unit--that could exceed the derived concentration guideline levels for small elevated areas of radioactivity (i.e., DCGL(EMC))--have a reasonably good probability of being detected. Soil sampling on a specified grid size, in conjunction with gamma radiation surface scanning, is used to obtain an adequate assurance level that these hot spots are not missed during the final status survey. Therefore, it is sometimes necessary to supplement the sample size required by the statistical test to provide additional assurance that potential hot spots of concern are detected.
Complexes of the type [Re(III)L6]X3, with L = thiourea, N-methylthiourea, N-ethylthiourea or N,N'-dimethytlthiourea and X = Cl- or PF6-, were prepared as suitable precursors for the synthesis of new rhenium complexes potentially useful in nuclear medicine. The infrared (IR) spectra of these complexes were recorded and analyzed and a general vibrational pattern for Re(III) complexes with thiourea derivatives could be established. Approximate assignments for N-allylthiourea and N-ethylthiourea are also proposed for the first time. The synthesis of the new complex [Re(III)(N-allylthiourea)6](PF6)3 is also reported, and information about its structural characteristics was obtained comparing its IR spectrum with those of the other complexes of the investigated series.