PubMed Health⌕ Search

PubMed · 9281486

Multiple nonlinear stimulated echoes.

Abstract

Three-pulse sequences in the presence of magnetic field gradients at high magnetic fields produce multiple nonlinear stimulated echoes (NOSE) at times ntau1 after the third pulse, where n is an integer and tau1 the interval between the first two pulses. These phenomena are due to the demagnetizing field produced by the spatial modulation of the nuclear magnetization arising in the sample after the first two pulses. The theory is presented and compared with experiments. The dependence of the NOSE amplitudes on the flip angles and on the pulse intervals is described. Implications for multidimensional NMR experiments based on sequences of three or more pulses in the presence of field gradients are discussed.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

I Ardelean, R Kimmich, S Stapf, D E Demco. 1997. Multiple nonlinear stimulated echoes.. https://doi.org/10.1006/jmre.1997.1197

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related citations

Surface biopassivation of replicated poly(dimethylsiloxane) microfluidic channels and application to heterogeneous immunoreaction with on-chip fluorescence detection.

Poly(dimethylsiloxane) (PDMS) appeared recently as a material of choice for rapid and accurate replication of polymer-based microfluidic networks. However, due to its hydrophobicity, the surface strongly interacts with apolar analytes or species containing apolar domains, resulting in significant uncontrolled adsorption on channel walls. This contribution describes the application and characterization of a PDMS surface treatment that considerably decreases adsorption of low and high molecular mass substances to channel walls while maintaining a modest cathodic electroosmotic flow. Channels are modified with a three-layer biotin-neutravidin sandwich coating, made of biotinylated IgG, neutravidin, and biotinylated dextran. By replacing biotinylated dextran with any biotinylated reagent, the modified surface can be readily patterned with biochemical probes, such as antibodies. Combination of probe immobilization chemistry with low nonspecific binding enables affinity binding assays within channel networks. The example of an electrokinetic driven, heterogeneous immunoreaction for human IgG is described.

Dimethylpolysiloxanes↗

Microfabrication of polydimethylsiloxane electrospray ionization emitters.

Microfabricated polydimethylsiloxane (PDMS) emitters for electrospray ionization mass spectrometry (ESI-MS) were implemented as tips along the edge of the PDMS device by three methods which utilize soft lithography processes. These microfabrication methods for producing PDMS emitters as an integral part of a microfluidic device will facilitate development of more complex microfluidic analysis systems using ESI-MS.

Dimethylpolysiloxanes↗

Staged reduction of gastroschisis: a simple method.

Staged reduction of abdominal contents using a silastic sheet has become standard management in gastroschisis where primary closure is not possible. With the introduction of a pre-made Silastic silo coupled to a spring-loaded ring (Ben Tec, Sacramento, CA), the procedure can be done at the bedside. We present a simple technique utilizing a disposable umbilical-cord clamp that makes reduction a fast, one-physician procedure and present a preoperative step that facilitates tension-free closure of the abdominal fascia.

Dimethylpolysiloxanes↗