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PubMed · 14677929

Metal-stabilized phenoxonium cation.

Arkadi Vigalok·Boris Rybtchinski·Yael Gozin·Tehila S Koblenz·Yehoshoa Ben-David·Haim Rozenberg·David Milstein
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Abstract

An unprecedented metal-stabilized phenoxonium cation was prepared by a process involving dearomatization of a phenoxy complex. The unique eta2 C=O-metal (iridium) coordination mode leaves the positive charge delocalized within the former aromatic ring. The X-ray structure and conversion into eta2 C=O-coordinated metal-quinone complex are described.

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CationsCrystallography, X-RayMolecular StructureOnium CompoundsOxidation-ReductionPhenolsJournal ArticleResearch Support, Non-U.S. Gov't

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Arkadi Vigalok, Boris Rybtchinski, Yael Gozin, Tehila S Koblenz, Yehoshoa Ben-David, Haim Rozenberg, David Milstein. 2003-12-24. Metal-stabilized phenoxonium cation.. https://doi.org/10.1021/ja0385639

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