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Results for “Phase Transition”

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At least 1,099 records · Page 61Linked to original sources

PubMed2005

Raman spectroscopic studies of the phase transitions in hexane at high pressure.

Raman spectroscopic study of n-hexane was carried out in a cubic zirconia anvil cell up to approximately 2.0 GPa. Under high pressure, the C-H stretching region of the spectrum at 2850-3000 cm(-1) shows measurable changes in frequency, bandwidth, and intensity. These Raman bands shift towards higher frequencies with increasing pressure. At about 1.4 GPa, phase transition from liquid to solid was induced by compression, as was simultaneously observed with the built-in microscope.

Hexanes↗

PubMed2005

Origin of shear-induced phase transitions in melts of liquid-crystal polymers.

Flow induced mechanical properties are often coupled with instabilities, spurt effects, or induced phase transitions. Recent studies have revealed that side-chain liquid crystal polymers exhibit typically shear-induced phases inside the isotropic (nonmesomorphic) liquid state. We present an experimental approach which brings a new understanding for nonlinear flow behaviors. The strategy consists in comparing the critical times issued from the flow behavior of a liquid-crystal polymer to the equilibrium orientational-order relaxation time was characterized. We demonstrate that shear-induced phases do not originate from a flow coupling to conventional orientational order parameter fluctuations. It does not also correspond to a direct coupling with the viscoelastic terminal time, leading to the conclusion that an additional relaxation process takes place with time scales longer than the terminal time. The identification of a low-frequency elastic plateau by viscoelastic measurements corroborates this conclusion.

Journal Article↗

PubMed2004

Nematic-isotropic phase transition in diblock fused-sphere chain fluids.

A density-functional theory for the isotropic-nematic phase transition in fluids of rigid or semiflexible fused hard-sphere chains, developed previously by the authors, is extended to diblock chains each consisting of both a rigid and a flexible part. The theory is compared with recent Monte Carlo simulation results of McBride et al. The theoretical results for the variation of pressure and nematic order parameter with density agree well with the simulation data over density ranges where the simulations find isotropic and nematic phases.

Journal Article↗

PubMed2004

Structure and fluctuations of phosphatidylcholines in the vicinity of the main phase transition.

We have determined the structural properties and bending fluctuations of fully hydrated phosphatidylcholine multibilayers in the fluid (Lalpha) phase, as well as the structure of the ripple (Pbeta') phase near the main phase transition temperature (TM) by x-ray diffraction. The number of carbons, nHC, per acyl chain of the studied disaturated lipids varied from 14 to 22. All lipids exhibit a nonlinear increase of the lamellar repeat distance d in the Lalpha phase upon approaching TM, known as "anomalous swelling." The nonlinear increase reduces with chain length, but levels off at a constant value of about 0.5 A for lipids with more than 18 hydrocarbons per chain. A detailed analysis shows that anomalous swelling has two components. One is due to an expansion of the water layer, which decreases with chain length and finally vanishes for nHC >18. The second component is due to a bilayer thickness increase, which remains unchanged in its temperature dependence, including a nonlinear component of about 0.5 A in the vicinity of TM. Thus, anomalous swelling above 18 hydrocarbons per chain is due to the pretransitional effects on the membrane only. These results are supported by a bending fluctuation analysis revealing increased undulations close to TM only for the short chain lipids. We have further calculated the electron density maps in the ripple phase and find no coupling of the magnitude of the ripple amplitude to the chain length effects observed in the Lalpha phase. Hence, in agreement with an earlier report by Mason et al. [Phys. Rev. E 63, 030902 (2001)] there is no connection between the formation of the ripple phase and anomalous swelling.

Biophysics↗

PubMed2006

Mid-infrared study of deoxycytidine at high pressures: evidence of a phase transition.

Room temperature mid-infrared experiments between 600 and 1600 cm(-1) have been performed on crystalline deoxycytidine as a function of pressure up to about 10 GPa. The wavenumbers of most vibrational modes shift to higher values with increasing pressures except for a mode near 840 cm(-1). Assignments for the observed modes are made on the basis of work published in the literature. Several anomalies are noted near 4.7 GPa, suggesting a phase transition. Our results for deoxycytidine are compared to similar measurements on cytidine.

Deoxycytidine↗

PubMed2001

Femtosecond Structural Dynamics in VO2 during an Ultrafast Solid-Solid Phase Transition.

Femtosecond x-ray and visible pulses were used to probe structural and electronic dynamics during an optically driven, solid-solid phase transition in VO(2). For high interband electronic excitation (approximately 5 x 10(21) cm(-3)), a subpicosecond transformation into the high-T, rutile phase of the material is observed, simultaneous with an insulator-to-metal transition. The fast time scale observed suggests that, in this regime, the structural transition may not be thermally initiated.

Journal Article↗

PubMedDate not supplied

[Phase transition in a native collagen in the presence of salts].

Effect of two salts NaCl and KCl on volume change due to phase transition in native collagen has been examined at different concentrations of the salt in the collagen phase. The melting diagrams of water-salt system have been plotted in the collagen phase. The obtained diagrams differ from those of pure water-salt solutions. To explain the difference chemical interaction between collagen and salt is assumed.

Animals↗

PubMed2006

Changes in molecular order across the lamellar-to-inverted hexagonal phase transition depend on the position of the double-bond in mono-unsaturated phospholipid dispersions.

A series of mono-unsaturated phosphatidylethanolamine (PE) model membranes is studied using deuterium nuclear magnetic resonance (NMR) and differential scanning calorimetry. As the position of the double bond is systematically changed, the internal conformational motions are monitored through the bilayer-to-inverted-hexagonal phase transition. The order parameter profiles extracted from the NMR spectra report on the conformational order of the lipid and on the way this order is changed by structural reorganizations of the membrane. The calculation of a ratio of renormalized order parameter profiles is presented here as an attempt to distill the essential features of these changes into dimensionless descriptions of "shape" functions. This variation of the extent of molecular disorder along the long molecular axis of the phospholipids appears to be a recurring motif, modulated by temperature, structural rearrangement, and chemical composition of the membrane. The reported experimentally measured changes in the shape of the order parameter profile can be compared to those obtained during molecular dynamics simulation studies.

Calorimetry, Differential Scanning↗

PubMed1983

Influence of various cationic amphiphilic drugs on the phase-transition temperature of phosphatidylcholine liposomes.

The influence of 16 cationic amphiphilic compounds from various pharmacological groups on the phase-transition temperature (Tt) of dipalmitoyl-phosphatidylcholine (DPPC) liposomes was investigated using the method of differential scanning calorimetry. All drugs, the hydrophobicity of which varied in a wide range, depressed Tt. Biphasic dose-effect curves were obtained when the reduction of Tt (delta Tt) was plotted vs the molar ratio of drug/DPPC; beyond a plateau, Tt could again be reduced markedly by increasing the molar ratio. Concomitantly with the depression of Tt, the width of the transition peak changed in a characteristic way: it broadened during the (first) steep part of the dose-effect curves and became narrow like a control transition when the plateau of the dose-effect curves was reached. At still higher ratios the peak broadened again and eventually vanished, probably due to a detergent-like effect of the drug. Increasing hydrophobicity of the compounds shifted the dose-effect curves to lower molar ratios and enhanced the delta Tt attained at the plateau phase. It is proposed that the different potencies of the drugs to depress Tt result from different binding equilibria between the compounds and DPPC membranes, the individual equilibrium being determined by hydrophobic attraction and electrostatic repulsion.

Anions↗

PubMed2006

Characteristic behavior of short-term dynamics in reorientation for Gay-Berne particles near the nematic-isotropic phase transition temperature.

A specific transition behavior was found in the tumbling motion near the nematic-isotropic phase boundary using molecular dynamics simulations of the Gay-Berne mesogenic model under isobaric conditions at a reduced pressure P* of 2.0. The relaxation time for the motion obtained from the second-rank orientational time correlation function and the rotational diffusion coefficient showed a clear jump at the nematic-isotropic phase transition temperature. Regardless of the temperature dependence of the relaxation time, the change in the rotational diffusion coefficient evaluated from the orientational order parameters and the relaxation time agreed qualitatively with that of real mesogens. The rotational viscosity coefficients gamma(1) and gamma(2) were obtained from the simulation data for the relaxation time for the short-term dynamics and for the rotational diffusion coefficients. gamma(1) was proportional to (2), where is the second-rank orientational parameter. Furthermore, the rotational behavior of the model was compared with that of the Debye approximation in the isotropic phase.

Journal Article↗

PubMed1984

Microwave bioeffects in the erythrocyte are temperature and pO2 dependent: cation permeability and protein shedding occur at the membrane phase transition.

Microwave exposure (2450 MHz, 60 mW/g, CW) of rabbit erythrocytes increases Na passive transport only at membrane phase transition temperatures (Tc) of 17-19 degrees C. This permeability effect is enhanced for relative hypoxia which is characteristic of intracellular oxygen tension (pO2 less than or equal to 5 mm Hg). Neither the permeability nor the pO2 effects are observed in temperature-matched (+/- 0.05 degrees C), sham-exposed controls. In addition, at Tc, microwave exposure is observed to induce the shedding or release of two erythrocyte proteins not seen in sham-exposed controls. Moreover, the enhanced shedding of at least seven other proteins all of molecular weight less than or equal to 28,000 D was detected in the microwave-treated samples. Using sensitive silver staining we estimate that approximately 450 fg of protein were shed per erythrocyte. These results demonstrate that temperature and pO2 are important influences on both functional and structural responses of cell membranes to microwave radiation.

Animals↗

PubMed1985

Ultrasonic absorption and permeability for liposomes near phase transition.

The specific ultrasonic absorption coefficient per wavelength as a function of temperature in the vicinity of the phase transition of liposomes, composed of a 4:1 mixture of dipalmitoylphosphatidylcholine (DPPC) and dipalmitoylphosphatidylglycerol (DPPG), of different sizes was determined using an acoustic interferometer. Small unilamellar vesicles (SUV) and multilamellar vesicles (MLV) yielded results similar to those in the literature, viz., an absorption maximum at the transition temperature. Seven intermediate sizes including several size distributions of large unilamellar vesicles (LUV) were studied, yielding information on size dependencies of the temperatures at which the peaks occur, the widths at half peak amplitude, and the peak amplitudes. All liposome sizes except the SUV exhibited approximately the same transition temperature as did the largest MLV. The widths of the peaks were inversely related to liposome size, with a strong dependence for the smallest vesicles and an approach to independence for the largest vesicles. The amplitudes of the peaks exhibited a general increase with size with two exceptions, viz., the SUV and the vesicles with average diameters of 90-100 nm. It was also found that the membrane permeability increased near the transition temperature. The temperature dependencies of ultrasonic absorption and membrane permeability are compared.

1,2-Dipalmitoylphosphatidylcholine↗

PubMed1991

Polymorphic phospholipid phase transitions as tools to understand peptide-lipid interactions.

The effect of peptides on bilayer----non-bilayer phase transitions can be used as a tool to investigate the molecular aspects of peptide-lipid interactions. In this contribution the action on membranes of the peptide antibiotic gramicidin A and the bee venom component melittin are compared. Although the known structures and locations of these peptides upon membrane binding are very different, their actions on membranes show striking parallels. A general model is proposed that explains the seemingly complex peptide-lipid interactions by making use of simple concepts.

Amino Acid Sequence↗

PubMed2000

General theory of lee-yang zeros in models with first-order phase transitions

We present a general, rigorous theory of Lee-Yang zeros for models with first-order phase transitions that admit convergent contour expansions. We derive formulas for the positions and the density of the zeros. In particular, we show that, for models without symmetry, the curves on which the zeros lie are generically not circles, and can have topologically nontrivial features, such as bifurcation. Our results are illustrated in three models in a complex field: the low-temperature Ising and Blume-Capel models, and the q-state Potts model for large q.

Journal Article↗

PubMed2002

Dynamics of quantum phase transition in an array of Josephson junctions.

We study the dynamics of the Mott insulator-superfluid quantum phase transition in a periodic 1D array of Josephson junctions. We show that crossing the critical point at a finite rate with a quench time tau(Q) induces finite quantum fluctuations of the current around the loop proportional to tau(-1/6)(Q). This scaling could be experimentally verified with an array of weakly coupled Bose-Einstein condensates or superconducting grains.

Journal Article↗

PubMed2002

Giant infrared intensity of the Peierls mode at the neutral-ionic phase transition.

We present exact diagonalization results on a modified Peierls-Hubbard model for the neutral-ionic phase transition. The ground state potential energy surface and the infrared intensity of the Peierls mode point to a strong, nonlinear electron-phonon coupling, with effects that are dominated by the proximity to the electronic instability rather than by electronic correlations. The huge infrared intensity of the Peierls mode at the ferroelectric transition is related to the temperature dependence of the dielectric constant of mixed-stack organic crystals.

Journal Article↗

PubMed2006

Simulation of phase transitions in highly asymmetric fluid mixtures.

We present a novel method for the accurate numerical determination of the phase behavior of fluid mixtures having large particle-size asymmetries. By incorporating the recently developed geometric cluster algorithm within a restricted Gibbs ensemble, we are able to probe directly the density and concentration fluctuations that drive phase transitions, but that are inaccessible to conventional simulation algorithms. We develop a finite-size scaling theory that relates these density fluctuations to those of the grand-canonical ensemble, thereby enabling accurate location of critical points and coexistence curves of multicomponent fluids. Several illustrative examples are presented.

Journal Article↗

PubMed2005

Nanoparticle size-dependent lowering of temperature for phase transition from In(OH)3 to In2O3.

Phase transformation of In(OH)3 to In2O3 has been studied as a function of nanoparticle size without any alteration of nanoparticle size during transformation. Chemically capped In(OH)3 nanoparticles having sizes of 15, 11, and 8 nm transform to In2O3 at temperatures of 285, 272, and 255 degrees C, respectively. This first-time unambiguous observation of size-dependent lowering of transformation temperature represents a thermodynamic characteristic of the nanoparticle system. The results have been explained in terms of a lower cohesive energy of surface atoms and an increase in surface-to-volume ratio with a decrease in nanoparticle size.

Hydroxides↗